One commonly used lubricant in rolling bearings is grease, which consists of base oil, thickener and small amounts of additives. Commercial greases are mostly produced from petrochemical base oil and thickener. Recently, the development of base oils from renewable resources have been significantly focused on in the lubricant industry. However, to produce an entirely bio-based grease, the thickener must also be produced from renewable materials. Therefore, this work presents the design and evaluation of three different bio-based polymer thickener systems. Tribological tests are performed to characterize lubrication properties of developed bio-based greases. The effect of thickener type on film thickness and friction behavior of the produced bio-based greases is evaluated on a ball-on-disc tribometer. Moreover, the results are compared to a commercial petrochemical grease chosen as benchmark.

Tetranitratoethane (C₂H₂N₄O₁₂), which has an oxygen content of 70.1% was synthesized by nitration of monomeric glyoxal using N₂O₅ and purified by sublimation.

The service life of rolling bearings is significantly affected by the film formation in elastohydrodynamic (EHD) contacts, which depends on the operating conditions, like rotational speed or temperature. In grease lubricated EHD contacts, the film formation is determined by the grease consistency and composition, i.e., thickener and base oil type as well as properties of the bleed oil, which is released from the grease during operation. Thus, the film formation of grease lubricated contacts as compared to base oil lubricated contacts can be different. With increasing rolling speed, the film thickness of oil lubricated contacts usually grows. However, in case of grease lubricated contacts, which are not fully flooded, the film thickness remains constant or even decreases with further increasing rotational speed. This effect is referred to as starvation. Since the onset of starvation depends on the grease composition, the film formation of two different grease compositions is investigated in this study. The film thickness measurements are performed on a ball-on-disc tribometer for each grease, as well as the corresponding bleed and pure base oils. Thereby, the characteristic rotational speed leading to the onset of starvation has been identified in dependence of the grease composition and the differences in the lubricating film formation of base oil, bleed oil, and grease lubricated EHD contacts have been discussed. The investigations should help to establish an advanced understanding of the physical mechanisms leading to the onset of starvation to encourage future work with focus on a method to predict the film formation in grease lubricated EHD contacts.

The service life of rolling bearings is significantly affected by the lubricating film formation in elastohydrodynamic (EHD) contacts. Grease lubricated EHD contacts show a film thickness decay from a characteristic rotational speed, which is referred to as starvation. Thus, the film thickness of grease lubricated contacts differs from that of oil lubricated contacts. However, the base oil properties under fully flooded conditions are commonly assumed to estimate the operating lifetime of grease lubricated bearings, which are usually not fully flooded. Hence, this assumption results in an overestimation of the film thickness for rotational speeds in the range of starvation, which can lead to uncertainties in the bearing design. At high rotational speeds, i.e., high over rolling frequencies, starvation is likely to occur, due to insufficient lubricant supply by replenishment behind the rolling element. Therefore, the focus of this contribution is to investigate the effect of over rolling frequency, and thus replenishment time, on the lubricating film formation in starved, grease lubricated EHD contacts. The film thickness measurements were performed on a ball-on-disc tribometer, which was extended by adding a second ball specimen in front of the measuring ball. By varying the angular distance between the two contacts, the lubricant displacement can be controlled, such that the effect of replenishment time on the film formation can be determined. These investigations should help to establish an advanced understanding of the mechanisms of grease lubrication, and encourage future work with a focus on developing a method to predict the film formation in grease lubricated EHD contacts.