Electrical voltage has a crucial effect on the nanofiber morphology as well as the jet number in the electrospinning process, while few literatures were found to explain the deep mechanism. Herein, the electrical field distribution around the spinning electrode was studied by the numerical simulation firstly. The results show that the electrical field concentrates on the tip of a protruding droplet under relatively low voltage, while subsequently turns to the edge of needle tip when the protruding droplet disappears under high voltage. The experimental results are well consistent with the numerically simulated results, that is, only one jet forms at low voltage (below 20 kV for PVDF-HFP and PVA nanofiber), but more than one jet forms under high voltage (two jets for PVDF-HFP nanofiber, four jets for PVA nanofiber). These more jets lead to (1) higher fiber diameter resulting from actually weaker electrical field for each jet and (2) wide distribution of fiber diameters due to unstable spinning process (changeable jet number/site/height) under high voltage. The results will benefit the nanofiber preparation and application in traditional single-needle electrospinning and other electrospinning methods.

In recent years, medicinal plant extracts have received remarkable attention due to their wound-healing properties. In this study, polycaprolactone (PCL) electrospun nanofiber membranes incorporated with different concentrations of pomegranate peel extract (PPE) were prepared. The results of the SEM and FTIR experiments demonstrated that the morphology of nanofiber is smooth, fine, and bead-free, and the PPE was well introduced into the nanofiber membranes. Moreover, the outcomes of the mechanical property tests demonstrated that the nanofiber membrane made of PCL and loaded with PPE exhibited remarkable mechanical characteristics, indicating that it could fulfill the essential mechanical requisites for wound dressings. The findings of the in vitro drug release investigations indicated that PPE was instantly released within 20 h and subsequently released gradually over an extended period by the composite nanofiber membranes. Meanwhile, the DPPH radical scavenging test confirmed that the nanofiber membranes loaded with PPE exhibited significant antioxidant properties. Antimicrobial experiments showed higher PPE loading, and the nanofiber membranes showed higher antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans. The results of the cellular experiments showed that the composite nanofiber membranes were nontoxic and promoted the proliferation of L929 cells. In summary, electrospun nanofiber membranes loaded with PPE can be used as a wound dressing.

In this work, a fast water-responsive shape memory hybrid polymer based on thermoplastic polyurethane (TPU) was prepared by crosslinking with hydroxyethyl cotton cellulose nanofibers (CNF-C) and multi-walled carbon nanotubes (CNTs). The effect of CNTs content on the electrical conductivity of TPU/CNF-C/CNTs nanocomposite was investigated for the feasibility of being a strain sensor. In order to know its durability, the mechanical and water-responsive shape memory effects were studied comprehensively. The results indicated good mechanical properties and sensing performance for the TPU matrix fully crosslinked with CNF-C and CNTs. The water-induced shape fixity ratio (R_f) and shape recovery ratio (R_r) were 49.65% and 76.64%, respectively, indicating that the deformed composite was able to recover its original shape under a stimulus. The TPU/CNF-C/CNTs samples under their fixed and recovered shapes were tested to investigate their sensing properties, such as periodicity, frequency, and repeatability of the sensor spline under different loadings. Results indicated that the hybrid composite can sense large strains accurately for more than 10³ times and water-induced shape recovery can to some extent maintain the sensing accuracy after material fatigue. With such good properties, we envisage that this kind of composite may play a significant role in developing new generations of water-responsive sensors or actuators.

A co-based porous metal-organic framework (MOF) of zeolitic imidazolate framework-67 (ZIF-67) and carbon nanofibers (CNFs) was utilized to prepare a ZIF-67/CNFs composite via a one-pot synthesis method. Scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), and X-ray diffraction (XRD) were employed to investigate the morphology, structure, and composition of the resulting composite. A novel high-performance non-enzymatic electrochemical sensor was constructed based on the ZIF-67/CNFs composite. The ZIF-67/CNFs based sensor exhibited enhanced electrocatalytic activity towards H₂O₂ compared to a pure ZIF-67-based sensor, due to the synergistic effects of ZIF-67 and CNFs. Meanwhile, chronoamperometry was utilized to explore the detection performance of the sensor. Results showed the sensor displayed high-efficiency electrocatalysis towards H₂O₂ with a detection limit of 0.62 μM (S/N = 3), a sensitivity of 323 µA mM⁻¹ cm⁻², a linear range from 0.0025 to 0.19 mM, as well as satisfactory selectivity and long-term stability. Furthermore, the sensor demonstrated its application potential in the detection of H₂O₂ in food.