This review details the structure of lignin and curates information on the characteristics that this polymer must have for each specific use. Lignin is a by-product of the pulp and paper industry and the second most abundant biopolymer after cellulose. Approximately 50 million tons of lignin are produced worldwide annually, of which 98% to 99% is incinerated to produce steam, process energy. Just 1% to 2% of the lignin, derived from the sulfite pulp industry, is used in chemical conversion to produce lignosulfonates. Biorefining is a promising approach to promote the wider use of kraft lignin. However, using kraft lignin to produce high value-added products is a great challenge, due to its complex structure, low reactivity, and low solubility, which are factors that limit the lignin’s large-scale use in biorefineries. Recent studies show that kraft lignin can be used as lignosulfonates and dispersants, technical carbons, transportation fuels, bioplastics, and adhesives, but some technological hurdles must be overcome and several industrial tests must be developed to make these uses viable.
Improper waste disposal is one of the leading causes of environmental pollution, impacting soil, water, and air quality. In coffee plantations, each kilogram of beans produced generates an equal amount of husk, emphasizing the urgent need for sustainable practices to process this residual biomass into valued products. This study aimed to evaluate the potential of coffee husks for pellet production. Three coffee husk types were selected with distinct chemical compositions and granulometries: I (>5.3 mm), II (>2.6 mm and <5.3 mm), and III (<1.77 mm). The biomass was characterized for elemental, structural, and proximate composition. Pellets were produced with two knife heights (15 and 20 mm) and assessed for moisture content, density, length, and mechanical resistance, which were compared with the EN 14691-6 standard (DIN, 2012). Pelletizer productivity was also evaluated. Pellets from biomass III had an ash content of 12.09%, exceeding the <10% requirement. Other treatments met the ash content standard, category B. Pellets from biomass I (17.55%) and II (18.1%) at 15 mm length did not meet the <15% moisture content standard. The remaining pellets met category B standards. Only pellets from origin III (1.62%) met the nitrogen content requirement for international trade (<2%). Pelletizer productivity was higher with smaller granulometry biomass. Coffee husk has demonstrated its potential for pellet production, highlighting the valorization and use of this waste for clean energy generation, contributing to greenhouse gas emissions mitigation, and strengthening circular economy.
This study explores a circular economy approach in charcoal production, utilizing combustion gases from the process itself to optimize efficiency and quality, minimizing waste and reducing emissions. The research investigates the pre-drying of Eucalyptus sp. wood with these gases before carbonization, through an innovative system that directs gases from the carbonizing furnace to a separate drying furnace. Wood samples were dried at 120 °C and 150 °C for 15, 22.5, and 30 h before carbonization. The analysis included the gravimetric yield of charcoal, semi-carbonized wood, and fines, in addition to evaluating key charcoal properties. Results demonstrated that drying with combustion gases at 150 °C increased the charcoal yield by 7%, regardless of drying time. Furthermore, this pre-drying improved charcoal quality, raising fixed carbon content from 74.68% to over 81% and reducing volatile matter from 24.40% to below 18%. These findings highlight that the utilization of combustion gases for wood drying not only significantly enhances the efficiency and quality of charcoal production but also contributes to the reduction in greenhouse gas emissions, promoting a more sustainable and environmentally friendly alternative compared to conventional methods.