The materials for large scale fused filament fabrication (FFF) are not yet designed to resist thermal degradation. This research presents a novel polymer blend of polylactic acid with polypropylene for FFF, purposefully designed with minimum feasible chemical grafting and overwhelming physical interlocking to sustain thermal degradation. Multi-level general full factorial ANOVA is performed for the analysis of thermal effects. The statistical results are further investigated and validated using different thermo-chemical and visual techniques. For example, Fourier transform infrared spectroscopy (FTIR) analyzes the effects of blending and degradation on intermolecular interactions. Differential scanning calorimetry (DSC) investigates the nature of blending (grafting or interlocking) and effects of degradation on thermal properties. Thermogravimetric analysis (TGA) validates the extent of chemical grafting and physical interlocking detected in FTIR and DSC. Scanning electron microscopy (SEM) is used to analyze the morphology and phase separation. The novel approach of overwhelmed physical interlocking and minimum chemical grafting for manufacturing 3D printing blends results in high structural stability (mechanical and intermolecular) against thermal degradation as compared to neat PLA.

This research presents a partial biodegradable polymeric blend aimed for large-scale fused deposition modeling (FDM). The literature reports partial biodegradable blends with high contents of fossil fuel-based polymers (>20%) that make them unfriendly to the ecosystem. Furthermore, the reported polymer systems neither present good mechanical strength nor have been investigated in vulnerable environments that results in biodegradation. This research, as a continuity of previous work, presents the stability against biodegradability of a partial biodegradable blend prepared with polylactic acid (PLA) and polypropylene (PP). The blend is designed with intended excess physical interlocking and sufficient chemical grafting, which has only been investigated for thermal and hydrolytic degradation before by the same authors. The research presents, for the first time, ANOVA analysis for the statistical evaluation of endurance against biodegradability. The statistical results are complemented with thermochemical and visual analysis. Fourier transform infrared spectroscopy (FTIR) determines the signs of intermolecular interactions that are further confirmed by differential scanning calorimetry (DSC). The thermochemical interactions observed in FTIR and DSC are validated with thermogravimetric analysis (TGA). Scanning electron microscopy (SEM) is also used as a visual technique to affirm the physical interlocking. It is concluded that the blend exhibits high stability against soil biodegradation in terms of high mechanical strength and high mass retention percentage.

By simply heating mixtures of α-cyclodextrins and dumbbell-like poly(ethylene glycol) derivatives at 120 °C, polyrotaxanes form spontaneously via reversible chain exchange between acylhydrazone bonds, which have been proven by analyses of diffusion-ordered NMR, WAXD, ¹H NMR, solid-state ¹³C CP/MAS NMR, DSC and UV-Vis together.