Effects of rare earth (La+Ce) on inclusions in hot-rolled band of 3.0∼3.3%Si-0.8∼1.0%Al non-oriented silicon steel was studied using industrial trials, scanning electron microscope (SEM) and thermodynamic analysis. Furthermore, combining Heterogeneous Nucleation Theory with Edge-to-Edge Matching (E2EM) model, the formation mechanism of complex inclusions was also investigated. Rare earth (La+Ce) would promote the spheroidization and coarsening of inclusions, and then transform into regular and near circle morphology composite inclusions of rare earth. The low content of rare earth (21 ppm) mainly deoxidized and modified Al₂O₃ inclusions, and formed (La,Ce)AlO₃ inclusions. Increasing of rare earth (29–45 ppm) would promote the formation of (La,Ce)AlO₃-(La,Ce)₂O₂S and (La,Ce)₂O₂S inclusions, reduce the sulfide precipitation, and promote a gradual transformation of the core of composite inclusions from (La,Ce)AlO₃ to (La,Ce)AlO₃-(La,Ce)₂O₂S and (La,Ce)₂O₂S, which agreed well with the thermodynamic analysis. However, rare earth (29–45 ppm) had a weak metamorphic effect on Al₂O₃ inclusions generated by temperature drop and secondary oxidation. LaAlO₃, CeAlO₃, La₂O₂S and Ce₂O₂S could be the heterogeneous nucleation core of AlN, Al₂O₃, MgO-Al₂O₃, typical composite inclusions with (La,Ce)AlO₃ and (La,Ce)₂O₂S as the core would ultimately form.

The cold-rolled non-oriented silicon steel sheets with a Si content of 2.4 wt.%, produced by continuous and reversible cold rolling, were used as the experimental material. The effects of annealing temperature on the microstructure, texture, and magnetic properties were studied by optical microscopy, an X-ray diffractometer, and a magnetic property measuring instrument. The experimental results showed that the dominant texture components at the surface of both sheets were almost the same, i.e., α and γ fibers. After annealing at 920 °C for 30 s, a complete recrystallization occurred in both sheets. When annealing below 1070 °C, the average grain sizes of continuous cold-rolled sheets were slightly higher than those of reversible cold-rolled ones. Additionally, for all specimens, the recrystallization texture components were γ fiber, as well as weak α fiber, λ fiber, and Goss texture. Additionally, the difference was the texture intensity. The iron losses of the finished products of continuous cold rolling were lower than those of the finished products of reversible cold rolling with the increase in annealing temperature, and the magnetic induction was higher than that of the finished products of reversible cold rolling.

The effects of Cu content on the microstructure, texture, precipitates, and magnetic and mechanical properties of 0.20 mm-thick non-oriented silicon steel (3.0% Si-0.8% Al-0.5% Mn) were systematically investigated using optical microscopy, X-ray diffraction, electron backscatter diffraction, and transmission electron microscopy. The strengthening mechanisms of Cu-bearing high-strength non-oriented silicon steel were further elucidated. Increasing Cu content inhibited grain growth and suppressed the development of the α*-fiber texture in annealed sheets, while promoting the formation of γ-fiber texture. As a result, the P_1.0/400 and B₅₀ values deteriorated. The P_1.0/400 and B₅₀ values of 1.47% Cu non-oriented silicon steel were 13.930 W/kg and 1.614 T, respectively. However, due to the solid solution strengthening effect of 0.5% Cu and partial precipitation strengthening, the R_p0.2 increased by 43 MPa. After aging treatment at 550 °C for 20 min, the P_1.0/400 values of the aged sheets slightly increased, while the B₅₀ values remained almost unchanged. In the aged sheets containing 1.0–1.5% Cu, clustered Cu-rich precipitates with average sizes of 2.71 nm and 13.28 nm were observed. The crystal structure of these precipitates transitioned from the metastable B2-Cu to the stable FCC-Cu. These precipitates enhanced the R_p0.2 of the non-oriented electrical steel to 241 MPa and 269 MPa through cutting and bypass mechanisms, respectively. A high-strength non-oriented silicon steel with balanced magnetic and mechanical properties was developed for driving motors of new energy vehicles by utilizing nanoscale Cu-rich precipitates formed through aging treatment. The optimized steel exhibits a yield strength of 708 MPa, a magnetic induction B₅₀ of 1.639 T, and high-frequency iron loss P_1.0/400 of 14.77 W/kg.