Co–Mg catalysts for methane combustion were synthesized and studied, revealing the transformation of MgCo₂O₄ spinel into a CoO–MgO solid solution with oxygen release from the spinel lattice as the calcination temperature increased. Repeated heat treatment of the calcined solid solution at lower temperatures led to spinel regeneration with segregation of the solid solution phase. A TPR of the samples showed the presence of two characteristic peaks, the first of which relates to the transition of Co³⁺_Oh spinel to the Co²⁺_Oh structure of CoO, and the second to the reduction of CoO to Co°. The second peak was observed at 540–620 °C for samples calcined at temperatures below spinel decomposition, and for high-temperature samples at 900–1100 °C. Taking into account the identity of the structure of phases obtained in both cases, the formation of not a true CoO–MgO solid solution, but rather a mixture of ordered oxides (“pseudo-solid solution”) in the low-temperature region, was postulated. A study of the activity of the samples showed the high activity of the spinel systems and a linear relationship between the activation energy of methane oxidation and the heat treatment temperature.

In order to establish the formation patterns of the Co–Mg oxide system, samples with different Co:Mg ratios and heat treatment temperatures were synthesized and studied. A study of the samples confirmed the phase transition of Mg_xCo_2–xO₄ spinels into the corresponding solid solutions at 800–900 °C. The similarity of the formation patterns for different compositions is shown. The rocksalt oxide in low-temperature samples is an anion-modified paracrystalline phase that forms a “true” solid solution only upon spinel decomposition. The TPR profiles of the decomposed Co₃O₄ spinel show surface Co₃O₄ peaks and a wide peak corresponding to the well-crystallized CoO, while partial Co₃O₄ TPR up to 380 °C results in dispersed and amorphous CoO. The high-temperature non-stoichiometric samples are poorly reduced, indicating their low oxygen reactivity. Spinel reoxidation after heat treatment to 1100 °C by calcination at 750 °C showed complete regeneration for MgCo₂O₄–Co₃O₄ samples and its absence in case of an excess of MgO relative to stoichiometry.

The catalytically active vanadium-containing system of γ-Al₂O₃ was studied using a wide range of physical and chemical methods, depending on the synthesis conditions. It is shown that the vanadium-containing system includes several complexes with different thermal stabilities and catalytic activities. Low-active complexes are destroyed with the formation of more active ones based on V₂O₅ oxide, as the temperature of heat treatment increases. It can be assumed that V₂O₅ oxide has the decisive role in its catalytic activity. It was concluded that the vanadium-containing catalytic system on aluminium oxide, in the studied temperature range, is thermally stable and shows high activity not only in the reduction of nitrogen oxides but also in the oxidation of hydrocarbons (even of the most difficult ones, such as oxidizable methane). These properties of the system make it quite promising in the field of application for the purification of the exhaust gases of motor transport and industrial enterprises with environmentally harmful components, as well as for understanding the mechanism of the action of the catalysts in these processes, which is very important for solving the problems of decarbonization and achieving carbon neutrality.

Iron and chromium based alloys have found wide application in various fields of science and technology. A primary carrier based on Fe-Cr-Al alloy is used in block catalysts for high-temperature hydrocarbon conversion, in production of block metal catalysts for neutralization of toxic gases released during operation of internal combustion engines, as well as those present in smoke emissions from enterprises. The influence of thermal action on Fe-Cr-Al alloy foil and stability of the secondary carrier on its surface was studied. The elemental composition of the surface layer of Fe-Cr-Al alloy foil does not remain constant during heating and depends on the thermal treatment mode. Some of the elements come to surface and the elemental composition of the surface layer can differ significantly from that observed in the bulk of the foil sample. This implies the possibility of changing the adhesive and adsorption properties of the foil surface, as well as the need to take this fact into account when supporting a secondary carrier and active phase to the foil. An applied technique of phosphating and supporting a secondary carrier at the foil surface makes it possible to obtain a sufficiently stable coating. There is no shedding of the secondary carrier from the foil surface during high-temperature treatment in air.

The purpose of this study is to evaluate the feasibility of different oil fields in Kazakhstan for Carbon Capture, Utilization, and Storage (CCUS) projects using advanced algorithms in Python. Using automated methods, the approach greatly simplifies and accelerates the selection process, allowing efficient analysis of large data sets. Taking into account key geological and operational parameters, with particular emphasis on the importance of the Dykstra-Parsons coefficient, the study presents a comprehensive ranking system for evaluating reservoir suitability. This coefficient is critical to accurately assess the fluid displacement efficiency, which significantly influences the selection of candidates for Enhanced Oil Recovery (EOR). The results show that the inclusion of the Dykstra-Parsons coefficient improves the accuracy of field evaluation by accounting for key reservoir heterogeneity factors along with conventional properties. The comparative analysis shows that this approach provides more reliable field selection compared to the existing methods that do not consider this parameter, thereby improving the efficiency of CO2 storage projects.

The composition of hydrocarbon systems plays an essential role in ensuring reliability in field operation processes, the design of oil onshore facilities, and the availability of reliable information about the PVT properties of systems. In this article, experimental and numerical methods are used to obtain data on the component composition of the extracted oil products and their PVT properties. These methods help obtaining a detailed composition and phase state of the hydrocarbon system. The numerical delumping method is utilized in this article. It is worth noting that all calculations were made on the basis of data on the component composition of Kazakhstani oil samples. The results and comparative evaluation show that the proposed delumping mix-method has excellent consistency with the data obtained with experiments and with the Nichita’s analytical approach. In the future, the results on the detailed composition can improve and link the compositional modeling of the reservoir with the modeling of surface structures.