The generation of a nickel-reduced, stainless spring steel strip with a thickness of 0.2 mm, producible under industrial conditions, is the aim of a transfer project together with the Institute of Metal Forming/TU BAF and the Auerhammer Metallwerk GmbH within the DFG Collaborative Research Centre (CRC) 799. The spring steel strip should exhibit a tensile strength of ≥1700 MPa in work-hardened and partitioned state. The mechanical and corrosive properties of the steel strip should be equal or better than those given for 1.4310 steel (AISI 301). The article presents the results of laboratory alloys focused on the design of steel strips, which meet the requirements for a cost-effective production. The results presented relate to steel design, microstructure formation, temperature-dependent mechanical properties, and corrosion resistance. Four alloys of the type X5CrMnNiMoN16-x-4 with manganese contents of approximately 2 to 6 wt.-percent were investigated. The austenitic steel X5CrMnNiMoN16-4-4 with TRIP/TWIP effect was selected for deformation and partitioning treatments. Its deformation-induced α’-martensite formation significantly contributes to the work hardening of the steel. A short-time annealing treatment (partitioning) further increases the strength properties.
This study focuses on the effect of pre-deformation on hydrogen diffusion and hydrogen embrittlement of the high alloy austenitic TRIP steel X3CrMnNiMo17-8-4. Different cold-rolled steel sheets with thicknesses of ≤400 µm were electrochemically charged on both sides in 0.1 M sodium hydroxide with hydrogen for two weeks. Comparative measurements on uncharged and immersed samples prove that hydrogen causes embrittlement in this steel for all investigated states. The embrittlement increases with increasing pre-deformation and is accompanied by deformation-induced martensite formation. The corresponding fractured surfaces were examined using electron microscopy and compared to modelled hydrogen distributions with previously determined diffusion coefficients. For this purpose, various diffusion coefficients are determined using the Devanathan–Stachurski permeation test and hot extraction in order to describe the diffusion process. The hydrogen concentration profiles and the fractographic analyses show a good agreement, so this study provides a basis for estimating the embrittlement behaviour for later application.
The accumulation of copper in steel scrap is becoming an increasingly problematic issue in the steelmaking industry. Accordingly, the present study was undertaken to investigate the removal of copper from a liquid Fe–Cu alloy via tapping under vacuum. Furthermore, the impact of surface-active components sulfur and oxygen was examined. For this purpose, four Fe–0.5 wt% Cu alloys with varying oxygen and sulfur contents were melted and subsequently poured at a pressure of 100 Pa. The findings indicate that alloys with low oxygen and sulfur content exhibited enhanced copper evaporation. Additionally, the evaporation of other tramp metals, including manganese, phosphorus, and tin, was observed, and the influence of sulfur and oxygen on this process was discussed. Furthermore, the vacuum treatment conditions for copper evaporation in industrial settings were explored.