Maximizing the efficient utilization of critical apatite resources through flotation necessitates the exploration of effective and innovative collectors. This study investigates the potential of a fatty acid mixture (FAM) synthesized from saturated palmitic and stearic acids, monounsaturated oleic and palmitoleic acids, and polyunsaturated linoleic acid. The saponified collector FAM and the depressant sodium alginate (NaAl) achieved a direct flotation of apatite from calcite and quartz (97% apatite, 10% calcite, and 7% quartz). The flotation performance with the tested combination exhibited a highly effective enrichment of apatite, mainly from calcite, which aligns with the surface chemistry assessments. Adsorption tests and zeta potential measurements confirmed the micro-flotation results. They provided compelling evidence of a chemisorption interaction between Ca²⁺ sites on calcite and the carboxyl and hydroxyl groups of NaAl. FTIR analyses suggested a reaction between the apatite surface and the carboxyl groups of saturated and unsaturated acid groups in FAM, even those conditioned with NaAl before, facilitating the complex formation. Remarkably, the synergistic effect of the functional groups demonstrates dual functionality, serving as both a hydrophilic entity for calcite and a hydrophobic entity for apatite flotation. The universal mechanism unveils substantial potential for the extensive application of FAM within apatite flotation.

This study attempts to assess the contribution of entrainment and true flotation in the overall recovery by the laboratory tests performed on a natural complex sulfide ore, provided by la Compagnie Minière des Guemassa (Morocco), and the effect of two different collectors, Potassium Amyl Xanthate (PAX) and Sodium di-isobutyl di-thiophosphinate (Aerophine 3418A), on the two contributions. Overall recovery and true recovery were fitted to first kinetic model and modified flotation parameters were calculated to measure of flotation separation selectivity of chalcopyrite, galena and sphalerite over gangue and pyrrhotite. To estimate the entrainment, Ross method was the most suitable in the case of complex sulfide ore with high content of pyrrhotite. Trahar method overestimates the effect of entrainment.

Moroccan Mining Company of Guemassa (MCG) produces from a complex sulphide ore three concentrates using Aerophine 3418A in the flotation circuits of galena and chalcopyrite and potassium amyl...

The selective separation of chalcopyrite from pyritic ores represents a major industrial challenge due to inadvertent copper activation. This study systematically investigates the batch flotation kinetics of a complex sulfide ore (Draa Sfar North, Morocco) using a first-order kinetic model ($R^2>0.916$). The impacts of pulp pH, chemical depressants, and specialized collectors were evaluated to optimize the copper/iron selectivity index ($S{I}_{Cu/Fe}$). The results reveal a high-alkalinity paradox: At pH 11.0, chalcopyrite kinetics experience a severe passivation bottleneck ($K_{i,Cu}=0.1330 {\min }^{-1}$). At pH 11.5, selectivity collapses ($SI=2.64$) due to persistent iron sulfide floatability ($K_{i,Fe}=0.2066 {\min }^{-1}$). Conversely, natural pH ($\approx 6.0$) provides a superior baseline ($SI=3.32$), where 40 g/t sodium cyanide (NaCN) yielded a peak index of $S{I}_{Cu/Fe}=10.25$. As an eco-friendly substitute, sodium lignosulfonate (LSNa) achieved outstanding performance ($S{I}_{Cu/Fe}=5.30$), reducing iron kinetics to their lowest level ($K_{i,Fe}=0.0356 {\min }^{-1}$) via ferric–anionic complexation. Furthermore, Danafloat 271 secured the highest collector-driven selectivity ($S{I}_{Cu/Fe}=5.03$) by suppressing the iron matrix ($K_{i,Fe}=0.0306 {\min }^{-1}$) following Hard–Soft Acid–Base principles. This study clarifies specific aspects of selective copper–iron flotation, demonstrating that natural pH circuits with green depressants or selective collectors offer a sustainable alternative.