The formation process of a microdischarge (MD) in both μ m- and nm-sized catalyst pores is simulated by a two-dimensional particle-in-cell/Monte Carlo collision model. A parallel-plate dielectric barrier discharge configuration in filamentary mode is considered in ambient air. The discharge is powered by a high voltage pulse. Our calculations reveal that a streamer can penetrate into the surface features of a porous catalyst and MDs can be formed inside both μ m- and nm-sized pores, yielding ionization inside the pore. For the μ m-sized pores, the ionization mainly occurs inside the pore, while for the nm-sized pores the ionization is strongest near and inside the pore. Thus, enhanced discharges near and inside the mesoporous catalyst are observed. Indeed, the maximum values of the electric field, ionization rate and electron density occur near and inside the pore. The maximum electric field and electron density inside the pore first increase when the pore size rises from 4 nm to 10 nm, and then they decrease for the 100 nm pore, due to a more pronounced surface discharge for the smaller pores. However, the ionization rate is highest for the 100 nm pore due to the largest effective ionization region.
We investigate the band and transport features of Dirac electrons on the surface of a three-dimensional topological insulator under the modulation of a periodic exchange field provided by an array of ferromagnetic insulating (FI) stripes. The Dirac point is shifted (unchanged) by the superlattice when the magnetizations of adjacent FI stripes are parallel (antiparallel). For a finite magnetic superlattice, there exists a full transmission gap for both the parallel and antiparallel configurations. When the two kinds of transmission gaps have no overlap, a large magnetoresistance ratio with a tunable sign can be achieved.
We investigated the mode transition from volume to surface discharge in a packed bed dielectric barrier discharge reactor by a two-dimensional particle-in-cell/Monte Carlo collision method. The calculations are performed at atmospheric pressure for various driving voltages and for gas mixtures with different N and O compositions. Our results reveal that both a change of the driving voltage and gas mixture can induce mode transition. Upon increasing voltage, a mode transition from hybrid (volume+surface) discharge to pure surface discharge occurs, because the charged species can escape much more easily to the beads and charge the bead surface due to the strong electric field at high driving voltage. This significant surface charging will further enhance the tangential component of the electric field along the dielectric bead surface, yielding surface ionization waves (SIWs). The SIWs will give rise to a high concentration of reactive species on the surface, and thus possibly enhance the surface activity of the beads, which might be of interest for plasma catalysis. Indeed, electron impact excitation and ionization mainly take place near the bead surface. In addition, the propagation speed of SIWs becomes faster with increasing N content in the gas mixture, and slower with increasing O content, due to the loss of electrons by attachment to O molecules. Indeed, the negative O ion density produced by electron impact attachment is much higher than the electron and positive O ion density. The different ionization rates between N and O gases will create different amounts of electrons and ions on the dielectric bead surface, which might also have effects in plasma catalysis.
Impedance matching can maximize the absorbed power transferred to the plasma load and minimize the reflected power, making it critical and indispensable for capacitively coupled plasmas (CCPs). The external circuit usually interacts with the plasma nonlinearly, so the global simulation of the external circuit and plasma and the matching design is very challenging. In this work, an a priori model was proposed to match the plasma impedance and the external circuit impedance for single-frequency CCPs. By calculating the plasma impedance and the matching network, the matching parameters were iteratively updated to find the best matching parameters. By adjusting the capacitance and the inductance of the circuit by numerical simulations, the reflection coefficient can be significantly reduced. At the same time, the plasma power absorption efficiency will be significantly improved. The universality of the method was demonstrated by choosing different initial circuit, discharge, and plasma parameters. The proposed method provides an effective matching design reference for CCPs.