Mechanical Function of Lignin and Hemicelluloses in Wood Cell Wall Revealed with Microtension of Single Wood Fiber

Chinese fir (Cunninghamia lanceolata (Lamb.) Hook.) has been an important afforestation species in northeast China. It has obvious defects of buckling and cracking easily, which are caused by its chemical components. Trametes versicolor (L.) Lloyd, a white-rot fungus, can decompose the cellulose, hemicellulose, and lignin in the wood. White-rot fungus was used to biologically degrade Chinese fir wood. The effects of different degradation time on the Chinese fir wood’s mechanical properties, micromorphology, chemical components, and crystallinity were studied. The results showed that the heartwood of Chinese fir was more durable than the sapwood and the durability class of Chinese fir was III. Trametes versicolor (L.) Lloyd had a greater influence on the mechanical properties (especially with respect to the modulus of elasticity (MOE)) for the sapwood. Trametes versicolor (L.) Lloyd degraded Chinese fir and colonized the lumen of various wood cell types in Chinese fir, penetrated cell walls via pits, caused erosion troughs and bore holes, and removed all cell layers. The ability of white-rot fungus to change the chemical composition mass fraction for Chinese fir was: hemicellulose > lignin > cellulose. The durability of the chemical compositions was: lignin > cellulose > hemicellulose. The crystallinity of the cellulose decreased and the mean size of the ordered (crystalline) domains increased after being treated by white-rot fungus.

The windmill palm (Trachycarpus fortunei (Hook.) H. Wendl.) is widely distributed and is an important potential source of lignocellulosic materials. The lack of knowledge on the anatomy of the windmill palm has led to its inefficient use. In this paper, the diversity in vascular bundle types, shape, surface, and tissue proportions in the leaf sheaths and stems were studied with digital microscopy and scanning electron microscope (SEM). Simultaneously, fiber dimensions, fiber surfaces, cell wall ultrastructure, and micromechanics were studied with atomic force microscopy (AFM) and a nanoindenter. There is diversity among vascular bundles in stems and leaf sheaths. All vascular bundles in the stems are type B (circular vascular tissue (VT) at the edge of the fibrous sheath (FS)) while the leaf sheath vascular bundles mostly belong to type C (aliform (VT) at the center of the (FS), with the wings of the (VT) extending to the edge of the vascular bundles). In addition, variation among the vascular bundle area and tissue proportion in the radial direction of the stems and different layers of the leaf sheaths is also significant. Microscopically, the fibers in the stem are much wider and longer than that in the leaf sheath. The secondary walls of stem fibers are triple layered while those in the leaf sheath are double layered. The indentation modulus and hardness of the cell wall of leaf sheath fibers are higher than that of the stem. An independent sample t-test also showed a significant difference between stems and leaf sheaths. All this indicates that windmill palm stems and leaf sheaths are two different materials and have different application prospects.

As the most promising biomass material, bamboo has been widely used, but at the same time, it is subject to many problems, such as processing residues and the failure of high-value utilization of residues. In this paper, bamboo powder and polybutylene succinate (PBS) were used as the main raw materials, and by changing the ratio of bamboo powder to PBS and adding polypropylene (PP) or polyethylene (PE) in combination with PBS, the effects of the ratio, as well as the effects of the use of PP and PE, on the physical–mechanical, thermal, and degradation properties of bamboo–plastic composites were investigated, and the microscopic changes of the materials were studied by chemical component analysis. The optimal formulation of bamboo powder/PBS composite material has been identified through experimentation, yielding a flexural strength of 24.87 MPa and a compressive strength of 29.74 MPa. This material can be used for outdoor furniture, wall panels, flooring, road barriers, and other applications, providing a new environmentally friendly approach to the consumption of residual bamboo materials.

The effects of a three-layer structure and age on the mechanical properties of moso bamboo were investigated. The ages of 1-, 3-, and 5-year-old bamboo were chosen to make test samples, and specimens from each age of moso bamboo were divided into three groups (raw bamboo, bamboo removed from outer layer, and bamboo removed from inner layer) for evaluation of modulus of rupture and parallel-to-grain compressive strength. The regression analysis was completed to evaluate the relationship between mechanical properties and bamboo age. The results showed that the age of moso bamboo was positively correlated with the flexural and parallel-to-grain compressive strengths. The mechanical strength of moso bamboo increased with the increased age of moso bamboo. For the moso bamboo with same age, the flexural and parallel-to-grain compressive strengths decreased for the samples without bamboo outer layer. However, for the samples without bamboo inner layer, the parallel-to-grain compressive strength remained unchanged, but the flexural strength increased. The outer layer of bamboo with high toughness and flexibility played an important role during bending. However, the inner layer of bamboo is relatively brittle, which has negative effects on its flexural strength. These results provide an important basis for the bamboo used in engineering.

This study was conducted to evaluate the properties of insulation boards made from bamboo paper sludge and fly ash floating beads. An orthogonal test design was applied to study the effects of certain factors on the properties of the insulation boards. The results indicated that the sequence of significant effect of factors on the properties of the composite boards was particle size of bamboo paper sludge, thickness of boards, and weight ratio of sludge to fly ash floating beads. The verified optimal conditions were confirmed to be 20 to 40 mesh, 80:20, and 14 mm, representing the particle size of bamboo paper sludge, weight ratio of sludge:fly ash floating beads, and thickness of boards, respectively. The thermal conductivity of the bamboo paper sludge and fly ash floating beads insulation boards was measured and suggested that both insulation boards had thermal conductivity values ranging from 0.12 to 0.165 W/mK, which is close to the conventional insulation material lightweight concrete.