The measurement of mixing time in a water model of soft-stirring steelmaking ladles is practically facing a problem of bad repeatability. This uncertainty severely affects both the understandings of transport phenomenon in ladles and the measurement accuracy. Scaled down by a ratio of 1:4, a water model based on an industrial 260-ton ladle is used. This paper studies the transport process paths and mixing time of salt solution tracers in the water model of eccentric gas-stirred ladles with a low gas flow rate. After a large number of repeated experiments, the different transport paths of the tracer and the error of the mixing time in each transport path are discussed and compared with the numerical simulation results. The results of a large number of repeated experiments on the water model show that there are five transport paths for the tracer in the ladle. The tracer of the first path is mainly transported by the left-side main circulation flow, which is identical to the numerical simulation results. The tracer of the second and third paths are also mainly transported by the left-side circulation flow, but bifurcations occur when the tracer in the middle area is transported downward. In the third path, the portion and intensity of the tracer transferring to the right side from the central region is higher than in the second path. The fourth path is that the tracer is transported downward from the left, middle, and right sides with a similar intensity at the same time. While the tracer in the fifth path is mainly transported on the right side, and the tracer forms a clockwise circulation flow on the right side. The mixing times from the first transport path to the fifth transport path are 158.3 s, 149.7 s, 171.7 s, 134 s and 95.7 s, respectively, among which the third transport path and the fifth transport path are the maximum and minimum values among all transport paths. The error between the mixing time and the averaged mixing time at each monitoring point in the five transport paths of the tracer is between −34.7% and 40.9%. Furthermore, the error of the averaged mixing time of each path and the path-based average value is between 5.5% and 32.6%.
Mixing time, as a key parameter for evaluating ladle refining efficiency, has long attracted extensive attention from researchers. In typical experimental studies, salt solution tracers are introduced into ladle water models to assess the degree of mixing within the ladle. Previous studies have demonstrated that the volume of tracer can significantly influence the measured mixing time. However, the gas flow rates employed in these studies are generally relatively high, whereas, in industrial operations, especially during final composition adjustments, lower gas flow rates are often applied. To systematically investigate the effect of the salt solution tracer volume on the mixing efficiency in a ladle water model under asymmetrical gas stirring with a low gas flow rate, a 1:3-scaled water model was developed based on a 130-ton industrial ladle. The mixing behaviors corresponding to different tracer volumes were comprehensively analyzed. The results indicate that the relationship between tracer volume and mixing time is non-monotonic. As the tracer volume increases, the mixing time first decreases and then increases, reaching a minimum at 185 mL. When the tracer volume was small, the dimensionless concentration curves at Monitoring Point 4 exhibited two distinct patterns: A parabolic profile, which was when the tracer initially moved through the left and central regions and then slowly crossed the gas plume to reach the monitoring point. A sinusoidal profile, which was when the tracer predominantly circulated along the right side of the ladle. When the tracer volume exceeded 277 mL, the concentration curves at Monitoring Point 4 consistently exhibited a sinusoidal pattern. Compared with moderate gas flow conditions (8.3 L/min), the peak concentration at Monitoring Point 3 was significantly lower under a low gas flow (2.3 L/min), and the overall mixing time was longer, indicating reduced mixing efficiency. Based on the findings, a recommended tracer volume range of 185–277 mL is proposed for low gas flow conditions (2.3 L/min) to achieve accurate and efficient mixing time measurements with minimal disturbance to the flow field. It was also observed that when the tracer concentration was relatively low, the mixing behavior throughout the ladle became more uniform.
The study focuses on the four-strand tundish as the research object, aiming at the phenomenon of fewer strand casting (stable blockage) and sudden blockage of the tundish in industrial production. Numerical simulation methods are employed to compare the velocity vectors, flow fields, residence time distribution (RTD) curves, and outflow percentage curves under stable blockage and sudden blockage of the tundishes with a double-weir structure, U-shaped weir structure, and U-shaped weir structure with holes in the front. The results indicate that, after sudden blockage of the tundish strands, the flow field transitions from an unstable four-strand flow field to a stable three-strand flow field. Both the double-weir tundish and the U-shaped weir tundish reach a stable state after 200 s, while the U-shaped weir tundish with holes in the front reaches stability after 150 s. Additionally, compared to other structures, the tundish strands of the U-shaped weir with holes in the front are less affected by blockage, showing better consistency among strands and better adaptability under non-standard casting conditions.
