Electric vehicles are considered the most promising alternative to internal combustion engine vehicles towards a cleaner transportation sector. Having null tailpipe emissions, electric vehicles contribute to fight localized pollution, which is particularly important in overpopulated urban areas. However, the electric vehicle implies greenhouse gas emissions related to its production and to the electricity generation needed to charge its batteries. This study focuses the analysis on how the electric vehicle emissions vary when compared to internal combustion engine vehicles, depending on the electric power plant fleet and the efficiency during the use-phase. For this to be done, the GWP associated to the electricity generation on the electric vehicle most selling European countries are calculated. Similarly, electric vehicle’s use-phase energy efficiency is calculated under a wide range of driving conditions using the Monte Carlo method. The results from energy production and energy use-phases are compared to the GWP calculated for internal combustion engine vehicles for six different driving cycles, to obtain the threshold values for which electric vehicles provide GWP reduction. These threshold values are then matched with the current electricity power plant fleet and the electric vehicle promotion incentives of the European countries considered in the study, showing that some countries (e.g. France or Norway) are better-suited for electric vehicles adoption, while countries like Spain or Portugal should boost electric vehicle promotion policies. Furthermore, other countries in Europe, such as Germany or the UK that are doing an effort on decarbonizing their power plant fleet, do not offer immediate greenhouse gas emission reductions for the uptake of electric vehicles instead of conventional cars.Peer ReviewedPostprint (author's final draft

Reusing electric vehicle batteries once they have been retired from the automotive application is stated as one of the possible solutions to reduce electric vehicle costs. Many publications in literature have analysed the economic viability of such a solution, and some car manufacturers have recently started running several projects to demonstrate the technical viability of the so-called battery second life. Nevertheless, the degradation behaviour of second life batteries remains unknown and represents one of the biggest gaps in the literature. The present work aims at evaluating the effects of Lithium-ion (Li-ion) NMC/C battery State of Health (SOH) and ageing history over the second life performance, on two different applications: a residential demand management application and a power smoothing renewable integration application. The performance and degradation of second life batteries are assessed both at the cell level and at stack level. Homogeneous and heterogeneous stacks are analysed in order to evaluate the impact of cell-to-cell history and SOH differences over the battery performance and degradation behaviour. Results obtained showed a strong influence of the first life battery ageing history upon the second life battery performance and degradation. Thereby, proper monitoring and battery selection appears crucial to certify the technical viability of battery second life.