In this work, solid flexible polymer blend electrolytes (PBE) composed of polyvinyl alcohol (PVA) and polyvinyl pyrrolidone (PVP) with different amounts of sodium thiocyanate (NaSCN) salt mixed in double-distilled water (solvent) are prepared via solution casting method. The obtained films are characterized using several techniques. The study of the surface morphology of the polymer blend salt complex films via the POM technique reveals the presence of amorphous regions due to the NaSCN effect. FTIR spectra studies confirm the complex formation between PVA, PVP, and NaSCN. The addition of 20 wt% NaSCN salt in the composition PVA: PVP (50:50 wt%) polymer blend matrix leads to an increase in the number of charge carriers and thus improves the ionic conductivity. The ionic conductivity of each polymer blend electrolyte was studied using the electrochemical impedance spectroscopy (EIS) method. The highest room temperature ionic conductivity of 8.1 × 10⁻⁵ S/cm S cm⁻¹ is obtained for the composition of PVA: PVP (50:50 wt%) with 20 wt% NaSCN. LSV test shows the optimized ion-conducting polymer blend electrolyte is electrochemically stable up to 1.5 V. TNM analysis reveals that 99% of ions contribute for the conductivity against 1% of electrons only in the highly conductive polymer electrolyte PVA: PVP (50:50 wt%) + 20 wt% NaSCN. A supercapacitor device was fabricated using the optimized ion-conducting polymer blend film and graphene oxide (GO) coated electrodes. The GCD curve clearly reveals the behavior of an ideal capacitor with less Faradic process and low ESR value. The columbic efficiency of the GO-based system is found to be 100%, the GO-based electrode exhibits a specific capacitance of 12.15 F/g and the system delivers the charge for a long duration. The specific capacitance of the solid-state supercapacitor cell was found to be 13.28 F/g via the CV approach close to 14.25 F/g obtained with EIS data at low frequency.

In recent decades, the enhancement of the properties of electrolytes and electrodes resulted in the development of efficient electrochemical energy storage devices. We herein reported the impact of the different polymer electrolytes in terms of physicochemical, thermal, electrical, and mechanical properties of lithium-ion batteries (LIBs). Since LIBs use many groups of electrolytes, such as liquid electrolytes, quasi-solid electrolytes, and solid electrolytes, the efficiency of the full device relies on the type of electrolyte used. A good electrolyte is the one that, when used in Li-ion batteries, exhibits high Li+ diffusion between electrodes, the lowest resistance during cycling at the interfaces, a high capacity of retention, a very good cycle-life, high thermal stability, high specific capacitance, and high energy density. The impact of various polymer electrolytes and their components has been reported in this work, which helps to understand their effect on battery performance. Although, single-electrolyte material cannot be sufficient to fulfill the requirements of a good LIB. This review is aimed to lead toward an appropriate choice of polymer electrolyte for LIBs.

The aim of this study is to evaluate the environmental impact of solar energy by analyzing its emissions, resource consumption, and waste generation throughout its life cycle. As one of the most widely adopted energy sources, solar power offers substantial benefits in reducing greenhouse gas emissions; however, its broader environmental footprint requires careful examination. The production, operation, and disposal of solar panels contribute to pollution, water consumption, and hazardous waste accumulation, with an estimated 250,000 tons of solar waste reported in 2016 alone. Furthermore, solar power generation requires significant water resources, averaging 650 gallons per megawatt-hour of electricity. A key focus of this study is the emissions associated with solar technology, particularly during panel manufacturing and operation. Using HOMER Pro software, this research quantifies the emissions from Trina Solar photovoltaic (PV) panels (345 Wp), revealing an annual output of 49,259 kg of carbon dioxide, 214 kg of sulfur dioxide, and 104 kg of nitrogen dioxide. This Study obtained using HOMER Pro primarily account for operational emissions and do not include full lifecycle impacts such as raw material extraction, transportation, and disposal. These findings highlight the trade-offs between solar energy’s environmental advantages and its indirect ecological costs. While solar systems contribute to energy security and long-term economic savings, their environmental implications must be factored into energy planning and sustainability strategies. This study underscores the importance of developing greener manufacturing processes, improving recycling strategies, and optimizing solar farm operations to reduce emissions and resource depletion. By providing a comprehensive assessment of solar energy’s environmental impact, this research contributes valuable insights for policymakers, researchers, and industry leaders seeking to balance the benefits of solar power with sustainable environmental management.