In recent years, optical fibers have found extensive use in special environments, including high-energy radiation scenarios like nuclear explosion diagnostics and reactor monitoring. However, radiation exposure, such as X-rays, gamma rays, and neutrons, can compromise fiber safety and reliability. Consequently, researchers worldwide are focusing on radiation-resistant fiber optic technology. This paper examines optical fiber radiation damage mechanisms, encompassing ionization damage, displacement damage, and defect centers. It also surveys the current research on radiation-resistant fiber optic design, including doping and manufacturing process improvements. Ultimately, it summarizes the effectiveness of various approaches and forecasts the future of radiation-resistant optical fibers.
Recent advancements in tritium separation technologies have significantly improved efficiency, particularly through the integration of vapor phase catalytic exchange (VPCE), liquid phase catalytic exchange (LPCE), and combined electrolysis catalytic exchange (CECE) methods. Combining these techniques overcomes individual limitations, enhancing separation efficiency and reducing energy consumption. The CECE process, which integrates electrolysis with catalytic exchange, offers high separation factors, making it effective for high-concentration tritiated water treatment. Solid polymer electrolyte (SPE) technology has also gained prominence for its higher efficiency, smaller equipment size, and longer lifespan compared to traditional alkaline electrolysis. While electrolysis offers high separation factors, its high energy demand limits its cost-effectiveness for large-scale operations. As a result, electrolysis is often combined with other methods like CECE to optimize both energy consumption and separation efficiency. Future research will focus on improving the energy efficiency of electrolysis for large-scale, low-cost tritiated water treatment.
Iodine is one of the key elements that must be removed from the off-gas systems of nuclear fuel reprocessing. This study systematically investigates the iodine vapor adsorption performance of the metal–organic framework (MOF) material HKUST-1(1-(2-methyl-4-(2-oxopyrrolidin-1-yl)phenyl)-3-morpholino-5,6-dihydropyridin-2(1H)-one), with particle sizes of 100 nm and 20 μm. HKUST-1 samples with varying particle sizes were synthesized via a hydrothermal method. The experimental results show that the 20 μm HKUST-1 exhibits superior crystallinity, a more intact pore structure, and a higher iodine adsorption capacity, reaching 700 mg/g, which is significantly greater than the 300 mg/g capacity of the 100 nm HKUST-1. Kinetic analysis reveals that the adsorption process follows the pseudo-second-order model, with physical adsorption as the predominant mechanism, where iodine molecules are accommodated within the pores. FTIR and XRD further confirm the structural stability of the HKUST-1 framework after iodine adsorption. However, desorption experiments show that iodine molecules are easily volatilized into the air, with a 20% weight loss observed within 10 h and a color change from black to green. The results provide experimental evidence for optimizing the application of HKUST-1 materials in iodine capture and suggest that material modification could enhance the long-term stability of iodine fixation.
14 January 2025 in Chinese Journal of Chemical Engineering
Continuous dissolution of spent fuel is indeed one of the key technologies that can significantly improve the efficiency and stability of spent fuel reprocessing. The China Institute of Atomic Energy designed a prototype rotary drum dissolver, and the dissolution behavior of UO2 pellets in the dissolver was calculated using the Discrete Element Method. A kinetic equation was established to model the dissolution behavior, considering variables such as temperature, nitric acid concentration, and stirring intensity. The calculations showed that complete pellet dissolution took about 10 h in the continuous reaction, compared to 6 h in the batch dissolution experiment due to the gradual decrease in nitric acid concentration. A 16 h continuous dissolution experiment confirmed the calculated results, with a deviation of 10.8% between the simulation and experiment in terms of the mass of dissolved pellets. It was also found that it takes approximately 30 h to reach equilibrium in the continuous rotary dissolver, with a nitric acid concentration of 2.8 mol/L and a uranium concentration of 243 g/L at equilibrium.
Hydroxylamine nitrate (HAN) and hydrazine nitrate (HN) are commonly found in radioactive waste solutions in nuclear fuel reprocessing, and their efficient removal is essential for waste treatment processes. In this study, six activated carbon carriers were selected to prepare Ru/AC catalysts for the simultaneous catalytic decomposition of HAN and HN, with the aim of exploring the effect of carrier properties on catalytic performance. The catalyst’s activity was evaluated in a batch reaction unit, and its structural properties were characterized using N2 physical adsorption, XRD, SEM, and TEM techniques. The results revealed that the catalyst’s activity was primarily determined by the carrier’s particle size and specific surface area. Additionally, corrosion-induced damage to the pore structure and Ru loss were identified as the main factors responsible for catalyst deactivation. This study highlights the importance of optimizing carrier structure to enhance the activity and stability of Ru/AC catalysts.