The aim of this research is the thermostructural study of Cu-Ti, Cu-Ti 1 vol% multiwall carbon nanotubes (MWCNTs) and Cu-Ti 3 vol% MWCNTs. Several investigation techniques were used to achieve this objective. Dilatometric data show that the coefficient of thermal expansion of the nanocomposite containing less multiwall carbon nanotubes is linear and small. The same nanocomposite exhibits regular heat transfer and weak mass exchange with the environment. Raman spectroscopy shows that the nanocomposite with more MWCNTs contains more defects. This implies that the carbon nanotubes have better dispersion in Cu-Ti 1 vol% MWCNTs. Infrared spectroscopy reveals that Cu-Ti 1 vol% MWCNTs has better crystallinity than Cu-Ti 3 vol% MWCNTs.
In the present study, fatigue performance of 6061-T6 and 6082-T6 commercially available extruded aluminum alloys in dry air and 3.5 wt% NaCl-saturated environment was investigated and compared. It was found that the aggressive chloride environment accelerated fatigue failure by up to an order of magnitude compared to laboratory air. Furthermore, alloy 6061-T6 shows more predictable fatigue life, having less scatter in its time to failure in a corrosive environment. The presence of localized pitting corrosion, particularly in Fe-rich intermetallic phases, provides initiation sites for fatigue cracks, leading to premature failure in both alloys. The corrosion fatigue cracks dominantly propagate through the grain interiors rather than along grain boundaries, indicating a tendency to transgranular crack propagation mechanisms. The effect of different loading frequencies (10 Hz and 0.2 Hz) on the corrosion fatigue life of 6061-T6 alloy showed a slightly enhanced fatigue life at the higher frequency. It was also found that alloy 6061-T6 was susceptible to pitting corrosion in NaCl-saturated environments with concentrations ranging between 0.5 wt% and 3.5 wt% without exhibiting significant changes in fatigue life.
Surface morphology and photoluminescence (PL) properties of both microcrystalline cellulose (MCC), microcrystalline powders of the alkali metals nitrites MNO2 (M = Na. K, Cs) (MCN) and two-component composite materials based on the MCC and MCN have been studied and characterized by means of optical microscopy and luminescence spectroscopy.
This paper reviews the relevant literature and covers the main aspects of the environmentally assisted cracking of Al-Mg-Si-(Cu) alloys. Apart from a brief overview of the major microstructural and mechanical properties, it presents research results on the corrosion sensitivity and stress corrosion susceptibility of Al-Mg-Si alloys. Possible mechanisms of stress corrosion cracking and corrosion fatigue in aluminum alloys, such as anodic dissolution and/or interaction with hydrogen, are considered. A number of factors, including atmospheric or solution conditions, applied stress, and material properties, can affect these mechanisms, leading to environmentally assisted cracking. Specific attention is given to Al-Mg-Si alloys with copper, which may increase the sensitivity to intergranular corrosion. The susceptibility to both intergranular corrosion and stress corrosion cracking of Cu-containing Al-Mg-Si alloys is mostly associated with a very thin layer (segregation) of Cu on the grain boundaries. However, the effect of Cu on the corrosion fatigue and fatigue crack growth rate of Al-Mg-Si alloys has received limited attention in the literature. At the current state of the research, it has not yet been holistically assessed, although a few studies have shown that a certain content of copper can improve the resistance of aluminum alloys to the environment with regard to corrosion fatigue. Furthermore, considerations of the synergistic actions of various factors remain essential for further studying environmentally assisted cracking phenomena in aluminum alloys.
1 July 2016 in Surface Engineering and Applied Electrochemistry
This work studies placement and contact features of thermally exfoliated graphite (TEG) particles with different dispersion levels under compression and analyzes the effect of the carbon filler’s...