In February 2017 the “Carbonaceous Aerosol in Rome and Environs (CARE)” experiment was carried out in downtown Rome to address the following specific questions: what is the color, size, composition, and toxicity of the carbonaceous aerosol in the Mediterranean urban background area of Rome? The motivation of this experiment is the lack of understanding of what aerosol types are responsible for the severe risks to human health posed by particulate matter (PM) pollution, and how carbonaceous aerosols influence radiative balance. Physicochemical properties of the carbonaceous aerosol were characterised, and relevant toxicological variables assessed. The aerosol characterisation includes: (i) measurements with high time resolution (min to 1–2 h) at a fixed location of black carbon (eBC), elemental carbon (EC), organic carbon (OC), particle number size distribution (0.008–10 $\mathsf{\mu }$ m), major non refractory PM₁ components, elemental composition, wavelength-dependent optical properties, and atmospheric turbulence; (ii) 24-h measurements of PM₁₀ and PM_2.5 mass concentration, water soluble OC and brown carbon (BrC), and levoglucosan; (iii) mobile measurements of eBC and size distribution around the study area, with computational fluid dynamics modeling; (iv) characterisation of road dust emissions and their EC and OC content. The toxicological assessment includes: (i) preliminary evaluation of the potential impact of ultrafine particles on lung epithelia cells (cultured at the air liquid interface and directly exposed to particles); (ii) assessment of the oxidative stress induced by carbonaceous aerosols; (iii) assessment of particle size dependent number doses deposited in different regions of the human body; (iv) PAHs biomonitoring (from the participants into the mobile measurements). The first experimental results of the CARE experiment are presented in this paper. The objective here is to provide baseline levels of carbonaceous aerosols for Rome, and to address future research directions. First, we found that BC and EC mass concentration in Rome are larger than those measured in similar urban areas across Europe (the urban background mass concentration of eBC in Rome in winter being on average 2.6 ± 2.5 $\mathsf{\mu }$ g · m ${}^{-3}$ , mean eBC at the peak level hour being 5.2 (95% CI = 5.0–5.5) $\mathsf{\mu }$ g · m ${}^{-3}$ ). Then, we discussed significant variations of carbonaceous aerosol properties occurring with time scales of minutes, and questioned on the data averaging period used in current air quality standard for PM ${}_{10}$ (24-h). Third, we showed that the oxidative potential induced by aerosol depends on particle size and composition, the effects of toxicity being higher with lower mass concentrations and smaller particle size. Albeit this is a preliminary analysis, findings reinforce the need for an urgent update of existing air quality standards for PM ${}_{10}$ and PM ${}_{2.5}$ with regard to particle composition and size distribution, and data averaging period. Our results reinforce existing concerns about the toxicity of carbonaceous aerosols, support the existing evidence indicating that particle size distribution and composition may play a role in the generation of this toxicity, and remark the need to consider a shorter averaging period (<1 h) in these new standards.

The Mediterranean is recognized among the most responsive regions to climate change, with annual temperatures projected to increase by 1–5 °C until 2100. Large cities may experience an additional stress discomfort due to the Urban Heat Island (UHI) effect. In the present study, the WRF-ARW numerical weather prediction model was used to investigate the climate change impact on UHI for two Mediterranean cities, Rome and Thessaloniki. For this purpose, three 5-year time-slice simulations were conducted (2006–2010, 2046–2050, 2096–2100) under the Representative Concentration Pathway (RCP) 8.5 emission scenario, with a spatial resolution of 2 km. In order to comprehensively investigate the urban microclimate, we analyze future simulation data across sections crossing urban/non-urban areas, and after grouping them into three classes depending on the location of the grid cells. The urban areas of both cities present increased average minimum temperature (T_min) in winter/summer compared to other rural areas, with an UHI of ~+1.5–3 °C on average at night/early morning. Considering UHI under future climate change, we found no significant variations (~±0.2 °C). Finally, we found that the numbers of days with T_min ≥ 20 °C will mostly increase in urban coastal areas until 2100, while the largest increase of minimum Discomfort Index (DI_min) is expected in urban low-ground areas.

Wherever a loose bed of sand is subject to sufficiently strong winds, aeolian dunes form at predictable wavelengths and growth rates. As dunes mature and coarsen, however, their growth trajectories become more idiosyncratic; nonlinear effects, sediment supply, wind variability and geologic constraints become increasingly relevant, resulting in complex and history-dependent dune amalgamations. Here we examine a fundamental question: do aeolian dunes stop growing and, if so, what determines their ultimate size? Earth’s major sand seas are populated by giant sand dunes, evolved over tens of thousands of years. We perform a global analysis of the topography of these giant dunes, and their associated atmospheric forcings and geologic constraints, and we perform numerical experiments to gain insight on temporal evolution of dune growth. We find no evidence of a previously proposed limit to dune size by atmospheric boundary layer height. Rather, our findings indicate that dunes may grow indefinitely in principle; but growth depends on morphology, slows with increasing size, and may ultimately be limited by sand supply.

The mixing-layer height is estimated using measurements from a high resolution surface-layer sodar run at the French-Italian station of Concordia at Dome C, Antarctica during the summer 2011–2012. The temporal and spatial resolution of the sodar allows the monitoring of the mixing-layer evolution during the whole diurnal cycle, i.e. a very shallow nocturnal boundary layer followed by a typical daytime growth. The behaviour of the summer mixing-layer height, variable between about 10- and 300 m, is analyzed as a function of the mean and turbulent structure of the boundary layer. Focusing on convective cases only, the retrieved values are compared with those calculated using a one-dimensional prognostic equation. The role of subsidence is examined and discussed. We show that the agreement between modelled and experimental values significantly increases if the subsidence is not kept fixed during the day. A simple diagnostic equation, which depends on the time-averaged integral of the near-surface turbulent heat flux, the background static stability and the buoyancy parameter, is proposed and evaluated. The diagnostic relation performance is comparable to that of the more sophisticated prognostic model.

The RHAPS (Redox-Activity And Health-Effects Of Atmospheric Primary And Secondary Aerosol) project was launched in 2019 with the major objective of identifying specific properties of the fine atmospheric aerosol from combustion sources that are responsible for toxicological effects and can be used as new metrics for health-related outdoor pollution studies. In this paper, we present the overall methodology of RHAPS and introduce the phenomenology and the first data observed. A comprehensive physico-chemical aerosol characterization has been achieved by means of high-time resolution measurements (e.g., number size distributions, refractory chemical components, elemental composition) and low-time resolution analyses (e.g., oxidative potential, toxicological assays, chemical composition). Preliminary results indicate that, at the real atmospheric conditions observed (i.e., daily PM₁ from less than 4 to more than 50 μg m⁻³), high/low mass concentrations of PM₁, as well as black carbon (BC) and water soluble Oxidative Potential (WSOP,) do not necessarily translate into high/low toxicity. Notably, these findings were observed during a variety of atmospheric conditions and aerosol properties and with different toxicological assessments. Findings suggest a higher complexity in the relations observed between atmospheric aerosol and toxicological endpoints that go beyond the currently used PM₁ metrics. Finally, we provide an outlook to companion papers where data will be analyzed in more detail, with the focus on source apportionment of PM₁ and the role of source emissions on aerosol toxicity, the OP as a predictive variable for PM₁ toxicity, and the related role of SOA possessing redox-active capacity, exposure-response relationships for PM₁, and air quality models to forecast PM₁ toxicity.