Extinguishing agents are a very important tool in the field of security, both in terms of private and social aspects. Depending on the type of burning substance and place of fire, appropriately prepared and developed solutions should be used. We can distinguish, among others, materials, powders or foaming agents. Modifications introduced into them, including ones based on the achievements in the field of nanotechnology, can improve their safety of use and extend their service life. Such amendments also reduce the costs of production and neutralization of the area after a fire, and increase the fire extinguishing effectiveness. The introduction of nanoparticles allows, e.g., shortening of the fire extinguishing time, reduction of the risk of smoke emission and the toxic substances contained in it, and an increase in the specific surface of particles and thus increasing the sorption of pollutants. The elaborations use metal nanoparticles, e.g., NP-Ag, metal oxides such as NP-SiO₂, as well as particles of substances already present in extinguishing agents but treated and reduced to nanosize. It should be noted, however, that all changes must lead to obtaining a tool that meets the relevant legal requirements and has appropriate approvals.

Increasingly intense changes in climatic conditions and the use of modified materials are causing fires, the consequences of which are increasingly serious for the environment. On one hand, there is the issue of access to water resources. On the other hand, there is the problem of post-fire wastewater, which often contains a mixture of simple inorganic compounds and complex organic molecules, making the removal of pollutants a difficult task requiring innovative approaches. Among these solutions, hydrogels stand out as a promising class of sorption materials. Depending on their synthesis or functionalization, hydrogels can effectively capture contaminants and facilitate the reduction or removal of specific pollutants. This study explores the functionalization of polymeric materials, specifically hydrogels, using microorganisms or bioactive substances to create materials capable of treating water contaminated with hazardous substances generated during firefighting incidents. The possibility of wastewater capture was also taken into account to retain pretreated water at the place of pollutant generation. The analysis covered the potential, conditions, and limitations of using hydrogels in post-fire operations for the effective management of contaminated waters. It was shown that hydrogels, depending on the modification, have the potential to capture wastewater and purify it from both organic and inorganic substances specific to post-fire wastewater. However, it is not possible for a given hydrogel to meet all desired expectations at the same time. Furthermore, modifications that facilitate the optimal performance of certain functionalities may render the others ineffective.

Fires constitute a significant threat due to the pollutants emitted and the destruction they cause. People who take part in firefighting operations must be equipped with appropriate tools, including special clothing that will allow them to work and guarantee safety. One of the threats is represented by compounds from the PAH (Polycyclic Aromatic Hydrocarbons) group, which are characterized by high toxicity and carcinogenicity. Therefore, it is important that the materials used constitute a barrier to contamination. Various materials from which individual elements of special firefighter’s clothing are made were tested. Additionally, the effect of height on the possibility of sorption of PAH compounds on a given type of material was analyzed. Based on the obtained analysis results, it was found that both the type of material and the zone in which the clothing items are used are important in the sorption processes of pollutants. For example, PAHs with high molecular weight are most likely to settle on rubber, i.e., the material from which shoes are made, with the exception of Chrysene, whose presence was found primarily in aramid fibers, i.e., the material from which trousers and jackets are made. However, among PAHs with low molecular weight, compounds such as Methylnaphthalene,1- and Fluorene were sorbed on the rubber surface in large quantities. The only compound that is present in comparable amounts in all materials is Acenaphthylene. Data in this area may be important for taking further actions related to the modification of materials used in special fire brigade clothing and in their cleaning processes.

Fires are among the few processes that significantly impact the state and quality of the environment. Depending on the type and quantity of materials, products, or waste accumulated at a given location, various substances can be released into the environment during a fire. Knowledge of the potential hazards resulting from emission levels allows for appropriate action to be taken and protective measures to be implemented for those present at the scene. Therefore, this article analyzes the composition of emissions depending on the type of material involved in the fire, with particular emphasis on forest fires, substance dumps, and waste disposal sites. An analysis of the available literature revealed the presence of countless toxic organic and inorganic substances, including ultrafine particles and nanoparticles of metals, nonmetals and their compounds, and compounds with long-term toxic and mutagenic effects, such as benzene, polycyclic aromatic hydrocarbons (PAHs), formaldehyde, and 1,3-butadiene. The development of new materials influences the composition of gases and fumes released during fires; therefore, continuous quantitative and qualitative analysis, the development of appropriate analytical tools, and legal requirements are essential.

Metals have a crucial impact on the environment and the economy. They constitute macro- and microelements essential for the proper functioning of living organisms. On the other hand, their excess can pose a life-threatening risk. Of particular economic importance are metals such as Co, Ni, Mn, Ti, Al, Cd, Fe, and Li, which are used, among other things, to build batteries in electric and hybrid cars. In the event of a cell fire, significant amounts of metals are rapidly released into the environment. The magnitude of emissions depends on the type of chemistry used in the battery and the type of extinguishing agent used to extinguish the fire. It should be noted that the available literature only provides information on the total amount or concentration of a given metal in the analyzed samples. However, there is no information on the speciation of metals, including their macro and nano forms, which is crucial for determining the toxicity and biological and chemical activity of a given element.

A review, with 19 refs., of occurrence and purifn. of fire wastewaters. In particular, a negative effect of the waters on environment was taken in consideration. A lack of legal acts necessary for an unambiguous qualification of the fire wastewaters was pointed out.