Catalytic methane decomposition (CMD) is a highly promising approach for the rational production of relatively CO_x-free hydrogen and carbon nanostructures, which are both important in multidisciplinary catalytic applications, electronics, fuel cells, etc. Research on CMD has been expanding in recent years with more than 2000 studies in the last five years alone. It is therefore a daunting task to provide a timely update on recent advances in the CMD process, related catalysis, kinetics, and reaction products. This mini-review emphasizes recent studies on the CMD process investigating self-standing/supported metal-based catalysts (e.g., Fe, Ni, Co, and Cu), metal oxide supports (e.g., SiO₂, Al₂O₃, and TiO₂), and carbon-based catalysts (e.g., carbon blacks, carbon nanotubes, and activated carbons) alongside their parameters supported with various examples, schematics, and comparison tables. In addition, the review examines the effect of a catalyst’s shape and composition on CMD activity, stability, and products. It also attempts to bridge the gap between research and practical utilization of the CMD process and its future prospects.

We report on the synthesis and testing of active and stable nano-catalysts for methane oxidation. The nano-catalyst was palladium/ceria supported on alumina prepared via a one-step solution-combustion synthesis (SCS) method. As confirmed by X-ray photoelectron spectroscopy (XPS) and high-resolution transmission electron microscopy (HTEM), SCS preparative methodology resulted in segregating both Pd and Ce on the surface of the Al₂O₃ support. Furthermore, HTEM showed that bigger Pd particles (5 nm and more) were surrounded by CeO₂, resembling a core shell structure, while smaller Pd particles (1 nm and less) were not associated with CeO₂. The intimate Pd-CeO₂ attachment resulted in insertion of Pd ions into the ceria lattice, and associated with the reduction of Ce⁴⁺ into Ce³⁺ ions; consequently, the formation of oxygen vacancies. XPS showed also that Pd had three oxidation states corresponding to Pd⁰, Pd²⁺ due to PdO, and highly ionized Pd ions (Pd^(2+x)+) which might originate from the insertion of Pd ions into the ceria lattice. The formation of intrinsic Ce³⁺ ions, highly ionized (Pd²⁺ species inserted into the lattice of CeO₂) Pd ions (Pd^(2+x)+) and oxygen vacancies is suggested to play a major role in the unique catalytic activity. The results indicated that the Pd-SCS nano-catalysts were exceptionally more active and stable than conventional catalysts. Under similar reaction conditions, the methane combustion rate over the SCS catalyst was ~18 times greater than that of conventional catalysts. Full methane conversions over the SCS catalysts occurred at around 400 °C but were not shown at all with conventional catalysts. In addition, contrary to the conventional catalysts, the SCS catalysts exhibited superior activity with no sign of deactivation in the temperature range between ~400 and 800 °C.

Due to ever-increasing global warming, the scientific community is concerned with finding immediate solutions to reduce or utilize carbon dioxide (CO₂) and convert it in useful compounds. In this context, the reductive process of CO₂ methanation has been well-investigated and found to be attractive due to its simplicity. However, it requires the development of highly active catalysts. In this mini-review, the focus is on biochar-immobilized nanocatalysts for CO₂ methanation. We summarize the recent literature on the topic, reporting strategies for designing biochar with immobilized nanocatalysts and their performance in CO₂ methanation. We review the thermochemical transformation of biomass into biochar and its decoration with CO₂ methanation catalysts. We also tackle direct methods of obtaining biochar nanocatalysts, in one pot, from nanocatalyst precursor-impregnated biomass. We review the effect of the initial biomass nature, as well as the conditions that permit tuning the performances of the composite catalysts. Finally, we discuss the CO₂ methanation performance and how it could be improved, keeping in mind low operation costs and sustainability.

Due to the ever increasing global warming, the scientific community is concerned with finding immediate solutions to reduce or utilize carbon dioxide (CO2) and convert it in useful compounds. In this context, the reductive process of CO2 methanation is well investigated and attractive due to its simplicity. However, it requires the development of highly active catalysts. In this mini-review, the focus is on biochar-immobilized nanocatalysts for CO2 methanation. We summarize the recent literature on the topic, reporting strategies for the design of biochar with immobilized nanocatalysts and their performances in CO2 methanation. We review the thermochemical transformation of biomass into biochar and its decoration with CO2 methanation catalysts. We also tackle direct methods of obtaining biochar-nanocatalysts, in one pot, from nanocatalyst precursor-impregnated biomass. We review the effect of the initial biomass nature, as well as the conditions that permit to tune the perfomances of the composite catalysts. Finally, we discuss the CO2 methanation performances and how they could be improved keeping in mind low operation cost and particularly sustainability.