Passive radiative cooling technology serves as an energy-free alternative to traditional cooling systems. Porous polymer structures are frequently employed for radiative cooling by leveraging the refractive index mismatch between the polymer and the pores, enabling the scattering of incoming sunlight. Recently, water-soluble and readily available Sodium chloride (NaCl) particles have been utilized as sacrificial templates for sustainable pore creation. Nevertheless, optimizing NaCl particle size, and thus the polymer pore size to enhance scattering capabilities remains a challenge. Here, we report a simple, scalable, and sustainable approach to creating an optimized porous polydimethylsiloxane (PDMS) film. This approach utilizes ultrafine NaCl powders as sacrificial templates, which were synthesized via ultrasonic precipitation to ensure their small size. The ultrafine NaCl particles have a size distribution centered around 6-8 μm, and the as-fabricated porous PDMS film achieves a high thermal emissivity of 0.95 within the atmospheric window (8-13 μm) and exhibits a reflectivity of 0.95 within the visible range (0.4-0.78 μm). Due to the desired dual-spectrum properties, the porous PDMS film exhibits a superior subambient cooling capacity over that fabricated with typically larger NaCl particles under strong sunlight. This study offers a scalable and practical radiative cooling solution for sustainable thermal management.
Multilayer piezoelectric stacks, which are multiple layers of piezoelectric materials placed on top of each other, are widely used to achieve precise linear movement and high-force generation. In this paper, a dynamic stiffness (DS) method for the dynamic vibration analysis of multilayer piezoelectric stacks is presented. First, the general solutions for all physical quantities of the three vibration contributions (i.e., pure vibration, symmetrically coupled vibration, and anti-symmetrically coupled vibration) are derived from the governing equations of motion. Then, the DS matrices of each layer of the piezoelectric stack are obtained, and they are assembled to form a global DS matrix. The electrical impedances and the mode shapes of a piezoelectric stack consisting of two piezoelectric disks connected in series and in parallel are calculated using our method as well as by the finite element method. The comparison shows good agreement. Finally, the effect of the number of layers on the dynamic responses of piezoelectric stacks is investigated. The DS method developed here provides an efficient and accurate analytical tool for the parametric and optimization analysis of the coupled vibrations of multilayer piezoelectric structures.
Given the strong coupling relationship between the Seebeck coefficient and electrical conductivity, achieving a significant increase in the thermoelectric power factor (PF) remains a formidable challenge. Previous studies have demonstrated that the ErAs:InGaAs system has the potential to leverage the energy filtering (EF) effect to enhance the Seebeck coefficient while maintaining high electron concentrations. Here, we present a method that significantly enhances the thermoelectric PF of InGaAs through the dual effects of quantum confinement and EF effects. Density Functional Theory calculations further demonstrate that the alterations in the ErAs band structure induce the EF effect. The results show that the ErAs quantum dots:In0.53Ga0.47As composite films exhibit high electrical conductivity and high Seebeck coefficient in the intermediate temperature range, resulting in a fivefold increase in the PF at 515 K. Our research presents a prospective approach to leveraging the combined effects for the advancement of high-performance thermoelectric materials.