On the evening of 5 April 2014, at a building located on 122 Tomis Boulevard, Constanta Municipality, Constanta County, Romania, a restaurant with its kitchen on the ground floor and a lounge bar located on the first floor experienced a fire, one that resulted in four victims and total building destruction. An important step in the technical-scientific expertise was the investigation of the incident based on the elaboration of two fire scenarios using the Fire Dynamic Simulator (FDS) model, which observed the fire propagation, the generation of toxic gases (carbon monoxide that disoriented and intoxicated the victims, three of whom could not save themselves) depending on the location of the plausible ignition sources, and explained the destructive effects. This paper focuses on the steps required to identify the critical conditions that led to the occurrence of the unwanted event. Based on the calculations, hypothesis, and FDS simulations, the mechanism of the event occurrence was considered to be strongly related to the onsite observations and criminal file issued by the state authorities.

Methane is one of the most common gaseous fuels that also exist in nature as the main part of the natural gas, the flammable part of biogas or as part of the reaction products from biomass pyrolysis. In this respect, the biogas and biomass installations are always subjected to explosion hazards due to methane. Simple methods for evaluating the explosion hazards are of great importance, at least in the preliminary stage. The paper describes such a method based on an elementary analysis of the cubic law of pressure rise during the early stages of flame propagation in a symmetrical cylindrical vessel of small volume (0.17 L). The pressure–time curves for lean, stoichiometric and rich methane–air mixtures were recorded and analyzed. From the early stages of pressure–time history, when the pressure increase is equal to or less than the initial pressure, normal burning velocities were evaluated and discussed. Qualitative experiments were performed in the presence of a radioactive source of ⁶⁰Co in order to highlight its influence over the explosivity parameters, such as minimum ignition energy, maximum rate of pressure rise, maximum explosion pressure and normal burning velocity. The results are in agreement with the literature data.

The dust cloud is the main form of existence of combustible dust in the production area and together with the existence of effective ignition sources are the main causes of dust explosions in production processes. The minimum ignition temperature has an important role in the process of selecting the explosion-protected electrical equipment when performing the explosion risk assessment of combustible dusts. The heated surfaces are able to ignite the dust clouds that can form in process industry. The oil products usually contain hydrogen sulfide and thus on the pipe walls iron sulfides can form, which can be very dangerous from health and safety point of view. In order to study the influence of the pyrophoric sulfide over the minimum ignition temperature of combustible dusts for this work were performed several experiments on a residue collected from the oil pipes contaminated with commercially iron sulfide.

In the present paper, the use of programmable microprocessors to develop a computerized stand for the preparation of a mixture of flammable/toxic/explosive gases in order to obtain mixtures at concentrations in explosive range is presented. The operating principle of the stand is based on the mixing of two volumetric flows, controlled with the help of microprocessors, where gases are stored and circulated at atmospheric pressure through cylindrical injectors, driven by stepper motors so that the gas circuit does not require valves. The exit of the stand is a homogenization chamber, with agitator and sensor to confirm the desired concentration of the mixture. This automated stand eliminates mechanical, electric or pneumatic valves from the gas circuits, avoiding elements with high mechanical resistance suitable for high pressures/depressions, removing the possibility of the return of the gas flow, without sensitivity to sudden pressures variations.

Although the accidental or intentional explosions produced in industrial facilities or in urban areas are events with low probability, they have a high destructive potential and potential for human injuries and/or fatalities. One of the types of such events is given by detonation of improvised explosive devices (IEDs)—dirty bombs for terrorist purposes—which may produce a high number of metallic fragments. Studying mass and spatial distributions of these fragments is useful for evaluating their lethality and destructive potential and may help to implement adequate protective measures. This work brings a closer insight into the fragment dispersion around the detonation of a steel-enclosed C4 charge with cylindrical symmetry. In this respect a specific approach involving both detonation experiments and numerical simulations performed by home-made and commercial software packages for investigation of the fragmentation process and accompanying angular scattering of the fragments was proposed. Special algorithms, which allow the estimation of the spatial distributions of fragments from the numerical analysis of perforations made by the metallic fragments generated by such IEDs on surrounding material walls, are developed. Further, numerical simulations of a similar IED device provided output parameters related to the statistical distributions of mass, kinetic energy and position of the fragments. Experimental fragmentation generated a recovered mass distribution (94 fragments of 67.5 g) that was compared with that extracted from simulation, revealing a reasonable agreement on the 0.3–1 g range. In the case of simulations, 300 fragments from a total number of 374 showed a mass ranging from 0.004 to 0.3 g. The simulations showed that the middle part of the steel case generated fragments of kinetic energy over 4 kJ and its ends generated fragments of kinetic energy under 1 kJ. Experimental fragment scattering distributions were investigated with specific home-made numerical algorithms, which, based on a set of images, analysed the correlations between spatial coordinates of perforations made by fragments on surrounding special panels and provided histograms that are discussed in relation with the fragment-induced lethality degree.

Polyurethane foam (PF) is a versatile polymer widely used in various applications. By changing the composition of polyol and isocyanate, these foams can be classified into rigid polyurethane foams (PUFRs) and flexible polyurethane foams (PUFFs). The flexible polyurethane foam (PUFFs) is well known for its sound absorption capacities; nevertheless, its flammability poses significant safety hazards. The purpose of this study is to look into how flexible polyurethane foam reacts to fire, specifically its combustion properties, and the risks that come with them. The study aims to find out the rates of horizontal and vertical burning, the make-up of the reaction products, and the temperatures that build up inside the polyurethane foam mass when a support pole is placed in front of the stage and sound-absorbing material is added to stop stage sounds from reverberating. There were performed experiments to determine the fire behavior of the samples in contact with an ignition source in the form of a small flame and experiments to determine the ignition temperature of the sound-absorbing sponge, where it was found that vertical position accelerates combustion, and in practical applications, this aspect must be considered for fire prevention. To determine the combustion gases, several methods were used, namely spectrophotometric, ion chromatography, and gas-chromatographic methods. Analysis of the gases resulting from the combustion of the sound-absorbing sponge indicates the presence of dangerous toxic compounds (hydrogen cyanide, carbon monoxide, and hydrochloric acid), which can endanger human health in the event of a fire.