Ultrafast lasers have been used for high-precision processing of a wide range of materials, including dielectrics, semiconductors, metals and polymer composites, enabling numerous applications ranging from micromachining to photonics and life sciences. To make ultrafast laser materials processing compatible with the scale and throughput needed for industrial use, it is a common practice to run the laser at a high repetition rate and hence high average power. However, heat accumulation under such processing conditions will deteriorate the processing quality, especially for polymers, which typically have a low melting temperature. In this paper, an analytical solution to a transient, two-dimensional thermal model is developed using Duhamel’s theorem and the Hankel transform. This solution is used to understand the effect of laser parameters on ultrafast laser processing of polypropylene (PP). Laser cutting experiments are carried out on PP sheets to correlate with the theoretical calculation. This study shows that, in laser cutting, the total energy absorbed in the material and the intensity are two important figures of merit to predict the cutting performance. Heat accumulation is observed at low scanning speeds and high repetition rates, leading to significant heat-affected zone and even burning of the material, which is supported by experimental data and modelling results. It is found that heat accumulation can be avoided by a proper choice of the processing condition.

In projection stereolithography (SL) processes, the separation of a newly cured layer from the constrained surface is a historical technical barrier and still greatly limits its printable size, process reliability, and print speed. This paper presents an approach to reduce the separation force in projection SL processes by texturing the constrained surface with radial microgroove patterns. Separation forces with conventional smooth constrained surface and textured surface are both modeled. The analytical model suggests that a proper design of micropatterns of the constrained surface is capable of reducing separation forces greatly. Furthermore, a projection SL testbed with online separation force monitoring unit is developed for experimental study. Experimental results verified the effectiveness of microsurface textures in reducing separation forces. Test cases also show that with the help of the proposed textured constrained surface, parts with wide solid cross sections that could not be printed using conventional methods were manufactured successfully. The influence of the textured constrained surface on the printed parts' surface roughness is studied, a gray scale projection approach is proposed to eliminate the influence and improve the surface quality of printed parts. Hence, the presented methods can help to improve the manufacturing capability of Projection SL processes.

Bessel beams with tunable spot size are desirable for many applications such as laser material processing, optical trapping, and imaging. In this paper, we report experimental and simulation results of using a segmented deformable mirror to generate zero- and higher-order Bessel beams that have a controllable transverse and longitudinal shape. The tilt angle and piston position of the mirror segments are optimized to recreate the phase structure of a reflective axicon. Zero-order Bessel beams are generated at various beam converging angles, and their core diameter, peak intensity, and depth-of-focus are found to agree with the calculated results. By applying a phase ramp along the azimuthal direction, the first-order Bessel beam is generated with the characteristic annular shape. Because deformable mirrors have low absorption and dispersion and operate at a fast frame rate, they are a promising candidate for spatial beam shaping of high-power ultrafast lasers, which are used in material processing applications.

Photopolymerization enables the printing of three-dimensional (3D) objects through successively solidifying liquid photopolymer on two-dimensional (2D) planes. However, such layer-by-layer process significantly limits printing speed, because a large number of layers need to be processed in sequence. In this paper, we propose a novel 3D printing method based on multiphoton polymerization using femtosecond Bessel beam. This method eliminates the need for layer-by-layer processing, and therefore dramatically increases printing speed for structures with high aspect ratios, such as wires and tubes. By using unmodulated Bessel beam, a stationary laser exposure creates a wire with average diameter of 100 μm and length exceeding 10 mm, resulting in an aspect ratio > 100:1. Scanning this beam on the lateral plane fabricates a hollow tube within a few seconds, more than ten times faster than using the layer-by-layer method. Next, we modulate the Bessel beam with a spatial light modulator (SLM) and generate multiple beam segments along the laser propagation direction. Experimentally observed beam pattern agrees with optics diffraction calculation. This 3D printing method can be further explored for fabricating complex structures and has the potential to dramatically increase 3D printing speed while maintaining high resolution.

We demonstrate a method of laser ablation with reduced feature size by using a pair of ultrashort pulses that are partially overlapped in space. By tuning the delay between the two pulses, features within the overlapping area are obtained on the surface of fused silica. The observed dependence of the feature position on delays longer than the free-carrier lifetime indicates an ionization pathway initiated by self-trapped excitons. This method could be used to enhance the resolution of laser-based lithography.

The nature of structural changes of nanosecond laser modification inside silicon is investigated. Raman spectroscopy and transmission electron microscopy measurements of cross sections of the modified channels reveal highly localized crystal deformation. Raman spectroscopy measurements prove the existence of amorphous silicon inside nanosecond laser induced modifications, and the percentage of amorphous silicon is calculated based on the Raman spectrum. For the first time, the high-resolution transmission electron microscopy images directly show the appearance of amorphous silicon inside nanosecond laser induced modifications, which corroborates the indirect measurements from Raman spectroscopy. The laser modified channel consists of a small amount of amorphous silicon embedded in a disturbed crystal structure accompanied by strain. This finding may explain the origin of the positive refractive index change associated with the written channels that may serve as optical waveguides.