A new application of Fe-Mn-Si based shape memory alloys (SMAs) was developed under the form of truncated cone-shaped module, for self-adaptive axial preload control in angular contact bearings. The modules were processed by high-speed high-pressure torsion (HS-HPT), from circular crowns cut from axially drilled ingots of Fe-28Mn-6Si-9Cr (mass%) SMA. The specimens were mechanically tested in the hot rolled state, prior to HS-HPT processing, demonstrating free-recovery shape memory effect (SME) and high values for ultimate tensile stress and strain as well as low cycle fatigue life. The HS-HPT modules were subjected to static loading–unloading compression, without/with lubrication at specimen-tool interface, both individually and in different coupling modes. Dry compression cycles revealed reproducible stress plateaus both during loading and unloading stages, being associated with hardness gradient, along cone generator, caused by HS-HPT processing. Constrained recovery tests, performed using compressed modules, emphasized the continuous generation of stress during heating, by one way SME, at a rate of ∼9.3 kPa/%. Dynamic compression tests demonstrated the capability of modules to develop closed stress–strain loops after 50 000 cycles, without visible signs of fatigue. HS-HPT caused the fragmentation of crystalline grains, while compression cycles enabled the formation of ε hexagonal close-packed stress-induced martensite ( ε ), which is characterized by a high density of stacking faults. Using an experimental setup, specifically designed and manufactured for this purpose, both feasibility and functionality tests were performed using HS-HPT modules. The feasibility tests proved the existence of a general tendency of both axial force and friction torque to increase in time, favoured by the increase of initial preloading force and the augmentation of rotation speed. Functionality tests, performed on two pairs of HS-HPT modules fastened in base-to-base coupling mode, demonstrated the capacity of modules to accommodate high preloads while maintaining both axial force and friction torque at constant values in time. These preliminary results suggest that, for the time being, the modules can operate only as single use applications, more effective during the running-in period. This bevahior recommends HS-HPT modules as a new application of Fe-Mn-Si SMAs, with the potential to be used for the development of new temperature-responsive compression displacement systems.

From commercial pellets of recycled polyethylene terephthalate glycol (R-PETG), 1.75 mm diameter filaments for 3D printing were produced. By varying the filament’s deposition direction between 10° and 40° to the transversal axis, parallelepiped specimens were fabricated by additive manufacturing. When bent at room temperature (RT), both the filaments and the 3D-printed specimens recovered their shape during heating, either without any constraint or while lifting a load over a certain distance. In this way, free-recovery and work-generating shape memory effects (SMEs) were developed. The former could be repeated without any visible fatigue marks for as much as 20 heating (to 90 °C)-RT cooling–bending cycles, while the latter enabled the lifting of loads over 50 times heavier than the active specimens. Tensile static failure tests revealed the superiority of the specimens printed at larger angles over those printed at 10°, since the specimens printed at 40° had tensile failure stresses and strains over 35 MPa and 8.5%, respectively. Scanning electron microscopy (SEM) fractographs displayed the structure of the successively deposited layers and a shredding tendency enhanced by the increase in the deposition angle. Differential scanning calorimetry (DSC) analysis enabled the identification of the glass transition between 67.5 and 77.3 °C, which might explain the occurrence of SMEs in both the filament and 3D-printed specimens. Dynamic mechanical analysis (DMA) emphasized a local increase in storage modulus of 0.87–1.66 GPa that occurred during heating, which might explain the development of work-generating SME in both filament and 3D-printed specimens. These properties recommend 3D-printed parts made of R-PETG as active elements in low-price lightweight actuators operating between RT and 63 °C.

Active elements made of Ti₅₀Ni₄₅Cu₅ shape memory alloy (SMA) were martensitic at room temperature (RT) after hot rolling with instant water quenching. These pristine specimens were subjected to two thermomechanical training procedures consisting of (i) free recovery shape memory effect (FR-SME) and (ii) work generating shape memory effect (WG-SME) under constant stress as well as dynamic bending and RT static tensile testing (TENS). The structural-functional changes, caused by the two training procedures as well as TENS were investigated by various experimental techniques, including differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), X-ray diffraction (XRD), and atomic force microscopy (AFM). Fragments cut from the active regions of trained specimens or from the elongated gauges of TENS specimens were analyzed by DSC, XRD, and AFM. The DSC thermograms revealed the shift in critical transformation temperatures and a diminution in specific absorbed enthalpy as an effect of training cycles. The DMA thermograms of pristine specimens emphasized a change of storage modulus variation during heating after the application of isothermal dynamical bending at RT. The XRD patterns and AMF micrographs disclosed the different evolution of martensite plate variants as an effect of FR-SME cycling and of being elongated upon convex surfaces or compressed upon concave surfaces of bent specimens. For illustrative reasons, the evolution of unit cell parameters of B19′ martensite, as a function of the number of cycles of FR-SME training, upon concave regions was discussed. AFM micrographs emphasized wider and shallower martensite plates on the convex region as compared to the concave one. With increasing the number of FR-SME training cycles, plates’ heights decreased by 84–87%. The results suggest that FR-SME training caused marked decreases in martensite plate dimensions, which engendered a decrease in specific absorbed enthalpy during martensite reversion.

