The goal of the study was to analyze fracture properties of adhesive bond using a three-point end-notched flexure test and the compliance-based beam method. Critical strain energy release rates (G _IIc ) and cohesive laws were obtained for adhesive bonds made of European beech (Fagus sylvatica L.) and adhesives such as EPI, MUF, PRF and PUR. The experiments were assisted with FE analyses employing three different material models of wood: elastic (Elas), symmetric elasto-plastic (EP) and elasto-plastic with different compressive and tensile yield stresses parallel to fiber (EP+). The highest mean G _IIc was achieved for PUR (5.40 Nmm⁻¹) and then decreased as follows: 2.33, 1.80, 1.59 Nmm⁻¹ for MUF, EPI, and PRF, respectively. The failure of bondline was brittle and occurred at bondline for EPI, MUF and PRF, and ductile and commonly occurring in wood for PUR adhesive. The FE simulations employing cohesive models agreed well with the experimental findings for all adhesives. FE model with Elas material was found accurate enough for EPI, MUF and PRF adhesives. For PUR adhesive, the model EP+ was found to be the most accurate in prediction of maximal force. The impact of friction between lamellas may be up to 4.2% when varying friction coefficient from 0 to 1. The impact of the grain angle distortion (α) with respect to longitudinal specimen axis showed its high influence on resulting stiffness and maximal force. It was found that three-point end-notched test is suitable for EPI, MUF, and PRF, while it is less appropriate for a bond with PUR adhesive due to notable plastic behavior.

Wood characterized by desired mechanical properties and wood joining material is essential for creating wooden structures. The polymer adhesives are suitable for such applications due to the possibility of energy dissipation from stresses generated by wooden structures and the elimination of thermal bridging, which are common problems in metal joining materials. This research focuses on the thermophysical properties of the laboratory-prepared flexible and rigid polyurethanes to select an appropriate polymer adhesive. Our results showed that the highest thermal stability was in the case of the new PSTF-S adhesive, which reached 230 °C, but the lowest mass loss in the air environment was around 54% for the PS material. The mean thermal expansion coefficient for F&R PU adhesives was 124–164∙10⁻⁶ K⁻¹. The thermal diffusivity of examined adhesives varied between 0.100 and 0.180 mm²s⁻¹. The thermal conductivity, depending on the type of polyurethane, was in the 0.13–0.29 W∙m⁻¹∙K⁻¹ range. The relative decrease in thermal diffusivity after heating the adhesives to 150 °C was from 2% for materials with the lowest diffusivity to 23% for the PU with the highest value of heat transfer. It was found that such data can be used to simulate wooden construction joints in future research.

Modification of wood improves certain properties of natural wood and presents competitive alternatives to synthetic materials that may have larger environmental impacts. One aspect of modified wood that is currently not fully understood is the dynamic performance and how it is affected by the modification process. In this study, low-molecular weight phenol formaldehyde (PF) resin was applied to Scots pine (Pinus sylvestris L.) and European beech (Fagus sylvatica L.) wood. The effect of this modification was evaluated using a three-point bending test undergoing cyclic loading. Compared to reference samples, modified wood showed higher static performance but revealed a reduction in cyclic fatigue strength (9% for pine and 14% for beech). Cyclic fatigue strength of unmodified wood was found to be 67% of the static modulus of rupture for both species. With PF resin modification, the fatigue strength dropped to 58% for pine and 53% for beech. While fatigue strength decreased, there was no reduction in cyclic modulus or change in the creep rate within the stationary creep phase. It is important to consider the reduction in fatigue strength when using PF modified wood for any construction purposes with expected cyclic loading conditions.

The torrefaction process is widely used in the energy field, but the characteristics of the torrefied wood also have positive effects on the production of wood plastic composites. In this study, short-rotation shrub willow was torrefied at 225 and 300 °C and incorporated into polypropylene composites filled with changing levels of weight percent (wt%) of non-torrefied and torrefied (5, 15, 25, and 40 wt%) wood. Nine different formulations were extruded for mechanical, thermal, and water absorption properties. The tensile properties of composites were not affected by any level of torrefaction, while higher flexure properties were in favor of lower wt% of torrefied wood. The slowest rate of thermal degradation was confirmed for the highest wt% of torrefied wood with a torrefaction temperature of 300 °C. In contrast, the presence of torrefied wood in composites did not show a difference in crystallization or melting temperatures. The most noticeable contribution of torrefaction temperature and wt% was found for water-absorbing properties, where the higher torrefaction temperature and largest wt% of torrefied wood in the composite resulted in decreased water uptake.

Protein-based fish adhesives have historically been used in various bonding applications; however, due to the protein’s high affinity for water absorption, these adhesives become destabilized in high-moisture environments, resulting in reduced bondline strength and early failure. This limitation makes them unsuitable for industrial applications with higher demands. To address this issue, water-insoluble raw powder materials such as iron, copper, or zeolite were incorporated into natural fish adhesives. In this study, the hygroscopicity, dry matter content, thermal analysis (TGA/DSC), FT-IR spectroscopy, surface tension measurements, vapour permeability, and scanning electron microscope (SEM) of the modified adhesives were determined. In addition, the bonding properties of the modified adhesives were evaluated by the tensile shear strength of the lap joints, and mould growth was visually inspected. The resulting modified protein-based adhesives demonstrated improved stability in high humidity environments. Enhancing the hygroscopic properties of protein-based fish adhesives has the potential to unlock new opportunities and applications, providing a healthier and more environmentally sustainable alternative to petroleum-based adhesives.

Single edge-notched three-point bending tests (SEN-TPB) for mode I were utilized to experimentally evaluate fracture properties of adhesive bondlines in European beech (Fagus Sylvatica L.). The bondline was examined at two anatomical planes with TR and RT orientation and at control and two elevated temperatures (70°C and 140°C). Among epoxy (EPI), melamine-urea formaldehyde (MUF), and polyurethane (PUR) adhesives, the highest average critical energy G_c with 0.80 N/mm and fracture energy G_f with 1079.4 N/mm were obtained for EPI in the TR plane and under standard climate conditions (20°C/65% relative humidity), followed by MUF (G_c = 0.50 N/mm and G_f = 620 N/mm) and PUR (G_c = 0.25 N/mm and G_f = 290.9 N/mm), respectively. PUR was least effected by elevated temperature, and no significant differences for G_c and G_f between TR and RT bondline orientations were found for MUF and PUR treated at 20°C/65% relative humidity while comparisons between other factors varied significantly. Treatment of specimens at elevated temperatures resulted in reduced fracture performance regardless of wood grain orientation or the adhesive system.