The influence of different replacement ratios of steel-slag powder as cement-replacement material on the fracture performance of concrete is studied in this paper. A three-point bending fracture test is carried out on slag powder-cement-based concrete (SPC)-notched beams with steel-slag powder as cementitious materials, partially replacing cement (0%, 5%, 10%, 15%, and 20%). Load-deflection curves and load-crack-opening displacement curves of SPC-notched beams with five different replacement ratios of steel-slag powder were obtained. The effects of different steel-slag-powder replacement ratios on the fracture properties (fracture energy, fracture toughness, and double-K fracture parameters) of the SPC were analyzed and discussed. The results showed that the incorporation of appropriate steel-slag powder can affect the fracture performance of SPC. Compared with concrete without steel-slag powder, adding appropriate steel-slag powder can effectively improve the bond performance between aggregate and matrix because the steel-slag powder contains hydration activity substances such as calcium oxide and aluminium trioxide. The fracture energy and fracture toughness of SPC increased and then decreased with the increase in steel-slag-powder replacement ratios, and the SPC concrete showed best fracture performance with a 5% steel slag powder replacement ratio. Its fracture energy increases by 13.63% and fracture toughness increases by 53.22% compared with NC.
The application of alkali-activated concrete (AAC) shows promise in reducing carbon emissions within the construction industry. However, the pursuit of enhanced performance of AAC has led to a notable increase in carbon emissions, with alkali activators identified as the primary contributors. In an effort to mitigate carbon emissions, this study introduces Na2CO3 as a supplementary activator, partially replacing sodium silicate. The objective is to develop a low-carbon alkali-activated-strain-hardening-ultra-high-performance concrete (ASUHPC). The experimental investigation explores the impact of varying levels of Na2CO3 replacement quantity (0, 0.75 Na2O%, and 1.5 Na2O%) and activator modulus (1.35, 1.5, and 1.65) on the fresh and hardened properties of ASUHPC. The augmentation of Na2CO3 replacement quantity and activator modulus are observed to extend the setting time of the paste, indicating an increase in the modulus of the activator and Na2CO3 replacement quantity would delay the setting time. While the use of Na2CO3 intensifies clustering in the fresh paste, it optimizes particle grading, resulting in higher compressive strength of ASUHPC. The tensile crack width of ASUHPC conforms to the Weibull distribution. ASUHPC with a Na2CO3 replacement quantity of 0.75 Na2O% exhibits superior crack control capabilities, maintaining a mean crack width during tension below 65.78 μm. The tensile properties of ASUHPC exhibit improvement with increasing Na2CO3 replacement quantity and activator modulus, achieving a tensile strength exceeding 9 MPa; otherwise, increasing the activator modulus to 1.5 improves the deformation capacity, reaching 8.58%. Moreover, it is observed that incorporating Na2CO3 as a supplementary activator reduces the carbon emissions of ASUHPC. After considering the tensile performance indicators, increasing the activator modulus can significantly improve environmental performance. The outcomes of this study establish a theoretical foundation for the design of low-carbon, high-performance-alkali-activated-strain-hardening-ultra—high-performance concrete.
The reuse of coal gangue (CG) and ground-granulated blast furnace slag (GGBFS) to synthesize geopolymers presents a sustainable strategy for industrial waste recycling. This study investigates the influences of various GGBFS/CG mixtures on the mechanical behavior and microstructure of the synthesized geopolymers. Results show that the geopolymer matrix is composed of calcium aluminosilicate (C-(A)-S-H) and sodium aluminosilicate (N-A-S-H) hydrates, which is essential for enhancing the compressive strength of the specimens. With 100% GGBFS, the geopolymer matrix sets in 17 min, reaching a compressive strength of 107.55 MPa after 28 days. As the CG content increases, both compressive strength and compactness decrease gradually, while the setting time prolongs. When the GGBFS/CG mass ratio is 1:1, the specimens’ setting time increases by 64.7% (from 17 to 28 min). The corresponding compressive strengths at 3 days, 7 days, and 28 days are recorded to be 46.73 MPa, 53.25 MPa, and 54.59 MPa, respectively. Specimens with 100% CG exhibit a prolonged setting time (122 min), but the compressive strength is just 21.80 MPa. Microscopic analysis reveals that specimens with 50% CG have smaller average pore diameters (22.84 nm) and a compact microstructure. These findings indicate that the GGBFS content significantly influences geopolymer performance, highlighting the effective utilization of GGBFS/CG wastes.