The International Maritime Organization (IMO) Marine Environment Protection Committee (MEPC) and some countries have gradually strengthened the laws regulating ship exhaust emissions. The aim of this paper is to estimate the impact of an after-treatment technology exhaust gas cleaning (EGC) system on marine diesel engine emissions and the cost advantage compared to using low-sulfur fuel oil. The emission characteristics of SO₂ and particulate matter (PM) produced from high sulfur oil and low sulfur oil in a low-speed two-stroke marine diesel engine were also presented. The removal efficiency of SO₂ has been tested and the PM removal efficiency was also predicted in this study. When using high sulfur oil, the emission factor of SO₂ and PM were from 8.73 g/kWh to 11.6 g/kWh and 2.0 g/kWh to 2.7 g/kWh, respectively. These values are significantly higher than the emission values from using low sulfur oil. The fuel sulfur content (FSC) was the key factor affecting the emission factors of SO₂ and PM. The fuel change could reduce the mass emission factor of PM, which is above 90% for the total particle emission with the two fuels. When using the EGC system, the desulfurization efficiencies were above 99%. The pH values at a 25, 39, 53, and 67% load were also stabilized to be around 7.5, 7.6, 7.7, and 8, respectively. The EGC system can also capture part of the primary PM and secondary PM formed from SO₂. The EGC system was more effective for PM of the size larger than 1 μm. Thus, according to this study, the usage of low sulfur oil and EGC will also substantially decrease the emission of currently unregulated hazardous chemical species in the exhaust gas of ships in addition to satisfying future emissions regulations of ship. Furthermore, the EGC system also had a significant cost advantage compared to using low-sulfur fuel oil.

PM (particulate matter) emissions from ships are the main sources of marine atmosphere pollution. Controlling the emissions of particulate matter from ships is related to the sustainable development of the shipping industry. To reduce PM emissions from marine four-stroke diesel engines, DPFs are effective. Our results show that DPF had more than 90% capturing efficiency for both the number and mass emissions of PM, and the capturing efficiency for the accumulation mode was higher than that of the nuclear mode. DPF can also significantly reduce the chemical components of PM in marine diesel exhaust gas. The removal efficiencies for OC and EC were 89.7–91.6% and 84.8–92.8%, respectively, with each particle size range showing over 80% efficiency. SO₄²⁻ was the ion with the highest content, followed by NH₄⁺, NO₃⁻, Na⁺, NO₂⁻, and Cl⁻, with their reduced proportions remaining consistent with the removal efficiency of particulate matter. DPF can also effectively reduce PAH content and toxicity. The use of DPF can greatly improve the impact of ship emissions on the marine atmospheric environment. The appropriate DPF with the best performance can be selected according to the exhaust parameters and particle size distributions with different characteristics.