In the present study, the capacity of two commercial NiTi and NiTiCu shape memory alloy (SMA) wires to develop work-generating (WG) and constrained-recovery (CR) shape memory effects (SMEs), as well as the capacity of a commercial NiTiFe super-elastic wire to act as cold-shape restoring element, have been investigated. Using differential scanning calorimetry (DSC), the reversible martensitic transformation to austenite of the three NiTi-based wires under study was emphasized by means of an endothermic minimum of the heat flow variation with temperature. NiTi and NiTiCu wire fragments were further tested for both WG-SME and CR-SME developed during the heating, from room temperature (RT) to different maximum temperatures selected from the DSC thermograms. The former tests revealed the capacity to repetitively lift various loads during repetitive heating, while the latter tests disclosed the repetitive development of shrinkage stresses during the repetitive heating of elongated wires. The tensile behavior of the three NiTi-based SMA wires was analyzed by failure and loading–unloading tests. The study disclosed the actuation capacity of NiTi and NiTiCu shape memory wires, which were able to develop work while being heated, as well as the resetting capacity of NiTiFe super-elastic wires, which can restore the initial undeformed shape of shape memory wires which soften while being cooled down. These features enable the design of a robotic gripper based on the development of NiTi-based actuators with repetitive action.

One of the useful features of 3D-printed specimens of recycled polyethylene terephthalate glycol (R-PETG) is the ability to repetitively develop free recovery as well as the work-generating, shape-memory effect. This behavior is enabled by the R-PETG’s capacity to stiffen during cooling, thus allowing for a new temporary shape to be induced. Aiming to devise an explanation for the polymer’s stiffening, in this study, the variation in some of the R-PETG’s parameters during cooling are emphasized and discussed. The evolution of an R-PETG filament’s shape was monitored during room-temperature-bending heating–cooling cycles. Straight-shape recovery and the complete loss of stiffness were observed at the start and the end of heating, respectively, followed by the forced straightening of the filament, performed by the operator, around 40 °C, during cooling. The tests performed by dynamic mechanical analysis disclosed the rise of the storage modulus (E’) after 100 °C heating followed by either liquid-nitrogen- or air-cooling to room temperature, in such a way that E’ was always larger after cooling than initially. Static tests emphasized a peculiar stress variation during a heating–cooling cycle applied in air, within the heating chamber of the tensile testing machine. Tensile-failure tests were performed at −10 °C at a rate of 100 mm/min, with specimens printed at various deposition directions between 10 and 40° to the transversal direction. The specimens printed at 40°, which had the largest ultimate strains, were broken with tensile rates between 100 and 500 mm/min. Deformation rate increase favored the shift from crazing to delamination failure modes. The correlation between the structural changes, the sharp E’ increase on heating, and the stiffening induced by cooling represents a novel approach that enables the use of 3D-printed R-PETG for the fabrication of the active parts of low-priced lightweight resettable actuators.

The paper analyzes the occurrence of evenly spaced cracks on the surface of lamellar specimens of Fe-28Mn-6Si-5Cr (mass %) shape-memory alloy (SMA), during cold rolling. The specimens were hot rolled and normalized and developed cold rolling cracks with an approximate spacing of about 1.3 mm and a depth that increased with the thickness-reduction degree. At normalized specimens, X-ray diffraction patterns revealed the presence of multiple crystallographic variants of brittle α′ body-bcc martensite, which could be the cause of cold-rolling cracking. Both normalized and cold-rolled specimens were analyzed using scanning electron microscopy SEM. SEM micrographs revealed the presence of several crystallographic variants of α′-body-centered cubic (bcc) and ε hexagonal close-packed (hcp) martensite plates within a γ-face-centered cubic (fcc) austenite matrix in a normalized state. High-resolution SEM, recorded after 25% thickness reduction by cold-rolling, emphasized the ductile character of the cracks by means of an array of multiple dimples. After additional 33% cold-rolling thickness reduction, the surface of crack walls became acicular, thus revealing the fragile character of failure. It has been argued that the specimens cracked in the neutral point but preserved their integrity owing to the ductile character of γ-fcc austenite matrix.