A product made from virgin raw materials that ends up in a landfill presents a linear supply chain model. Today's photovoltaic (PV) industry is still largely based on this model. With the increasing volume of production, the raw materials required for it, and consequently the volume of waste, the application of circular economy principles in the PV sector can significantly increase its environmental efficiency. This study analyzes the impact of circularity on the supply chain of PV silicon used for PV module production. Four scenarios based on the combination of technological pathways and circularity options are created. Their evaluation is carried out by the methodologies of Material Circularity Indicator (MCI) and Life Cycle Assessment (LCA). The State-of-art case of the PV polysilicon supply chain corresponds to the MCI score of 0.54. Closed-loop circularity solutions provide the MCI score of 0.80 presenting the potential for a circular economy approach in the industry. LCA results show the reduction of environmental impact by 12% with improved circularity. The study presents the benefits of potential circularity options within the supply chain as well as the impact of technological development on the polysilicon demand.

High-quality recycling of photovoltaic (PV) modules starts with a delamination process. It aims to remove the encapsulation layer between glass and solar cells. Many studies have investigated the delamination of ethylene-vinyl acetate encapsulant, whereas the delamination of polyolefin elastomer (POE) encapsulation in solar modules remains a research gap. This study presents methods of solvent and thermal treatment for the separation of layers in a PV module encapsulated with POE polymer. Various organic compounds were tested for the solvent treatment. The results showed that most of the solvents did not separate the materials. However, with some of them, polymer swelling was achieved. Glycerol was the only solvent capable of separating glass from multi-material laminate. The separated glass does not include contaminants and is therefore suitable for the use as a secondary material. However, the solar cells remained encapsulated in the polymer, thus additional processing is needed to remove it. The time and solvent temperature for glycerol treatment were measured. The thermal treatment was conducted based on the results of thermogravimetric analyses, which determined the degradation of POE under heating conditions. Thermal treatment at 500°C for 1 hour in an air atmosphere was found to be the effective way to detach PV layers. Glass, solar cells and metal ribbons were separated without polymer contamination and are therefore suitable for further use.

As photovoltaic (PV) installations expand globally, effective recycling of end-of-life crystalline silicon solar cells has become increasingly important, including the recovery of valuable metals such as silver (Ag) and aluminium (Al). Traditional nitric acid-based chemical leaching methods, although effective, present environmental challenges due to the generation of hazardous nitrogen oxide (NO_x) emissions. To address these concerns, this study investigated alternative hydrometallurgical leaching strategies. Two selective treatments (NaOH for Al, and NH₃ + H₂O₂ for Ag) and one simultaneous treatment (HNO₃ + H₂O₂) were evaluated for metal recovery efficiency. All methods demonstrated high recovery efficiencies, achieving at least 99% for both metals within 60 min. The investigated methods effectively suppressed NO_x emissions without compromising leaching efficiency. These findings confirm that hydrometallurgical leaching techniques incorporating hydrogen peroxide can achieve efficient and environmentally safer recovery of silver and aluminium from solar cells, providing valuable insights into the development of more sustainable recycling practices for photovoltaic waste management.