The 2014-2015 Holuhraun eruption in Iceland, emitted ~11 Tg of SO2 into the troposphere over 6 months, and caused one of the most intense and widespread volcanogenic air pollution events in centuries. This study provides a number of source terms for characterisation of plumes in large fissure eruptions, in Iceland and elsewhere. We characterised the chemistry of aerosol particle matter (PM) and gas in the Holuhraun plume, and its evolution as the plume dispersed, both via measurements and modelling. The plume was sampled at the eruptive vent, and in two populated areas in Iceland. The plume caused repeated air pollution events, exceeding hourly air quality standards (350 μg/m3) for SO2 on 88 occasions in Reykjahlíð town (100 km distance), and 34 occasions in Reykjavík capital area (250 km distance). Average daily concentration of volcanogenic PM sulphate exceeded 5 μg/m3 on 30 days in Reykjavík capital area, which is the maximum concentration measured during non-eruptive background interval. There are currently no established air quality standards for sulphate. Combining the results from direct sampling and dispersion modelling, we identified two types of plume impacting the downwind populated areas. The first type was characterised by high concentrations of both SO2 and S-bearing PM, with a high Sgas/SPM mass ratio (SO2(g)/SO42-(PM) >10). The second type had a low Sgas/SPM ratio (<10). We suggest that this second type was a mature plume where sulphur had undergone significant gas-to-aerosol conversion in the atmosphere. Both types of plume were rich in fine aerosol (predominantly PM1 and PM2.5), sulphate (on average ~90% of the PM mass) and various trace species, including heavy metals. The fine size of the volcanic PM mass (75-80% in PM2.5), and the high environmental lability of its chemical components have potential adverse implications for environmental and health impacts. However, only the dispersion of volcanic SO2 was forecast in public warnings and operationally 47 monitored during the eruption. We make a recommendation that sulphur gas-to-aerosol conversion processes, and a sufficiently large model domain to contain the transport of a tropospheric plume on the timescale of days be utilized for public health and environmental impact forecasting in future eruptions in Iceland and elsewhere in the world

The climatic effects of climate engineering—or geoengineering—via cirrus cloud thinning are examined. Thinner cirrus clouds can allow more outgoing longwave radiation to escape to space, potentially cooling the climate. The cloud properties and climatic effects due to perturbing the ice crystal fall speed are investigated in a set of hemispheric scale sensitivity experiments with the Community Earth System Model. It is found that increasing the ice crystal fall speed, as an analog to cirrus cloud seeding, depletes high‐level clouds and reduces the longwave cloud forcing. Deliberate depletion of cirrus clouds increases outgoing longwave radiation, reduces the upper tropospheric water vapor, and cools the climate. Global cirrus cloud thinning gave a net cloud forcing change of −1.55 W m⁻² and a global annual mean temperature change of −0.94 K. Though there is negligible change in the global annual mean precipitation (−0.001 mm/d), the spatially nonhomogeneous forcing induces circulation changes and hence remote climate changes. Climate engineering the Southern Hemisphere only results in a northward shift of the Intertropical Convergence Zone and possible Sahelian drought alleviation, while targeting the Northern Hemisphere alone causes a greater cooling. It was found that targeting cirrus clouds everywhere outside of the tropics results in changes to the circulation and precipitation even in the nonclimate engineered regions, underscoring the risks of remote side effects and indeed the complexity of the climate system.

The 2009 eruption of Redoubt Volcano, Alaska, provided a rare opportunity to compare satellite measurements of sulfur dioxide (SO2) by the Ozone Monitoring Instrument (OMI) with airborne SO2 measurements by the Alaska Volcano Observatory (AVO). Herein we: (1) compare OMI and airborne SO2 column density values for Redoubt's tropospheric plume, (2) calculate daily SO2 masses from Mount Redoubt for the first three months of the eruption, (3) develop simple methods to convert daily measured SO2 masses into emission rates to allow satellite data to be directly integrated with the airborne SO2 emissions dataset, (4) calculate cumulative SO2 emissions from the eruption, and (5) evaluate OMI as a monitoring tool for high-latitude degassing volcanoes. A linear correlation (R2~0.75) is observed between OMI and airborne SO2 column densities. OMI daily SO2 masses for the sample period ranged from ~60.1kt on 24 March to below detection limit, with an average daily SO2 mass of ~6.7kt. The highest SO2 emissions were observed during the initial part of the explosive phase and the emissions exhibited an overall decreasing trend with time. OMI SO2 emission rates were derived using three methods and compared to airborne measurements. This comparison yields a linear correlation (R2~0.82) with OMI-derived emission rates consistently lower than airborne measurements. The comparison results suggest that OMI's detection limit for high latitude, springtime conditions varies from ~2000 to 4000t/d. Cumulative SO2 masses calculated from daily OMI data for the sample period are estimated to range from 542 to 615kt, with approximately half of this SO2 produced during the explosive phase of the eruption. These cumulative masses are similar in magnitude to those estimated for the 1989–90 Redoubt eruption. Strong correlations between daily OMI SO2 mass and both tephra mass and acoustic energy during the explosive phase of the eruption suggest that OMI data may be used to infer relative eruption size and explosivity. Further, when used in conjunction with complementary datasets, OMI daily SO2 masses may be used to help distinguish explosive from effusive activity and identify changes in lava extrusion rates. The results of this study suggest that OMI is a useful volcano monitoring tool to complement airborne measurements, capture explosive SO2 emissions, and provide high temporal resolution SO2 emissions data that can be used with interdisciplinary datasets to illuminate volcanic processes

After more than a year of unrest, a small effusive eruption commenced in Fagradalsfjall, Iceland, on 19 March 2021. The eruption lasted six months. The first six weeks were characterized by multiple fissure openings, and the remainder was dominated by effusive activity from a single crater. During the eruption, lava and low-level gases propagated over the complex terrain: a hyaloclastite massif with mountain peaks up to about 350 m asl with valleys in between. The area is uninhabited, but easily accessible at about 30 km distance from Reykjavík. While the eruption was ongoing, more than 356,000 tourists visited the eruptive site. To maintain low risk access to the area, it was critical to monitor the eruption (including opening of new fissures) in real-time, forecast the transport of gas and lava flow emplacement, and assess the evolving hazards. In addition to data accessibility and interpretation, managing this volcanic crisis was possible thanks to strong collaboration between the scientific institutions and civil protection agencies. The eruption presented an opportunity to tune, test and validate a variety of numerical models for hazard assessment as well as to refine and improve the delivery of information to the general public, communities living near the eruption site and decision makers. The monitoring team worked long hours during both the pre- and syn-eruptive phases for identifying low risk access areas to the eruption site and to provide a regular flow of information. This paper reviews the eruption and its associated hazards. It also provides an overview of the monitoring setup, the adopted numerical tools and communication materials disseminated to the general public regarding current exclusion zones, hazards and possible future eruptive scenarios.