The chemical analysis of humic acids and their activated forms based on brown coal from the Maikuben coal basin (Kazakhstan) was carried out. The humic aci

Titanium-manganites of LaLi₂TiMnO₆ and LaNa₂TiMnO₆ were synthesized by the methods of ceramic technology from the oxides of lanthanum, titanium (IV), manganese (III), and the carbonates of lithium and sodium. The types of their syngony and the parameters of their gratings were determined radiographically. The isobaric heat capacities of titanium-manganites were measured with experimental calorimetry in the range of 298.15–673 K. It was found that on the dependence curve of heat capacity versus temperature of C°_p~f(T), for LaLi₂TiMnO₆ at 348 K and 598 K, and LaNa₂TiMnO₆ at 348 K, there are abnormal jumps in heat capacity, probably related to phase transitions of the second kind. Taking into account the temperatures of the phase transitions, the equations of the temperature dependence of the heat capacity of titanium-manganites were derived. Their standard entropies were calculated by the ion increments method. Temperature dependences of the thermodynamic functions of S°(T), H°(T)-H°(298.15), and Φ^xx(T) were calculated using the experimental data on heat capacities and the calculated values of the standard entropies. The standard heat capacities of the studied compounds were calculated by the independent methods of ion increments and Debye, the values of which were in satisfactory agreement with the experimental data. The standard enthalpy of the formation of LaLi₂TiMnO₆ and LaNa₂TiMnO₆ was calculated according to the methodology developed by the authors. The conducted electrophysical studies determined the nature of the second-order phase transition and the semiconductor features of their conductivity. Thus, all the above-mentioned data on the experimental and calculated studies of the temperature dependence of heat capacity, the thermodynamic functions to determine a standard enthalpy of formation of LaLi₂TiMnO₆ and LaNa₂TiMnO₆, and the investigation of their electrical properties are absolutely new, and they have no analogues.

Temperature dependences of the heat capacities of cobalt manganites LaM2IICoMnO6 (MII= Mg, Ca, Sr, Ba) are investigated by means of dynamic calorimetry in the temperature range of 298.15–673 K. It...

The enthalpies of myricetin dissolution are measured by means of calorimetry with mol dilutions of flavonoid: 96 mol % ethanol equal to 1: 9000, 1: 18000, and 1: 36000. The standard enthalpies of...

Cuprate manganites of the composition LaM2IICuMnO6 (MII= Mg, Ca, Sr, Ba) were synthesized from lanthanum, copper(II), and manganese(III) oxides and alkaline-earth metal carbonates by...

The isobaric heat capacities of nanostructured manganese ferrites NdMe1.5MnFeO6, where Me is Mg, Ca, Sr, and Ba, are investigated at Δ Tranging from 298.15 to 673 K by means of dynamic calorimetry....