Co–Mg catalysts for methane combustion were synthesized and studied, revealing the transformation of MgCo₂O₄ spinel into a CoO–MgO solid solution with oxygen release from the spinel lattice as the calcination temperature increased. Repeated heat treatment of the calcined solid solution at lower temperatures led to spinel regeneration with segregation of the solid solution phase. A TPR of the samples showed the presence of two characteristic peaks, the first of which relates to the transition of Co³⁺_Oh spinel to the Co²⁺_Oh structure of CoO, and the second to the reduction of CoO to Co°. The second peak was observed at 540–620 °C for samples calcined at temperatures below spinel decomposition, and for high-temperature samples at 900–1100 °C. Taking into account the identity of the structure of phases obtained in both cases, the formation of not a true CoO–MgO solid solution, but rather a mixture of ordered oxides (“pseudo-solid solution”) in the low-temperature region, was postulated. A study of the activity of the samples showed the high activity of the spinel systems and a linear relationship between the activation energy of methane oxidation and the heat treatment temperature.

Kazakhstan, a fossil-fuel-dependent economy, faces growing pressure to reduce greenhouse gas emissions while maintaining industrial competitiveness. Carbon Capture, Utilization, and Storage (CCS/CCUS) technologies offer a viable pathway for decarbonizing hard-to-abate sectors, particularly in power generation, metallurgy, and oil and gas processing. This paper provides a comprehensive review of the state of CCS/CCUS technologies globally and examines their applicability within Kazakhstan. The study also explores long-term CO₂ storage mechanisms and monitoring frameworks, with attention to carbon leakage risks and the importance of addressing methane emissions. A critical part of the analysis is dedicated to Kazakhstan’s Emissions Trading System, identifying its current limitations such as low carbon prices, and limited sectoral coverage, and outlining practical reforms to enhance its role in supporting CCS/CCUS and broader decarbonization efforts. The integration of CCS/CCUS with a strengthened ETS, combined with access to international climate finance instruments and voluntary carbon markets, is proposed as a key strategy for Kazakhstan’s transition to a low-carbon economy. By linking engineering innovation with targeted policy interventions, this study offers a dual-perspective contribution. It not only provides technical insights into CCS/CCUS technologies but also presents policy recommendations that are specifically tailored to Kazakhstan’s context. The findings reinforce the role of CCS/CCUS as a crucial component of national climate strategy and industrial transformation.

The catalytically active vanadium-containing system of γ-Al₂O₃ was studied using a wide range of physical and chemical methods, depending on the synthesis conditions. It is shown that the vanadium-containing system includes several complexes with different thermal stabilities and catalytic activities. Low-active complexes are destroyed with the formation of more active ones based on V₂O₅ oxide, as the temperature of heat treatment increases. It can be assumed that V₂O₅ oxide has the decisive role in its catalytic activity. It was concluded that the vanadium-containing catalytic system on aluminium oxide, in the studied temperature range, is thermally stable and shows high activity not only in the reduction of nitrogen oxides but also in the oxidation of hydrocarbons (even of the most difficult ones, such as oxidizable methane). These properties of the system make it quite promising in the field of application for the purification of the exhaust gases of motor transport and industrial enterprises with environmentally harmful components, as well as for understanding the mechanism of the action of the catalysts in these processes, which is very important for solving the problems of decarbonization and achieving carbon neutrality.

In order to establish the formation patterns of the Co–Mg oxide system, samples with different Co:Mg ratios and heat treatment temperatures were synthesized and studied. A study of the samples confirmed the phase transition of Mg_xCo_2–xO₄ spinels into the corresponding solid solutions at 800–900 °C. The similarity of the formation patterns for different compositions is shown. The rocksalt oxide in low-temperature samples is an anion-modified paracrystalline phase that forms a “true” solid solution only upon spinel decomposition. The TPR profiles of the decomposed Co₃O₄ spinel show surface Co₃O₄ peaks and a wide peak corresponding to the well-crystallized CoO, while partial Co₃O₄ TPR up to 380 °C results in dispersed and amorphous CoO. The high-temperature non-stoichiometric samples are poorly reduced, indicating their low oxygen reactivity. Spinel reoxidation after heat treatment to 1100 °C by calcination at 750 °C showed complete regeneration for MgCo₂O₄–Co₃O₄ samples and its absence in case of an excess of MgO relative to stoichiometry.