This study presents a detailed analysis of thermal and radiation resistances of low density polyethylene (LDPE)/ultra-high molecular weight polyethylene (UHMWPE) blends containing hydroxyapatite as functional filler and rosemary acting as antioxidant against oxidative degradation. Three main procedures, chemiluminescence (CL), Fourier transform infrared spectroscopy (FTIR), and differential scanning calorimetry (DSC), were applied for the determination of the degree of degradation when these materials are subjected to heat and radiation action. The crystallinity was also assessed for the characterization of diffusion peculiarities. The contributions of the mixing components are discussed based on their oxidation strength. The activation energies required for the oxidative degradation of the studied formulations were calculated.

This study investigates the stability behavior of blends composed of ethylene-propylene-diene monomer (EPDM) and styrene-butadiene-styrene (SBS), focusing on the effects of γ-irradiation on these materials. FTIR, CL, and DSC analysis indicate that blends with more than 50% SBS demonstrate remarkable resistance to significant radiation doses. This study highlights that at increased γ-irradiation doses, specifically 100 and 150 kGy, structural changes in the polystyrene aromatic rings are detected, providing insights into the modifications induced by radiation exposure. Among the tested formulations, the blend containing 75% SBS demonstrated the best performance against γ-irradiation, showcasing superior mechanical and structural resistance to radiation-induced degradation. The results indicate that γ-irradiation leads to managed degradation within the SBS/EPDM mixtures: while EPDM experiences increased crosslinking, SBS proves resilient against crosslinking, thus bolstering the stability of EPDM under irradiation scenarios. Additionally, thermal analysis underlines the beneficial role of SBS by showing enhanced thermal stability in SBS-rich samples (SBS content higher than 50%) experiencing reduced thermal degradation through repeated heating cycles. This outcome suggests that the inclusion of SBS effectively reduces crosslinking and chain scission impacts, thereby enhancing consistency in thermal properties over multiple cycles.

This study presents the functional effects of BaTiO₃ powder loaded in ethylene–propylene–diene rubber (EPDM) in three concentrations: 0, 1, and 2.5 phr. The characterization of mechanical properties, oxidation strength, and biological vulnerability is achieved on these materials subjected to an accelerated degradation stimulated by their γ-irradiation at 50 and 100 kGy. The thermal performances of these materials are improved when the content of filler becomes higher. The results obtained by chemiluminescence, FTIR-ATR, and mechanical testing indicate that the loading of 2.5 phr is the most proper composition that resists for a long time after it is γ-irradiated at a high dose. If the oxidation starts at 176 °C in the pristine polymer, it becomes significant at 188 and 210 °C in the case of composites containing 1 and 2.5 phr of filler, respectively. The radiation treatment induces a significant stability improvement measured by the enlargement of temperature range by more than 1.5 times, which explains the durability growth for the radiation-processed studied composites. The extension of the stability period is also based on the interaction between degrading polymer substrate and particle surface in the composite richest in titanate fraction when the exposure is 100 kGy was analyzed. The mechanical testing as well as the FTIR investigation clearly delimits the positive effects of carbon black on the functionality of EPDM/BaTiO₃ composites. The contribution of carbon black is a defining feature of the studied composites based on the nucleation of the host matrix by which the polymer properties are effectively ameliorated.

The thermal and radiation stabilities of the formulations based on ethylene–propylene–diene rubber (EPDM), which contain barium titanate (BaTiO₃) doped with lanthanum and cerium oxides, were investigated by chemiluminescence and mechanical testing. The contributions of these doped fillers are related to the surface interaction between the structural defects (doping atoms, i.e., lanthanum and cerium) implanted in the filler lattice and the molecular fragments formed during the progress of degradation. These composite materials present extended durabilities with respect to the references; the oxidation periods are a minimum of three times longer than the corresponding times for pristine polymers. This behavior is associated with the scavenging activity of dopants. Mechanical testing has demonstrated the contributions of doped filler to the improvement of tensile strength and elongation at break by the restructuration of the polymer phase. Scanning electron microscopy images revealed the densification of materials in the presence of doped barium titanates. All the investigations constitute valid proof for the qualification of BaTiO₃ doped with Ce as the more efficient stabilizer compared to the same inorganic filler doped with La.

The accelerated degradation of alkyd resins via γ-irradiation is investigated using non-isothermal chemiluminescence. The stability qualification is possible through the comparison of emission intensities on a temperature range starting from 100 °C up to 250 °C under accelerated degradation caused by radiolysis scission. The measurements achieved in the samples of cured state resin modified by various inorganic oxides reveal the influence of metallic traces on the aging amplitude, when the thermal resistance increases as the irradiation dose is augmented. Even though the unirradiated samples present a prominent chemiluminescence intensity peak at 80 °C, the γ-processed specimens show less intense spectra under the pristine materials and the oxidation starts smoothly after 75 °C. The values of activation energies required for oxidative degradation of the sample subjected to 100 kGy are significantly higher in the composite states than in the neat resin. The degradation mechanism of polymerized resins is discussed taking into account the effects of fillers on the stability of studied epoxy resin at various temperatures when the degradation and crosslinking are in competition for the decay of free radical.