In order to increase the corrosion resistance of magnesium alloy AZ91 in corrosion environments containing chlorides, the alloy surface has been modified by plasma electrolytic oxidation (PEO). The chemical composition of electrolyte in the PEO process consisted of 12 g/L Na₃PO₄·12 H₂O and 1 g/L KOH, and a direct current was applied to the sample. The corrosion resistance of PEO coating and as-cast AZ91 (sample without PEO coating) was assessed using two different electrochemical methods: electrochemical impedance spectroscopy (EIS) and potentiodynamic polarisation (PDP) in 0.1 M NaCl at laboratory temperature. In addition to the electrochemical methods, the morphology of the oxidic coating was observed in the cross-sectional and top surface view by using the SEM technique. For better determination of the microstructure and PEO coating, chemical composition EDX analysis was used. The results of the experiments show that the formation of the PEO coating on AZ91 alloy has a more positive effect on the corrosion resistance in 0.1 M NaCl based on electrochemical methods than in the case of the formed coating on AZ31 alloy from the previous study. Based on electrochemical measurements in the selected environment, the formation of PEO coating on AZ91 was accompanied by a significant increase in polarisation resistance after short-term exposure compared to the as-cast surface. The EIS results showed a 73 times higher R_p value for PEO coated AZ91 when compared to the as-cast AZ91. Correspondingly, a 27 times lower i_corr value was observed for PEO coated AZ91 than in the case of substrate AZ91 in 0.1 M NaCl. At the same time, the typically porous and inhomogeneous structure of the formed PEO coating on the magnesium alloy AZ91 was demonstrated.

Wrought AZ31 magnesium alloy was used as the experimental material for fluoride conversion coating preparation in Na[BF₄] molten salt. Two coating temperatures, 430 °C and 450 °C, and three coating times, 0.5, 2, and 8 h, were used for the coating preparation. A scanning electron microscope and energy-dispersive X-ray spectroscopy were used for an investigation of the surface morphology and the cross-sections of the prepared coatings including chemical composition determination. The corrosion resistance of the prepared specimens was investigated in terms of the potentiodynamic tests, electrochemical impedance spectroscopy and immersion tests in the environment of simulated body fluids at 37 ± 2 °C. The increase in the coating temperature and coating time resulted in higher coatings thicknesses and better corrosion resistance. Higher coating temperature was accompanied by smaller defects uniformly distributed on the coating surface. The defects were most probably created due to the reaction of the Al_xMn_y intermetallic phase with Na[BF₄] molten salt and/or with the product of its decomposition, BF₃ compound, resulting in the creation of soluble Na₃[AlF₆] and AlF₃ compounds, which were removed from the coating during the removal of the secondary Na[MgF₃] layer. The negative influence of the Al_xMn_y intermetallic phase was correlated to the particle size and thus the size of created defects.

A progressive type of tungsten-doped DLC coating was applied to a quenched and tempered 100Cr6 steel with the aim to improve the wear and corrosion properties in simulated seawater conditions and to compare the performance to conventional DLC coating. Tungsten doping caused a shift of the corrosion potential (E_corr) to a lower negative value of −172 mV, while the conventional DLC exhibited an E_corr of −477 mV. In dry conditions, the W-DLC coefficient of friction is slightly higher than that of the conventional DLC (0.187 for the W-DLC vs. 0.137 for the DLC), but in cases of a saltwater environment, this difference becomes almost negligible (0.105 for the W-DLC vs. 0.076 for the DLC). The conventional DLC coating also started to show marks of deterioration when exposed to a combination of wear in a corrosive environment, while the W-DLC layer still maintained its integrity.

Fatigue tests were performed on the AZ91 cast alloy to identify the mechanisms of the fatigue crack initiation. In different fatigue regions, different mechanisms were observed. In the low and high cycle fatigue regions, slip markings formation accompanied with Mg₁₇Al₁₂ particles cracking were observed. Slip markings act as the fatigue crack initiation sites. The size and number of slip markings decreased with decreased stress amplitude applied. When slip markings formation was suppressed due to low stress amplitude, particle cracking became more important and the cracks continued to grow through the particle/solid solution interface. The change of the fatigue crack initiation mechanisms led the S-N curve to shift to the higher number of cycles to the fracture, demonstrated by its stepwise character. A lower fatigue limit of 60 MPa was determined at 20 kHz for 2 × 10⁹ cycles compared to the 80 MPa determined at 60 Hz for 1 × 10⁷ cycles.

A surface treatment process, composed of plasma electrolytic oxidation (PEO) and sealing by temporary oil preservation system containing corrosion inhibitors, was performed on AZ31 magnesium alloy in order to improve its corrosion resistance i...

Low alloyed steels of low, medium, or high strength are frequently used for many applications in the automotive, civil (bridges), aerospace, and petrochemical industries. A variety of thermomechanical regimes, in which these steels can be produced, enable customization of their matrix with respect to their fatigue resistance, resistance against friction and impact wear, fracture toughness, corrosion resistance, etc. This study analyses the influence of magnetising conditions on Barkhausen noise and other extracted parameters. It was found that the increasing magnetising frequency makes Barkhausen noise weaker, especially in the high strength low alloyed steels, as a result of the decreasing magnetic field in a sample. For this reason, increasing fraction of domain walls is unpinned at the higher frequencies. Barkhausen noise for the high strength low alloyed steels at higher frequencies is remarkably attenuated. Moreover, the different behaviour with respect to direction of the sheet rolling and the transversal direction, can be found due to realignment of the domain walls. This study demonstrates that the position of Barkhausen noise envelopes and the number of Barkhausen noise pulses increase in a systematic manner at the lower magnetising frequencies. Those parameters can be employed for distinction of the low alloyed steels, investigated in this study. However, the increasing magnetising frequency makes attenuation of Barkhausen noise more remarkable for the low alloyed steels of the higher strength. Therefore, the effective value of Barkhausen noise, at the magnetising frequency 750 Hz, in the rolling direction exhibits the systematic descent along with the increasing yield strength. This parameter can be used for distinction of the low alloyed steels after their thermomechanical processing, as well.