Perovskite solar cells (PSCs) leverage the exceptional photoelectric properties of perovskite materials, yet interfacial energy level mismatches limit carrier extraction efficiency. In this work, energy level alignment was exploited to reduce the charge transport barrier, which can be conducive to the transmission of photo-generated carriers and reduce the probability of electron–hole recombination. We designed a dual-transition perovskite solar cell (PSC) with the structure of FTO/TiO₂/Nb₂O₅/CH₃NH₃PbI₃/MoO₃/Spiro-OMeTAD/Au by finite element analysis methods. Compared with the pristine device (FTO/TiO₂/CH₃NH₃PbI₃/Spiro-OMeTAD/Au), the open-circuit voltage of the optimized cell increases from 0.98 V to 1.06 V. Furthermore, the design of a circular platform light-trapping structure makes up for the light loss caused by the transition at the interface. The short-circuit current density of the optimized device increases from 19.81 mA/cm² to 20.36 mA/cm², and the champion device’s power conversion efficiency (PCE) reaches 17.83%, which is an 18.47% improvement over the planar device. This model provides new insight for the optimization of perovskite devices.

In this paper, germanium-based solar cells were designed based on germanium (Ge) materials, and the cross-cone (CC) nanostructures were used as the absorber layer of the solar cells. The optical path inside the absorber layer was increased by microstructure reflection, thereby increasing the absorption efficiency of the germanium-based solar cell. The reflectivity, transmittance, electric field and magnetic field of the corresponding position of the device were simulated and calculated by the finite difference time domain (FDTD) method. By simulating doping and simulating the external potential difference, the short-circuit current density (J_SC), open-circuit voltage (V_OC), output power and photoelectric conversion efficiency (η) of the device were calculated. The study found that for the entire study wavelength range (300–1600 nm), the transmittance of the device was close to none, and the average light absorption rate under air mass 1.5 global (AM1.5G) was 94.6%. In the light wavelength range from 310 nm to 1512 nm with a width of 1201 nm, the absorption rate was greater than 90%, which is in line with the high absorption of the broadband. Among them, the absorption rate at 886 nm reached 99.84%, the absorption rate at 1016 nm reached 99.89%, and the absorption rate at 1108 nm reached 99.997%, which is close to full absorption. By exploring the electrical performance of the device under different Ge nanostructure parameters, a germanium-based solar cell device under the nanocross-cone absorption structure array with both high-efficiency light absorption and excellent electrical performance was finally obtained. The study shows that the V_OC of its single-junction cell was 0.31 V, J_SC reached 45.5 mA/cm², and it had a fill factor (FF) of 72.7% and can achieve a photoelectric conversion efficiency of 10.3%, surpassing the performance of most Ge solar cells today.

Perovskite solar cells (PSCs) still suffer from varying degrees of optical and electrical losses. To enhance the light decoupling and capture ability of Planar PSCs, an ultra-thin PSC structure with an Al₂O₃ pyramid anti-reflection layer (Al₂O₃ PARL) is proposed. The effect of the structure of the Al₂O₃ PARL on the photoelectric performance of PSCs was investigated by changing various parameters. Under the AM1.5 solar spectrum (300–800 nm), the average light absorption rates and quantum efficiency (QE) of PSCs containing pyramid-array textured rear layers (PARLs) were significantly higher than those of planar PSCs. The Al₂O₃ PARL-based PSCs achieved a light absorption rate of 96.05%. Additionally, electrical simulations were performed using the finite element method (FEM) to calculate the short-circuit current density (J_SC), open-circuit voltage (V_OC), and maximum power (Pmax). Based on the maximum value of the average light absorbance, the geometric structure of the Al₂O₃ pyramid PSCs was optimized, and the optimization results coincided with the J_SC and QE results. The results of the electrical simulation indicated that the maximum J_SC was 23.54 mA/cm². Additionally, the J_SC of the Al₂O₃ pyramid PSCs was 22.73% higher than that of planar PSCs, resulting in a photoelectric conversion efficiency (PCE) of 24.34%. As a result, the photoelectric conversion rate of the solar cells increased from 14.01% to 17.19%. These findings suggest that the presence of the Al₂O₃ PARL enhanced photon absorption, leading to an increase in electron–hole pairs and ultimately improving the photocurrent of the solar cells.

In this study, we used the solar cell capacitance simulator (SCAPS) to analyse numerically the performance of perovskite solar cells (PSCs) containing CH₃NH₃PbI₃. The findings indicate that P-N homologous junction processing based on traditional P-I-N PSCs can enhance the photoelectric conversion efficiency (PCE). Furthermore, the authors analyzed the effect of uniform P-N doping of CH₃NH₃PbI₃, concluding that the photoelectric efficiency can be improved from 16.10% to 19.03% after doping. In addition, the optical properties of PSCs under solar irradiation are simulated using finite difference time-domain (FDTD) software under AM1.5. This method is applied to investigate the effect of the P-N uniform junction on the internal electric field generated within the cell. The generation of this electric field promotes carrier separation and transmission, ultimately increasing the open circuit voltage (V_OC) of the solar cell from 1.03 to 1.12 V. The usage of P-N junctions enhances PSCs performance and exhibits vast potential for designing and developing PSCs.

In this paper, the solar absorption level of PEDOT:PSS/Ge organic and inorganic hybrid solar cells (HSCs) with different parameters of cruciform microstructure (CM) is studied, using the finite-difference time domain (FDTD) method. The light absorption in HSCs with CM is above 90% in the range of 300 nm to 1300 nm. Under the AM1.5 solar spectrum, the average absorptivity of solar energy is also at a very high level. At the same time, we use DEVICE software to calculate the electrical properties, such as the open-circuit voltage (V_oc), short-circuit current density (J_sc), and maximum power density (P_max). The electrical simulation results show that the P_max of HSCs with CM improves to 72.16% from the planar HSCs. Besides, in order to study the mechanism of solar energy absorption in HSCs containing CM, the logarithmic plots of electric field intensity of HSCs with CM and planar HSCs, are analyzed at different wavelengths. The work shows that the CM shows an excellent light-trapping effect, which reduces the surface reflectivity of HSCs, and greatly improves the photoelectric conversion efficiency of Ge solar cells.