High-titanium steel contains an elevated titanium content, which promotes the formation of abundant non-metallic inclusions in molten steel at high temperatures, including titanium oxides, sulfides, and nitrides. These inclusions adversely affect continuous casting operations and generate substantial internal/surface defects in cast slabs, ultimately compromising product performance and service reliability. Therefore, stringent control over the size, distribution, and population density of inclusions is imperative during the smelting of high-titanium steel to minimize their detrimental effects. In this paper, samples of high titanium steel (0.4% Ti, 0.004% N) casting billets were analyzed by industrial test sampling and full section comparative analysis of the samples at the center and quarter position. Using the Particle X inclusions, as well as automatic scanning and analyzing equipment, the number, size, location distribution, type and morphology of inclusions in different positions were systematically and comprehensively investigated. The results revealed that the primary inclusions in the steel consisted of TiN, TiS, TiC and their composite forms. TiN inclusions exhibited a size range of 1–5 µm on the slab surface, while larger particles of 2–10 μm were predominantly observed in the interior regions. Large-sized TiN inclusions (5–10 μm) are particularly detrimental, and this problematic type of inclusion predominantly concentrates in the interior regions of the steel slab. A gradual decrease in TiN inclusion number density was identified from the surface toward the core of the slab. Thermodynamic and kinetic calculations incorporating solute segregation effects demonstrated that TiN precipitates primarily in the liquid phase. The computational results showed excellent agreement with experimental data regarding the relationship between TiN size and solidification rate under different cooling conditions, confirming that increased cooling rates lead to reduced TiN particle sizes. Both enhanced cooling rates and reduced titanium content were found to effectively delay TiN precipitation, thereby suppressing the formation of large-sized TiN inclusions in high-titanium steels.
In continuous casting, fewer strand operations are sometimes required to match production schedules. However, the study of flow behavior and temperature distribution under fewer strand casting conditions remains insufficiently systematic, especially with regard to the grade casting process, which has not yet been explored. This study presents an innovative investigation of the grade transition process in a symmetrical 12-strand tundish under fewer strand casting conditions. Seven operational cases were analyzed: standard casting (the normal symmetric Case 0), individual closure of strands 1–6 (the asymmetric Cases 1–6), and simultaneous closure of strands 1–2 (the asymmetric Case 7). Notably, strand closures in Cases 5 and 6 significantly impair flow characteristics in their respective strands. The impact area temperature reaches approximately 1844 K (new heat) after 30 min of continuous casting. However, Case 6 exhibits persistent low-temperature regions near strands 5 and 6. The average transition billet lengths for Cases 0 to 7 are 72.41 m, 70.16 m, 70.30 m, 71.68 m, 72.95 m, 72.12 m, 76.35 m, and 65.45 m, respectively. Based on a comprehensive evaluation of flow dynamics, temperature uniformity, and transition billet length, Case 1 emerges as the most favorable single-strand closure strategy. Operational recommendations suggest avoiding strand closure patterns implemented in Cases 5 and 6 during reduced strand casting operations.
In this study, a laboratory-scale slag–steel reaction experiment was conducted to systematically evaluate the influence of the initial MgO content (3–7 wt.%) in LF refining slag on the cleanliness of GCr15 bearing steel. The assessment was performed from multiple perspectives by comparing the total oxygen content (T[O]) in molten steel, the inclusion area fraction, and the inclusion number density after 30 min of slag–steel interaction. To further elucidate the thermodynamic driving forces and kinetic mechanisms governing inclusion capture by slag, a predictive slag adsorption model was developed using an in-house computational code coupled with FactSage 8.1. Under conditions of slag basicity R (CaO/SiO2) ranging from 4.0 to 8.0, MgO content varying from 0 to 7 wt.%, and a constant Al2O3 content of 32 wt.%, the chemical driving force ΔC (the mass-fraction difference between slag components and inclusions), the slag viscosity η, and the combined parameter ΔC/η were calculated at 1600 °C for three representative inclusion types: Al2O3, MgO·Al2O3, and MgO. In addition, the model was employed to quantitatively characterize the adsorption capacity of slag toward Mg–Al binary inclusions under varying MgO levels. Both experimental observations and model calculations demonstrate that the slag–steel reaction markedly enhances inclusion removal, as evidenced by pronounced decreases in T[O], inclusion number density, and inclusion area fraction after reaction. With increasing MgO content in slag, T[O] and inclusion-related indices exhibit a consistent trend of first decreasing and then increasing, reaching minimum values at an MgO level of 5 wt.%. Further analysis reveals a positive correlation between the apparent inclusion-removal rate constant ko and ΔC/η corresponding to MgO·Al2O3 inclusions. Moreover, the slag’s adsorption capacity toward Mg–Al binary inclusions decreases overall as the MgO fraction in inclusions increases. Notably, when the MgO content in inclusions exceeds 29 wt.%, the adsorption capacity undergoes an abrupt drop, indicating a pronounced cliff-like attenuation behavior.