This study investigates the effects of varying CuO doping concentrations on the performance of titanium dioxide (TiO₂)-based or zinc oxide (ZnO)-based dye-sensitized solar cells (DSSCs). TiO₂ or ZnO mixed with CuO at different weight percentages (0–50 wt %) was employed as photoanodes in DSSCs, prepared via mechanical mixing. X-ray diffraction analysis revealed the structural changes, showing that as the CuO content increased in the hybrid, the CuO peaks (notably at 35.5° and 38.7°) became more prominent. Morphological and elemental characterizations were conducted using SEM and XRF, respectively. The solar cells were photosensitized by Vitis lasbrusca (V.L.) extract and N3 dye. The presence of anthocyanin molecules in the extracted V.L. was confirmed using UV-VIS and FTIR spectroscopy. The electrochemical characterization demonstrated optimal solar conversion efficiencies at a 20% doping level for both photosensitizers. Specifically, in the V.L. dye, TiO₂-CuO achieved a conversion efficiency of 7.18%, and ZnO-CuO reached 5.77%. In the N3 dye, TiO₂-CuO showed an efficiency of 11.34%, and ZnO-CuO, 9.55%. Notably, undoped photoanodes displayed a significantly lower photovoltaic performance: for V.L. dye, TiO₂ showed 1.12% and ZnO 0.87%; for N3 dye, TiO₂ showed 6.02% and ZnO 4.39%. Doping was therefore effective, yielding up to a seven-fold increase in performance in the case of V.L. with TiO₂, compared to undoped DSSCs. The results demonstrate that using the hybrid photoanode led to a considerable increase in performance compared to using only TiO₂ or ZnO photoanodes, highlighting the potential of DSSCs as sustainable energy sources.

This work addresses the implementation of the co-sensitization technique to increase the energy efficiency of organic dye-sensitized solar cells (DSSCs). Fluorescent dyes derived from boron complexes— (BORANIL) and (BODIPY)— were successfully synthesized and used as co-sensitizers in different volume percentage ratios to verify the most effective concentration for photon capture through these sensitizers. The dyes were optically characterized using ultraviolet–visible spectroscopy (UV-VIS) and Fourier transform infrared (FTIR), analyzing them through the optical performance of each hybrid combination of dyes, an optimization of the photon collection capacity in the tests performed in a volume percentage ratio of 25:75 or 1:3. The morphology and surface roughness of the electrodes were analyzed using scanning electron microscopy (SEM) and atomic force microscopy (AFM), respectively. Through electrochemical characterizations, it was found that the highest photovoltaic conversion efficiency was obtained with the ATH1005 (D) dye mixed with ATH032 (G) in the proportion of 25%:75% or DG 1:3, with efficiency (η) of 3.45%, against 2.43% and 1.90% for DG 1:1 and DG 3:1 cells, respectively. Cells with BODIPY dyes also present higher conversion efficiencies compared to BORANIL cells. The results corroborate the presentation of organic solar cells as a viable option for electricity generation.

This study investigated the enhancement of photovoltaic efficiency of dye-sensitized solar cells (DSSCs) through titanium dioxide (TiO ₂ ) anodes composite with iron oxide (Fe ₂ O ₃ ). TiO ₂ with Fe ₂ O ₃ at different weight percentages (0–30 wt%) were employed as photoanodes in DSSCs, prepared via mechanical mixing. Natural dyes extracted from Chrysanthemum violet and Alstroemeria flower petals were used as sensitizers, with platinum (Pt) cathode being employed to facilitate the photocatalytic process. The electronic excitation and molecule vibration characteristics of the dye molecules were investigated by UV-Vis and FTIR spectroscopy, respectively. For the analysis of the photovoltaic parameters, electrochemical characterizations were performed. The performances of the Chrysanthemum violet dye-sensitized cells with 10%, 20%, and 30% composite were 3.24%, 5.25%, and 4.15%, respectively, compared to 1.35% for the mere TiO ₂ cells. Similarly, the photovoltaic conversion yields of the Alstroemeria dye-sensitized cells were 3.54%, 6.33%, and 5.74%, while the mere TiO ₂ cells showed 1.74%. In both cases, composite with 20% Fe ₂ O ₃ resulted in the highest efficiency. The findings indicate that this doping technique substantially improves the performance of DSSCs, reaching up to four times the efficiency compared to the mere TiO ₂ cells. These results are promising and reinforce the potential of DSSCs in sustainable electricity production.