Development of high performance electrode materials for energy storage is one of the most important issues for our future society. However, a lack of clear analytical views limits critical understanding of electrode materials. This review covers useful analytical work using X-ray diffraction, X-ray absorption spectroscopy, microscopy and neutron diffraction for ion storage systems. The in situ observation facilitates comprehending real-time ion storage behaviour while the ion storage system is operating, which help us to understand detailed physical and chemical properties. We will discuss how the tools have been used to reveal detailed reaction mechanisms and underlying properties of electrode materials.

The evolution of the phase and morphology of FeOOH nanorods prepared by a hydrothermal method is studied via X-ray diffraction (XRD) and in situ transmission electron microscopy. The FeOOH nanorod with a tetragonal structure (β-FeOOH) is gradually converted into a rhombohedral Fe₂O₃ nanorod by a simple thermal treatment. The existence of an intermediate FeOOH structure with high lattice strains during the phase transition is identified by Rietveld analysis using XRD. The electrochemical properties of the nanorods are investigated based on the crystal phases to elucidate their relative catalytic activities. The strained-FeOOH nanorods exhibited enhanced catalytic water oxidation activity and stability. Typically, the strained-FeOOH nanorods showed high electrochemical stability under neutral conditions, while tetragonal FeOOH nanorods under the same conditions showed rapid deactivation for water oxidation reaction.

Longitudinal critically refracted (L_CR) waves are considered bulk longitudinal waves and penetrate into an effective depth beneath the surface parallel to the material surface. Such L_CR waves can be employed to measure residual stresses because the acoustoelastic effect is the basis for ultrasonic residual stress measurements. This effect is described by the relationship between change of wave travel time and stress applied when such waves propagate in a stressed medium. In this paper, stresses applied in a rail were evaluated by using a developed L_CR probe. With this transducer, it was verified how the difference in the arrival times of the L_CR waves showed a trend as the tensile stresses increased. The acoustoelastic coefficients were calculated using the relationship between the stresses and the travel times, and the residual stresses of the used rails were measured using these coefficients. In addition, the difference in residual stress distribution according to the characteristics of the wheel-rail contact surface was analyzed from the obtained residual stress value. It was concluded that this non-destructive evaluation technique using L_CR waves could be employed for accurate stress measurement of rails because differences in stress applied to the rail can be detected.