Natural gas hydrates represent a promising clean energy source with vast reserves. Their efficient development is crucial for ensuring the sustainable advancement of human society. However, wellhead instability occurred in the long-term development, which poses a significant challenge that impacts its commercial development. In the present work, the properties of hydrate-bearing sediments were experimentally investigated. It was found that the elastic modulus, cohesion, and internal friction angle of hydrate-bearing sediments exhibit an increase with the effective stress. As an example, when the effective stress increases from 0 MPa to 25 MPa, the normalized elastic modulus exhibits a rise from 1.00 to 1.36. Conversely, the Poisson’s ratio, permeability, and porosity demonstrate a decline in accordance with this trend. As an example, both normalized porosity and permeability decrease to values below 0.40 as the effective stress increases to 25 MPa. Based on the experimental results and previous work, a comprehensive model for describing the effect of both hydrate saturation and effective stress on physical parameters was obtained. Subsequently, a multi-field coupled investigation methodology was developed to evaluate wellhead stability during the long-term development of hydrate-bearing sediments, and the evolution characteristics and mechanisms of wellhead instability were numerically explored. It reveals that development operation using the vertical wellbore decomposes hydrates in the surrounding sediments only within a radius of 19.52 m, which significantly undermines the wellhead stability. Moreover, the wellhead system not only sinks with sediment subsidence but also experiences additional sinking due to the failure of bonding between the wellhead system and sediments. Furthermore, the latter accounts for a significant portion, amounting to approximately 68.15% of the total sinking under the research conditions. This study can provide methodological prerequisites for exploring the impact of various factors on wellhead stability during the long-term hydrate development process.

Water-based fracturing fluid has recently garnered increasing attention as an alternative oilfield working fluid for propagating reservoir fractures and transporting sand. However, the low temperature resistance and stability of water-based fracturing fluid is a significant limitation, restricting the fracture propagation and gravel transport. To effectively ameliorate the temperature resistance and sand-carrying capacity, a modified cross-linker with properties adaptable to varying reservoir conditions and functional groups was synthesized and chemically characterized. Meanwhile, a multifunctional collaborative progressive evaluation device was developed to investigate the rheology and sand-carrying capacity of fracturing fluid. Utilizing molecular dynamics simulations, the thickening mechanism of the modified cross-linker and the sand-carrying mechanism of the fracturing fluid were elucidated. Results indicate that the designed cross-linker provided a high viscosity stability of 130 mPa·s and an excellent sand-carrying capacity of 15 cm² at 0.3 wt% cross-linker content. Additionally, increasing reservoir pressure exhibited enhanced thickening and sand-carrying capacities. However, a significant inverse relationship was observed between reservoir temperature and sand-carrying capacity, attributed to changes in the drag coefficient and thickener adsorption. These results verified the effectiveness of the cross-linker in enhancing fluid viscosity and sand-carrying capacity as a modified cross-linker for water-based fracturing fluid.

The depleted gas reservoirs can serve not only as sites for CO$_2$ sequestration but also as potential spaces for hydrogen storage. However, this process remains insufficiently investigated and thus cannot offer reliable technical support for the injection operations. In this study, a mathematical model for simulating hydrogen storage in depleted gas reservoirs was developed and numerically solved. Meanwhile, the applicability was then verified through comparison with results from previous studies. Based on this model, a detailed analysis was performed to investigate the evolution of key parameters under specific injection conditions. Finally, the effects of various factors on parameters such as hydrogen distribution and maximum pore pressure during the hydrogen injection process were thoroughly discussed. It was found that hydrogen gradually drives the CH$_4$ and CO$_2$ outward from the near-wellbore region, leading to increases in both bottom-hole pressure and pore pressure during hydrogen injection. Furthermore, as the injection progresses, the spatial extent of hydrogen distribution expands nonlinearly, and the buffering effects of CH$_4$ and CO$_2$ become prominent. Sensitivity analysis further reveals that, although low permeability-induced high pore pressure poses sealing challenges, limited hydrogen storage space within reservoir is beneficial for further hydrogen recovery. Meanwhile, a moderate increase in the injection rate can enhance storage efficiency without compromising reservoir sealing integrity. In contrast, extending the length of wellbore section used for hydrogen injection does not lead to a significant improvement in storage performance.

Natural gas hydrates are a promising alternative energy source for oil and gas in the future. However, geomechanical issues, such as wellhead instability, may arise, affecting the safe and efficient development of hydrates. In the present work, a sensitivity analysis was performed on sediment subsidence and wellhead instability during the development of marine hydrates using a multi-field coupled model. This is accomplished by adjusting the corresponding parameters based on the basic data of the default case. Meanwhile, the corresponding influencing mechanisms were explored. Finally, design recommendations for operation parameters were proposed based on the research findings regarding wellhead stability. It was found that the wellhead undergoes rapid sinking during a certain period in the early stage of hydrate development, followed by a slower, continued sinking. The sensitivity analysis found that when the depressurization amplitude is small, the wellhead sinking is also minimal. To maintain wellhead stability during the development process, it is recommended that neither the depressurization amplitude or drawdown pressure exceed 3.0 MPa. Although a high heating temperature can increase gas production to some extent, the accompanying excessive hydrate dissociation may compromise the stability of both the formation and wellhead. To balance gas production and wellhead stability, it is recommended that the heating amplitude does not exceed 50 °C. In addition, the permeability influences the distribution of pore pressure, which in turn affects sediment subsidence and wellbore stability. Wellhead stability deteriorates as permeability increases. Therefore, it is crucial to accurately determine the reservoir characteristics (such as permeability) before developing hydrates to avoid wellhead instability. Finally, the investigation results reveal that using different versions of the investigation model can impact the accuracy of the results, and neglecting certain physical fields may lead to an underestimation of the wellhead sinking.

To mitigate the influence of wellbore heat transfer on the physicochemical properties of water-based fracturing fluids in the high-temperature environments of low-permeability shale reservoirs, this study investigates the fluid filtration behavior of water-based fracturing fluids within the wellbore under such reservoir conditions. A wellbore heat-transfer model based on solid–liquid coupling was constructed in order to analyse the effects of different reservoir and wellbore factors on fluid properties (viscosity and filtration volume) in the water-based fracturing fluids. Concurrently, boundary conditions and control equations were established for the numerical model, thereby delineating the heat-transfer conditions extant between the water-based fracturing fluid and the wellbore. Furthermore, molecular dynamics theory and microgrid theory were utilised to elucidate the mechanisms of the alterations of the fluid properties of the water-based fracturing fluids due to wellbore heat transfer in low-permeability shale reservoirs. The findings demonstrated that wellbore heat transfer in low-permeability shale reservoirs exerts a pronounced influence on the fluid viscosity and filtration volume of the water-based fracturing fluids. Parameters such as wellbore wall thickness, heat-transfer coefficient, radius, and pressure differential introduce distinct variation trends in these fluid properties. At the microscopic scale, the disruption of intermolecular hydrogen bonds and the consequent increase in free molecular content induced by thermal effects are the fundamental mechanisms driving the observed changes in viscosity and fluid filtration. These findings may offer theoretical guidance for improving the thermal stability of water-based fracturing fluids under wellbore heat-transfer conditions.