Leire Barruetabeña

Ms. Leire Barruetabeña


Research Focus & Metrics

Academic Career Length

5Years (2022-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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24 July 2022 in Environment Systems and Decisions
Verified
Journal Article
Open access
PDF file
Martin MullinsMartin Mullins
Martin Mullins
MHMartin Himly
Martin Himly
IRIsabel Rodríguez-Llopis
Isabel Rodríguez-Llopis
IFIrini Furxhi
Irini Furxhi
SHSabine Hofer
Sabine Hofer
Damjana DrobneDamjana Drobne
Damjana Drobne
The utility of decision-making tools for the risk governance of nanotechnology is at the core of this paper. Those working in nanotechnology risk management have been prolific in creating such tools, many derived from European FP7 and H2020-funded projects. What is less clear is how such tools might assist the overarching ambition of creating a fair system of risk governance. In this paper, we reflect upon the role that tools might and should play in any system of risk governance. With many tools designed for the risk governance of this emerging technology falling into disuse, this paper provides an overview of extant tools and addresses their potential shortcomings. We also posit the need for a data readiness tool. With the EUs NMP13 family of research consortia about to report to the Commission on ways forward in terms of risk governance of this domain, this is a timely intervention on an important element of any risk governance system.

27 March 2025 in Coatings
Verified
Journal Article
Open access
PDF file
IEIdoia Etxeberria
Idoia Etxeberria
ISIngemar Svensson
Ingemar Svensson
ADAna Isabel Díaz
Ana Isabel Díaz
LBLeire Barruetabeña
Leire Barruetabeña
Alkyd resins are still one of the most important classes of binders for paint systems. They are outstanding in terms of their versatility of formulations and applications, cost-effectiveness, and durability. Traditionally, they are synthesized using phthalic anhydride, polyalcohols with three or four functional groups (pentaerythritol, glycerol, and trimethylolpropane), and fatty acids or oils. In this study, new bio-alkyd resins were synthesized with the objective of increasing the bio-based content by substituting phthalic anhydride, thereby also enhancing the biodegradability of coatings. The newly synthesized alkyd resins, formulated with azelaic acid, were used to develop coatings incorporating additives while avoiding cobalt-based driers. Additional agents such as leveling, wetting, and anti-skinning agents, were also included. Paints were applied to wood substrates and dried at room temperature. The resulting films were characterized by pendulum hardness, transparency, and color by colorimetry, cross-cut test, contact angle, and gloss. Thermal properties were analyzed by Differential Scanning Calorimetry (DSC), and Total Organic Carbon (TOC) content and aerobic biodegradation were also evaluated. The resulting coating films exhibited good mechanical performance, with hardness values ranging from 132 to 148 Persoz oscillations and strong adhesion to wood substrates (smooth cross-cut edges, Class 0). Significant biodegradability (70% in less than 90 days) was demonstrated under composting conditions, which was considerably higher than that of a commercial reference alkyd coating (34.7%) under the same conditions. These findings suggest that the developed bio-alkyd coatings formulated with azelaic acid and DCO-FA without cobalt-based driers represent a promising alternative to conventional phthalic acid-based alkyds. These novel coatings move closer to fully bio-based formulations and offer enhanced biodegradability, making them a more sustainable option for coating applications.