Per- and polyfluoroalkyl substances (PFAS), also known as forever chemicals, exhibit exceptional chemical stability and resistance to environmental degradation thanks to their strong C-F bonds and nonpolar nature. However, their widespread use and persistence have a devastating impact on the environment. This review examines the roles of PFAS in tribological applications, specifically in lubricants and lubricating systems. This article focuses on conventional and advanced lubricants, including ionic liquids (ILs) and their use in modern automotive vehicles. The objective of this paper is to provide a comprehensive overview of the adverse impacts of PFAS whilst acknowledging their outstanding performance in surface coatings, composite materials, and as additives in oils and greases. The pathways through which PFAS are introduced into the environment via lubricating systems such as in seals and O-rings are identified, alongside their subsequent dispersion routes and the interfaces across which they interact. Furthermore, we examine the toxicological implications of PFAS exposure on terrestrial and aquatic life forms, including plants, animals, and humans, along with the ecological consequences of bioaccumulation and biomagnification across trophic levels and ecosystems. This article ends with potential remediation strategies for PFAS use, including advanced treatment technologies, biodegradation, recovery and recycling methods, and the search for more environmentally benign alternatives.

High-entropy alloys (HEAs) are recognized as a class of advanced materials with outstanding mechanical properties and corrosion resistance. Among these, nickel-based HEAs stand out for their impressive strength, ductility, and oxidation resistance. This review delves into the latest advancements in nickel-containing HEAs, covering their fundamental principles, alloy design strategies, and additive manufacturing techniques. We start by introducing HEAs and their unique properties, emphasizing the crucial role of nickel. This review examines the complex relationships between alloy composition, valence electron concentration (VEC), and the resulting crystal structures. This provides insights into design principles for achieving desired microstructures and mechanical properties. Additive manufacturing (AM) techniques like selective laser melting (SLM), electron beam melting (EBM), and laser metal deposition (LMD) are highlighted as powerful methods for fabricating intricate HEA components. The review addresses the challenges of AM processes, such as porosity, fusion defects, and anisotropic mechanical properties, and discusses strategies to mitigate these issues through process optimization and improved powder quality. The mechanical behavior of AM-processed nickel-based HEAs is thoroughly analyzed, focusing on compressive strength, hardness, and ductility. This review underscores the importance of microstructural features, including grain size, phase composition, and deformation mechanisms, in determining the mechanical performance of these alloys. Additionally, the influence of post-processing techniques, such as heat treatment and hot isostatic pressing (HIP) on enhancing mechanical properties is explored. This review also examines the oxidation behavior of nickel-containing HEAs, particularly the formation of protective oxide scales and their dependence on aluminum content. The interplay between composition, VEC, and oxidation resistance is discussed, offering valuable insights for designing corrosion resistant HEAs. Finally, this review outlines the potential applications of nickel-based HEAs in industries such as aerospace, automotive, and energy, and identifies future research directions to address challenges and fully realize the potential of these advanced materials.

This work examines the micrometer-scale wear behavior of pure Mg and its composites at various loads (100–500 mN) under single and multiple scratch conditions. The Mg-0.4Ce alloy reinforced with nanoparticles of zinc oxide (ZnO) and yttrium oxide (Y₂O₃) is investigated. The effect of reinforcement addition on wear characteristics and the coefficient of friction (COF) was evaluated. Moreover, the influence of number of scratches on wear quantification and wear mechanism was deduced at different loads. The results suggest that both the mechanical and tribological performance of ZnO-reinforced composite is significantly better than that of the Y₂O₃-reinforced composite, which can be attributed to a low COF and higher strengthening due to ZnO addition.