In the rapidly evolving field of human-machine interfaces (HMIs), high-resolution wearable electronic skin (e-skin) is essential for user interaction. However, traditional array-structured tactile interfaces require increased number of interconnects, while soft material–based computational methods have limited functionalities. Here, we introduce a thin and soft e-skin for tactile interfaces, offering high mapping capabilities through electrical impedance tomography (EIT). We employed an organic/inorganic hybrid structure with simple, cost-effective fabrication processes, ensuring flexibility and stability. The conductive and stretchable sensing domain includes a micropatterned multiwall carbon nanotube and elastomer composite. The skin-like tactile interface effectively detects pressure-induced conductivity changes, offering superior spatiotemporal resolution with fewer interconnects (pixel/interconnects >57). This EIT-based tactile interface discerns external pressures to a submillimeter degree and vertical deformations of a few hundred micrometers. It sustains stable functions under external damage or environmental changes, confirming its suitability for persistent wearable use. We demonstrate practical applications in real-time HMIs: handwriting recognition and drone control.
Silane coupling agents (SCAs) with different organofunctional groups were coated on the surfaces of Al2O3 ceramic particles through hydrolysis and condensation reactions, and the SCA-coated Al2O3 ceramic particles were dispersed in a commercial photopolymer based on interpenetrating networks (IPNs). The organofunctional groups that have high radical reactivity and are more effective in UV curing systems are usually functional groups based on acryl, such as acryloxy groups, methacrloxy groups, and acrylamide groups, and these silane coupling agents seem to improve interfacial adhesion and dispersion stability. The coating morphology and the coating thickness distribution of SCA-coated Al2O3 ceramic particles according to the different organofunctional groups were observed by FE-TEM. The initial dispersibility and dispersion stability of the SCA-coated Al2O3/High-temp composite solutions were investigated by relaxation NMR and Turbiscan. The rheological properties of the composite solutions were investigated by viscoelastic analysis and the mechanical properties of 3D-printed objects were observed with a nanoindenter.
Oxygen functionalized carbon nanotubes synthesized by surface acid treatment were used to improve the dispersion properties of active materials for catalysis. Carbon nanotubes have gained attention as a support for active materials due to their high specific surface areas (400–700 m2 g−1) and chemical stability. However, the lack of surface functionality causes poor dispersion of active materials on carbon nanotube supports. In this study, oxygen functional groups were prepared on the surface of carbon nanotubes as anchoring sites for decoration with catalytic nanoparticles. The oxygen functional groups were prepared through a chemical acid treatment using sulfuric acid and nitric acid, and the amount of functional groups was controlled by the reaction time. Vanadium, tungsten, and titanium oxides as catalytic materials were dispersed using an impregnation method on the synthesized carbon nanotube surfaces. Due to the high density of oxygen functional groups, the catalytic nanoparticles were well dispersed and reduced in size on the surface of the carbon nanotube supports. The selective catalytic reduction catalyst with the oxygen functionalized carbon nanotube support exhibited enhanced NOx removal efficiency of over 90% at 350–380 °C which is the general operating temperature range of catalysis in power plants.
Laser‐induced graphene (LIG) is a porous carbon nanomaterial that can be produced by irradiation of CO2 laser directly on the polymer substrate under ambient conditions. LIG has many merits over conventional graphene, such as simple and fast synthesis, tunable structure and composition, high surface area and porosity, excellent electrical and thermal conductivity, and good flexibility and stability. These properties make LIG a promising material for energy applications, such as supercapacitors, batteries, fuel cells, and solar cells. In this review, we highlight the recent advances of LIG in energy materials, covering the fabrication methods, performance enhancement strategies, and device integration of LIG‐based electrodes and devices in the area of hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, zinc‐air batteries, and supercapacitors. This comprehensive review examines the potential of LIG for future sustainable and efficient energy material development, highlighting its versatility and multifunctionality in energy conversion.
Under acidic conditions, IrO2 exhibits high catalytic activity with respect to the oxygen evolution reaction (OER). However, the practical application of Ir-based catalysts is significantly limited owing to their high cost in addition to the scarcity of the metal. Therefore, it is necessary to improve the efficiency of the utilization of such catalysts. In this study, IrO2-coated Ti felt (IrO2/Ti) electrodes were prepared as high-efficiency catalysts for the OER under acidic conditions. By controlling the surface roughness of the Ti substrate via wet etching, the optimum Ti substrate surface area for application in the IrO2/Ti electrode was determined. Additionally, the IrO2 film that was electrodeposited on the 30 min etched Ti felt had a large surface area and a uniform morphology. Furthermore, there were no micro-cracks and the electrode obtained (IrO2/Ti-30) exhibited superior catalytic performance with respect to the OER, with a mass activity of 362.3 A at a potential of 2.0 V (vs. RHE) despite the low Ir loading (0.2 mg cm−2). Therefore, this proposed strategy for the development of IrO2/Ti electrodes with substrate surface control via wet etching has potential for application in the improvement of the efficiency of catalyst utilization with respect to the OER.