Intertidal sediments are rich in biological resources, which are important for material circulation and energy exchange. Meanwhile, these areas can be treated as sinks as well as sources of coastal heavy metal pollutants. Due to the influence of the tide, the intertidal sediments are in a state of periodic flooding and exposure, and environmental factors such as dissolved oxygen, salinity and overlying water pressure are changeable. Heavy metals in sediments are prone to migration and transformation with the dynamic effects of tidal water and the changes in the environment factors, which increase the bioavailability of heavy metals. In this review, the characteristics of distribution and the bioavailability of heavy metals in intertidal sediments are described; the migration and transformation behavior of heavy metals and its influencing factors under tidal conditions are analyzed; and the mechanisms of heavy metal’s migration and transformation in the intertidal zone are summarized. Moreover, the bioaccumulation of heavy metal by organisms and the remediation techniques are discussed. Therefore, this review systematically summarizes the states of existence, the transport mechanisms, and the fate of heavy metals in the intertidal sediment, fills in the research gap of the cycling of heavy metal in the intertidal zone, and provides a theoretical basis for the control of heavy metal pollution.
The unreasonable development and pollution of groundwater have caused damage to the groundwater system and environmental problems. To prevent this, the concept of “groundwater vulnerability” was proposed, and various evaluation methods were developed for groundwater protection. However, with changing climatic conditions and human activities, groundwater vulnerability is now emphasizing physical processes. This study aims to review and analyze the principles and applications of process-based groundwater vulnerability methods to achieve the source protection of groundwater resources. It introduces the assessment method and elaborates on pollutant migration processes and numerical simulation technology. Relevant articles from the past 30 years are reviewed to show the evolution of process-based groundwater vulnerability assessment. The study also discusses current research trends and proposes future development paths. It concludes that process-based groundwater vulnerability assessment will become the mainstream method, and modern technologies such as artificial intelligence will be necessary to solve challenges and achieve sustainable development.
The nitrate pollution of groundwater can cause serious harm to human health. Biochar electrodes, combined with adsorption and electroreduction, have great potential in nitrate removal from groundwater. In this study, bamboo chopsticks were used as feedstocks for biochar preparation. The bamboo chopstick biochar (BCBC), prepared by pyrolysis at 600 °C for 2 h, had a specific surface area of 179.2 m2/g and an electrical conductivity of 8869.2 μS/cm, which was an ideal biochar electrode material. The maximum nitrate adsorption capacity of BCBC-600-2 reached 16.39 mg/g. With an applied voltage of 4 V and hydraulic retention time of 4 h, the nitrate removal efficiency (NRE) reached 75.8%. In comparison, the NRE was only 32.9% without voltage and 25.7% with graphite cathode. Meanwhile, the average nitrate removal rate of biochar electrode was also higher than that of graphite cathode under the same conditions. Therefore, biochar electrode can provide full play to the coupling effect of adsorption and electroreduction processes and obtain more powerful nitrate removal ability. Moreover, the biochar electrode could inhibit the accumulation of nitrite and improve the selectivity of electrochemical reduction. This study not only provides a high-quality biochar electrode material, but also provides a new idea for nitrate removal in groundwater.
In this pilot study, the performance of an “ultrafiltration (UF) + nanofiltration (NF)” advanced treatment process in improving drinking water quality was investigated. The membrane performance and effluent qualities of three commercial NF membranes (Dow Filmtec NF270-400, VONTRON TAPU-LS, and GE Osmonics-HL8040F 400) were evaluated, and the reasons for the difference in effluent quality of these three NF membranes were analyzed. The results showed that UF as a pretreatment process could provide NF with stable and qualified influent. After passing through the UF unit, the turbidity of raw water decreased by 88.6%, and the SDI value was less than 3. Due to the small pore size of NF membranes, organics and polyvalent ions in raw water were further removed. With a water recovery of 90%, the conductivity, chemical oxygen demand (CODMn), and hardness of NF effluent are significantly improved. The three commercial NF membranes showed different performance advantages. Among them, Dow Filmtec NF270-400 had the best desalting performance, VONTRON TAPU-LS had the highest retention rate of organic matter, and GE Osmonics-HL8040F 400 had significantly advanced softening performance. Thanks to the combination of the UF membrane and NF membrane, membrane fouling was effectively inhibited, and drug consumption was within an acceptable range. The operation costs of these three NF membranes were 0.165, 0.179, and 0.171 USD per ton of produced water, respectively. The results showed that the UF + NF process is an ideal technology for advanced treatment in water plants.
Frequent changes in the tide levels in estuaries cause constant changes in the hydraulics of fish passage systems, with important effects on successful fish passage and swimming behavior. In most cases, Japanese eels often have low passage rates in engineered fishways because of their special habits. In this study, we established a 1:4 scaled-down weir-hole combination bulkhead fishway, studied the effects of different tidal differences and water depths on the passage rates and swimming behavior of yellow-phase Japanese eels, and analyzed the response of the Japanese eels to the hydraulic factors by superimposing their swimming trajectories and the flow field simulation results. We found that the passage rate of the eels decreased from 68.18% to 50.00% and 45.45% under extreme high tide differences and extreme low tide differences, respectively. The eels tended to use the low-velocity area to climb up the wall, and when crossing the mainstream, the yellow-phase Japanese eels preferred the area with a flow velocity of 0.1~0.36 m/s and a turbulent kinetic energy range of 0.001~0.007 m2/s2. Their upstream swimming speed was maintained at a range of 0.1~0.3 m/s.
Aiming at establishing the transient flow characteristics of gas–liquid two-phase flow in high-undulation water pipelines, based on the bubble distribution law measured using physical tests, the bubble distribution law function was input into the hump-pipe fluid domain model, and CFD numerical simulation was carried out for different flow rates and different air contents. The CLSVOF two-phase flow model and the RNG k-ε turbulence model were used to analyze the flow pattern evolution and pressure pulsation propagation in the process of gas–liquid two-phase flow through a hump pipe. The results show that the bubble size has a lognormal distribution, the equivalent diameter is between 3 mm and 10 mm, and the evolution of the flow pattern in the hump pipe is complex and violent. In the horizontal pipe section, there are three main flow patterns: bubble flow, wavy flow and segment plug flow. In the vertical pipe, there are two main flow patterns, slug flow and churning flow, and the flow pattern is affected by the flow rate and the air content rate. When air bubbles or air pockets in the pipeline flow through a certain area, this leads to a steep increase and decrease in the pressure pulsation amplitude in the region, and the pressure fluctuation is extremely frequent. Compared with the water flow rate, the air content is the main factor affecting the relative pressure pulsation amplitude under the condition of a 0.15-air content operating mode, which is generally approximately two to six times that of the 0-air content operating mode. The results of the research should facilitate the prediction of stagnant gas pipeline system bursts and water hammer protection, providing a theoretical basis and calculation parameters.