In recent years, buried bellows have often had safety accidents such as pipeline bursts and ground subsidence due to the lack of adequate mechanical properties and other quality problems. In order to improve the mechanical properties of bellows, fly ash (FA) was used as a reinforced filler in high density polyethylene (HDPE) to develop composites. The FA was surface treated with a silane coupling agent and HDPE-g-maleic anhydride was used as compatibilizer. Dumbbell-shaped samples were prepared via extrusion blending and injection molding. The cross-section morphology, thermal stability and mechanical properties of the composites were studied. It was observed that when 10% modified FA and 5% compatibilizer were added to HDPE, the tensile yield strength and tensile breaking strength of the composites were nearly 30.2% and 40.4% higher than those of pure HDPE, respectively, and the Young’s modulus could reach 1451.07 MPa. In addition, the ring stiffness of the bellows was analyzed using finite element analysis. Compared with a same-diameter bellows fabricated from common commercially available materials, the ring stiffness increased by nearly 23%. The preparation method of FA/HDPE is simple, efficient, and low-cost. It is of great significance for the popularization of high-performance bellows and the high value-added utilization of FA.
Due to the extremely inert surface of polyester (PET) fabric, a toxic and traditional resorcinol-formaldehyde-latex (RFL) dipping solution is always necessary in the rubber composite industry. Unfortunately, other effective methods for fabric surface treatment are in urgent need to improve the poor bonding interface between the fabric and the rubber matrix. In our study, a facile way to modify PET fabric was developed. Specifically, the fabric was treated by an alkaline solution and a coupling agent with magnetic agitation. Afterwards, the treated fabric/rubber composites were prepared through a co-vulcanization process. Attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), and thermogravimetric analysis (TGA) were used to characterize the surface chemical composition of the modified fabrics. The adhesion behavior was analyzed by the peel test. The results showed that the fabric surface was successfully grafted with a coupling agent, and the peel strength reached 9.8 N/mm after KH550 treatment, which was an increase if 32% compared with that of the original fabric/rubber composite. In addition, the vulcanization rate and interfacial fracture mechanism are also researched.