Perovskite can be used to prepare high-performance photodetectors due to its excellent optical properties. However, the detection range of perovskite photodetectors is mostly limited to the visible light range, restricting their further development and application. In recent years, combining perovskite with organic bulk heterojunctions to prepare photodetectors with broadband detection capability has proven to be an effective strategy. Through this approach, the response spectrum of the photodetector can be flexibly regulated, and organic compounds can improve the perovskite film quality by passivating defects and inhibit the penetration of water molecules in the air, thereby improving the device performance and stability. In this work, we propose and demonstrate the feasibility of combining MAPbI3 perovskite with PTB7-Th:COTIC-4F to prepare high-performance photodetectors with wide spectral response characteristics. With the assistance of an organic bulk heterojunction, the defects of perovskite crystals are effectively passivated, and the detection spectrum of the device is successfully extended to about 1100 nm. As a result, the responsivity achieved is 0.58 A/W, 1.19 A/W, and 1.41 A/W under laser illumination of 532 nm, 808 nm, and 980 nm, with the power density of 5 μW/cm2 at the bias voltage of −0.5 V, respectively, which is one of the best performances among vertical device structures of this type. Moreover, the stability of the final hybrid film has been greatly improved. This work provides a new approach to the preparation of high-performance and broadband perovskite photodetectors.
This paper presents a novel silicon-based piezoresistive pressure sensor composed of a silicon layer with sensing elements and a glass cover for hermetic packaging. Unlike conventional designs, this study employs numerical simulation to analyze the influence of varying roughness levels of the sensitive membrane on the sensor’s output response. Simulation results demonstrate that pressure sensors with smoother sensitive membranes exhibit superior performance in terms of sensitivity (5.07 mV/V/MPa), linearity (0.67% FS), hysteresis (0.88% FS), and repeatability (0.75% FS). Furthermore, an optimized process for controlling membrane roughness was achieved by adjusting the concentration of the etchant solution. Experimental results reveal that a membrane roughness of 35.37 nm was attained under conditions of 80 °C and 25 wt% TMAH. Additionally, the fabrication process of this piezoresistive pressure sensor was significantly simplified and cost-effective due to the adoption of a backside wet etching technique. The fabricated sensor demonstrates excellent performance metrics, including a sensitivity of 5.07 mV/V/MPa, a full-scale (FS) output of 101.42 mV, a hysteresis of 0.88% FS, a repeatability of 0.75% FS, and a nonlinearity of 0.67% FS. These results indicate that the proposed sensor is a promising tool for precise pressure measurement applications, offering both high performance and cost efficiency. This study not only advances the understanding of the impact of membrane roughness on sensor performance but also provides a practical and scalable fabrication approach for piezoresistive pressure sensors.
Sn-Pb perovskite solar cells, which have the advantages of low toxicity and a simple preparation process, have witnessed rapid development in recent years, with the power conversion efficiency for single-junction solar cells exceeding 23%. Nevertheless, the problems of poor crystalline quality of Sn-Pb perovskite films arising from rapid crystallization rate and facile oxidation of Sn2+ to Sn4+ have become key issues for the further development of Sn-Pb perovskite solar cells. Herein, we report the incorporation of triazinamide (N-(6-methyl-3-oxo-2,5-dihydro-1,2,4-Triazin-4(3H)-YL) acetamide) as an additive to regulate the crystalline growth of Sn-Pb perovskite films, resulting in films with low trap density and large grain size. The triazinamide additive effectively passivated defects in the perovskite films. As a result, the triazinamide-modified perovskite solar cells achieved a higher efficiency of 15.73%, compared with 13.32% for the control device, significantly improving device performance. Notably, the optimal triazinamide-modified perovskite solar cell maintained 72% of its initial power conversion efficiency after being stored in an air environment for nearly 300 h, while only 18% of the power conversion efficiency of the control perovskite solar cell was retained. This study proposes an effective strategy for fabricating highly efficient and stable Sn-Pb perovskite solar cells.
This study demonstrates a high-performance thermopile infrared detector that incorporates a carbon black nanoparticle (CBNP) absorption layer. To overcome the limitations associated with conventional infrared-absorbing materials—including high cost, complex fabrication, and constrained spectral response—a highly porous CBNP thin-film absorption layer was deposited onto the thermopile sensing area using inkjet printing. Combined with an optimized microcavity design, this approach significantly enhances the photothermal conversion efficiency of the device. Experimental results indicate that the detector equipped with the CBNP absorption layer achieves a responsivity of 47.9 V/W and a detectivity of 1.14 × 108 cm·Hz1/2·W−1. These values represent improvements of 34.55% in responsivity and 34.28% in detectivity, respectively, compared to a reference device without the CBNP layer. This work provides a promising strategy for the development of low-cost yet high-performance infrared detectors.
Perovskite materials have garnered significant attention in both fundamental research and practical applications owing to their exceptional light absorption coefficients, low fabrication costs, and inherent advantages for thin-film and flexible device fabrication. Nevertheless, interface defects within perovskite films induce detrimental non-radiative carrier recombination and pronounced hysteresis effects, which collectively impose substantial limitations on the photovoltaic performance and long-term operational stability of perovskite solar cells (PSCs). Conventional passivation strategies, despite their demonstrated efficacy in mitigating interface defects, often inadvertently introduce secondary defects in originally defect-free regions, thereby restricting the extent of device performance improvement. To overcome this critical limitation, we have developed a precision defect passivation methodology that employs a targeted two-step immersion–cleaning process, achieving selective defect passivation while concomitantly eliminating residual passivating agents. This approach effectively prevents the formation of new defects in unaffected regions of the perovskite films, and the resultant PSC possesses a power conversion efficiency (PCE) of 21.08%, accompanied by a substantial mitigation of hysteresis behavior. Furthermore, unencapsulated devices demonstrate remarkable stability, retaining over 81% of their initial efficiency after 20 days of atmospheric storage under 50% relative humidity, which underscores the effectiveness of our passivation strategy in simultaneously enhancing both device performance and operational stability.
Electrochromic devices have emerged as promising candidates for non-emissive displays due to their particular photoelectric performance in complex lighting environments. They exhibit considerable potential in emerging fields such as Internet of Things terminals, flexible wearables and human–computer interaction interfaces. In this study, we developed a low-power electrochromic display based on a Pt/FTO (Fluorine doped tin oxide) electrocatalytic counter electrode and a Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) porous gel electrolyte. The Pt catalyst enhances Br−/Br3− redox reactivity, which reduces the driving voltage from 2 V to 1 V, and accelerates the electrode reaction kinetics. It is systematically explained by the Density Functional Theory (DFT) calculations and electrochemical characterization. Furthermore, we demonstrate a proof-of-concept multicolor display incorporating the electrocatalytic counter electrode with various viologen derivatives. This approach provides a significant advancement toward next-generation high-performance displays and is supportive of the development of energy-efficient optoelectronic devices.