To demonstrate the effects of surface atoms on photoluminescence (PL) and photocatalytic activities of luminescent carbon dots (CDs), we design and tailor the surface groups of CDs with heteroatoms by a facile and effective approach. The coexistence of O and N radicals in CDs results in strong PL while CDs containing O and Cl radicals show high photocatalytic activity. This is attributed to the different degrees and directions of energy band bending from inner to surface induced by O, N, and Cl radicals at the surface of CDs. The coexistence of both upward and downward band bending that are caused by the O and Cl radicals, respectively, in CDs is similar to an internal electronic field that facilitates the separation of electron–hole pairs and carrier migration, leading to high photocatalytic activity. These results may also be used for designing and tailoring optical–electronic properties of carbon nanostructures.
We propose and realize a novel packaged microsphere-taper coupling structure (PMTCS) with a high quality factor (Q) up to 5 × 106 by using the low refractive index (RI) ultraviolet (UV) glue as the coating material. The optical loss of the PMTCS is analyzed experimentally and theoretically, which indicate that the Q is limited by the glue absorption and the radiation loss. Moreover, to verify the practicability of the PMTCS, thermal sensing experiments are carried out, showing the excellent convenience and anti-jamming ability of the PMTCS with a high temperature resolution of 1.1 × 10−3°C. The experiments also demonstrate that the PMTCS holds predominant advantages, such as the robustness, mobility, isolation, and the PMTCS can maintain the high Q for a long time. The above advantages make the PMTCS strikingly attractive and potential in the fiber-integrated sensors and laser.
This paper demonstrates a fabrication technology of Ag wrinkled electrodes with application in highly stretchable wireless sensors. Ag wrinkled thin films that were formed by vacuum deposition on top of pre-strained and relaxed polydimethylsiloxane (PDMS) substrates which have been treated using an O2 plasma and a surface chemical functionalization process can reach a strain limit up to 200%, while surface adhesion area can reach 95%. The electrical characteristics of components such as resistors, inductors and capacitors made from such Ag conductors have remained stable under stretching exhibiting low temperature and humidity coefficients. This technology was then demonstrated for wireless wearable electronics using compatible processing with established micro/nano fabrication technology.
1 November 2015 in Optics and Lasers in Engineering