Furnas volcano, in São Miguel island (Azores), being the surface expression of rising hydrothermal steam, is the site of intense carbon dioxide (CO2) release by diffuse degassing and fumaroles. While the diffusive CO2 output has long (since the early 1990s) been characterized by soil CO2 surveys, no information is presently available on the fumarolic CO2 output. Here, we performed (in August 2014) a study in which soil CO2 degassing survey was combined for the first time with the measurement of the fumarolic CO2 flux. The results were achieved by using a GasFinder 2.0 tunable diode laser. Our measurements were performed in two degassing sites at Furnas volcano (Furnas Lake and Furnas Village), with the aim of quantifying the total (fumarolic + soil diffuse) CO2 output. We show that, within the main degassing (fumarolic) areas, the soil CO2 flux contribution (9.2 t day−1) represents a minor (~15 %) fraction of the total CO2 output (59 t day−1), which is dominated by the fumaroles (~50 t day−1). The same fumaroles contribute to ~0.25 t day−1 of H2S, based on a fumarole CO2/H2S ratio of 150 to 353 (measured with a portable Multi-GAS). However, we also find that the soil CO2 contribution from a more distal wider degassing structure dominates the total Furnas volcano CO2 budget, which we evaluate (summing up the CO2 flux contributions for degassing soils, fumarolic emissions and springs) at ~1030 t day−1.

The La Fossa volcano is near the inhabited zone of the island of Vulcano and is a suitable case for studying gas sources of different geological origins. Since the last eruption, fumarolic-solfataric activity has interested this area with fumarolic emissions, mainly at the top of the volcanic cone and at Vulcano Porto. In recent decades, the anomalous degassing zones on the island have not significantly changed their location. On the contrary, there have been several significant changes in the emission rate due to the addition of volcanic gas. In these zones, CO₂ flux from the ground is responsible for a decrease in the indoor air quality. A recent increase in volcanic degassing led to an increase in the gas hazard in the inhabited area of Vulcano Island, and people were temporarily displaced from Vulcano Porto. The results of this study show that a monitoring system can be used for the early detection of transients in soil CO₂ flux (φCO₂) in the anomalous degassing zone of Vulcano. Synchronous monitoring of φCO₂ and outdoor air CO₂ concentration has shown variations in volcanic degassing that affect outdoor air CO₂ concentration in the populated zone of Faraglione.

The Earth’s degassing is an important factor in evaluating global carbon budget estimates and understanding the carbon cycle. As a result, numerous studies have focused on this topic. However, current estimates predominantly focus on subaerial CO₂ emissions and CO₂ deep submarine emissions, particularly along mid-ocean ridges (MORs), whereas very few and only spatially limited estimates of shallow submarine CO₂ emissions have been reported, despite being widespread features of the seafloor. This study reports the results of measuring the dissolved CO₂ concentrations in shallow submarine environments along the coast of Vulcano Island (Aeolian Islands, Italy). For the areas exhibiting the highest concentrations, we calculated the amount of diffuse degassing by computing the sea–air CO₂ flux. The results revealed extremely high dissolved CO₂ concentrations, reaching up to 24 vol.% in areas with visible hydrothermal activity, including one location far from the island’s main crater. Notably, elevated CO₂ levels were also detected in areas with minimal or no apparent hydrothermal discharge, indicating the occurrence of diffuse degassing processes in these areas. In addition, the calculated diffuse degassing flux was comparable in magnitude to the CO₂ flux directly emitted into the atmosphere from the island’s main bubbling pools.