The present study aims to investigate the advantages of diamond-like carbon (DLC) films in reducing friction and lubrication to address issues such as the low surface hardness, high friction coefficients, and poor wear resistance of titanium alloys. Cr-doped DLC films were deposited by high-power impulse magnetron sputtering (HiPIMS) in an atmosphere of a gas mixture of Ar and C2H2. The energy of the deposited particles was controlled by adjusting the target powers, and four sets of film samples with different powers (4 kW, 8 kW, 12 kW, and 16 kW) were fabricated. The results showed that with an increase in target power, the Cr content increased from 3.73 at. % to 22.65 at. %; meanwhile, the microstructure of the film evolved from an amorphous feature to a nanocomposite structure, with carbide embedded in an amorphous carbon matrix. The sp2-C bond content was also increased in films, suggesting an intensification of the film’s graphitization. The hardness of films exhibited a trend of initially increasing and then decreasing, reaching the maximum value at 12 kW. The friction coefficient and wear rate of films showed a reverse trend compared to hardness variation, namely initially decreasing and then increasing. The friction coefficient reached a minimum value of 0.14, and the wear rate was 2.50 × 10−7 (mm3)/(N·m), at 8 kW. The abrasive wear was the primary wear mechanism for films deposited at a higher target power. Therefore, by adjusting the target power parameter, it is possible to control the content of the metal and sp2/sp3 bonds in metal-doped DLC films, thereby regulating the mechanical and tribological properties of the films and providing an effective approach for addressing surface issues in titanium alloys.
In the present study, copper (Cu) films were deposited on polyethylene terephthalate (PET) substrates using direct-current (DC) magnetron sputtering technology. A systematic investigation was conducted on the effects of process parameters, such as target power, gas flow rate, and substrate temperature, on the microstructure and properties of copper films. The results showed that an increase in the target power resulted in enhanced film grain size, accompanied by a reduction in resistivity and an improvement in adhesion strength. Furthermore, resistivity increased monotonically with elevated gas flow rates, whereas the adhesion strength was found to achieve its maximum at a flow rate of 350 mL/min. In addition, substrate temperature variations had negligible influence on the film grain size and resistivity; nevertheless, the adhesion progressively decreased with increasing substrate temperature. A set of optimal parameters (3 kW, 350 mL/min, −15 °C) was determined based on the comprehensive evaluation of deposition efficiency, conductivity and adhesion performance. The Cu film prepared under these conditions exhibited low resistivity (8.37 × 10−8 Ω·m) and improved adhesion strength (166 gf/mm). Therefore, it is concluded that high performance of metallized Cu films could be achieved by fine-tuning deposition parameters.
14 February 2026 in Surface Science and Technology
CrN/CrSiN multilayer coatings with different Si contents (Si-5, Si-10, Si-15) were fabricated by arc ion plating. The microstructure, mechanical properties, electrochemical performance and tribocorrosion behavior of the coatings were investigated systematically. The coatings were mainly composed of CrN phase. With increasing Si content, grain refinement and diffraction peak broadening of CrN were observed, while no significant changes in coating hardness or adhesion strength were detected. Electrochemical measurements revealed that the densification of the coatings was improved by Si doping, which consequently led to an increase in pore resistance (Rf) with higher Si content, while the charge transfer resistance (Rct) was reduced. The Si-15 coating exhibited the lowest Rct value of 1.08 × 104 Ω·cm2. Compared with the CrN coating, the tribocorrosion resistance was improved through the adoption of the Si doping multilayer structure. However, the performance was not linearly enhanced with increasing Si content. The Si-15 coating presented the highest tribocorrosion rate of 1.81 × 10–6 mm3/(N·m) among the CrN/CrSiN multilayer coatings. It was found that excessive Si content enlarged the potential difference between the coating and substrate, which exacerbated galvanic corrosion at the interface and consequently degraded the tribocorrosion performance. Finally, the tribocorrosion failure mechanism of the CrN/CrSiN coatings was discussed.
The effects of RF plasma treatments using different gases (Ar, O2, and N2) and processing parameters on the surface wettability of polyethylene terephthalate (PET) films were systematically investigated. Atomic force microscopy (AFM) and X–ray photoelectron spectroscopy (XPS) were employed to characterize the evolution of surface topography and chemical composition. While all treatments enhanced hydrophilicity, the magnitude of improvement and the governing mechanisms were gas-dependent. Among them, O2 plasma treatment exhibited the most pronounced effect: under optimal conditions (20 W, 80 s), the water contact angle (WCA) was reduced to 3.7°, indicating a superhydrophilic surface. This enhancement was primarily attributed to a substantial increase in surface oxygen content (O/C ratio) and the incorporation of strongly polar oxygen-containing functional groups, such as C=O and COOH. N2 plasma offered moderate improvement via nitrogen-containing groups, while non-reactive Ar plasma relied primarily on physical etching, yielding the smallest enhancement. Analysis revealed that wettability evolution was dominated by increased polar surface energy from chemical functionalization, with surface roughness playing a synergistic role. These results demonstrate that optimizing plasma gas and parameters effectively controls PET wettability through the coupled regulation of surface chemistry and topography.