Nanotechnology has been widely used in many fields including in soil and groundwater remediation. Nanoremediation has emerged as an effective, rapid, and efficient technology for soil and groundwater contaminated with petroleum pollutants and heavy metals. This review provides an overview of the application of nanomaterials for environmental cleanup, such as soil and groundwater remediation. Four types of nanomaterials, namely nanoscale zero-valent iron (nZVI), carbon nanotubes (CNTs), and metallic and magnetic nanoparticles (MNPs), are presented and discussed. In addition, the potential environmental risks of the nanomaterial application in soil remediation are highlighted. Moreover, this review provides insight into the combination of nanoremediation with other remediation technologies. The study demonstrates that nZVI had been widely studied for high-efficiency environmental remediation due to its high reactivity and excellent contaminant immobilization capability. CNTs have received more attention for remediation of organic and inorganic contaminants because of their unique adsorption characteristics. Environmental remediations using metal and MNPs are also favorable due to their facile magnetic separation and unique metal-ion adsorption. The modified nZVI showed less toxicity towards soil bacteria than bare nZVI; thus, modifying or coating nZVI could reduce its ecotoxicity. The combination of nanoremediation with other remediation technology is shown to be a valuable soil remediation technique as the synergetic effects may increase the sustainability of the applied process towards green technology for soil remediation.
Pharmaceutical contamination threatens both humans and the environment, and several technologies have been adapted for the removal of pharmaceuticals. The coagulation-flocculation process demonstrates a feasible solution for pharmaceutical removal. However, the chemical coagulation process has its drawbacks, such as excessive and toxic sludge production and high production cost. To overcome these shortcomings, the feasibility of natural-based coagulants, due to their biodegradability, safety, and availability, has been investigated by several researchers. This review presented the recent advances of using natural coagulants for pharmaceutical compound removal from aqueous solutions. The main mechanisms of natural coagulants for pharmaceutical removal from water and wastewater are charge neutralization and polymer bridges. Natural coagulants extracted from plants are more commonly investigated than those extracted from animals due to their affordability. Natural coagulants are competitive in terms of their performance and environmental sustainability. Developing a reliable extraction method is required, and therefore further investigation is essential to obtain a complete insight regarding the performance and the effect of environmental factors during pharmaceutical removal by natural coagulants. Finally, the indirect application of natural coagulants is an essential step for implementing green water and wastewater treatment technologies.
The process of looking for alternative energy sources is driven by the increasing demand for energy and environmental contamination caused by using fossil fuels. Recent investigations reported the efficiency of microalgae for biofuel production due to its low cost of production, high speed of growth, and ability to grow in harsh environments. In addition, many microalgae are photosynthetic, consuming CO2 and solar light to grow in biomass and providing a promising bioenergy source. This review presents the recent advances in the application of microalgae for biofuel production. In addition, cultivation and harvesting systems and environmental factors that affect microalgae cultivation for biofuel production have also been discussed. Moreover, lipid extraction and conversion technologies to biofuel are presented. The mixotrophic cultivation strategy is promising as it combines the advantages of heterotrophy and autotrophy. Green harvesting methods such as using bio-coagulants and flocculants are promising technologies to reduce the cost of microalgal biomass production. In the future, more investigations into co-cultivation systems, new green harvesting methods, high lipids extraction methods, and the optimization of lipid extraction and converting processes should be implemented to increase the sustainability of microalgae application for biofuel production.
Algae have the potential to be used as a feedstock for the synthesis of valuable compounds and biofuels. In addition, algal waste can be further transformed into biofuel, biogas, and biochar using different thermochemical processes such as microwave pyrolysis, pyrolysis, torrefaction, and hydrothermal conversion. Due to its high specific surface area, rapid electron transport, and graphitic carbon structure, algal biochar carbonized at high temperatures has shown outstanding performance for applications as CO2 adsorbents, supercapacitors, and persulfate activation. Due to the combination of various functional groups and porous structures, the algae biomass pyrolysis at a moderate temperature produced high-quality biochar that shows high performance in terms of pollutant removal, while low-temperature pyrolysis produces coal fuel from algae via torrefaction. Over time, there have been exponentially more petroleum-based polymers created that have harmful impacts on both humans and the environment. As a result, researchers are becoming more interested in algae-based biopolymers as a potential alternative strategy for establishing a sustainable circular economy globally. The advantages of microalgal biopolymer over other feedstocks are its capacity to compost, which provides greenhouse gas credits, its quick growth ability with flexibility in a variety of settings, and its ability to minimize greenhouse gas emissions.
Laboratory-scale column experiments were conducted to assess the impact of different LNAPL volumes on LANPL migration behavior in capillary zone in porous media. Three different volumes of diesel (50 mL, 100 mL, and 150 mL) were released in different experiments using a 1D rectangular column filled with natural sand. The water table was set at 29 cm from the bottom of the column. The image analysis results provided quantitative time-dependent data on the LNAPL distribution through the duration for the experiments. Results demonstrated that the higher diesel volume (150 mL) exhibited the faster LNAPL migration through all experiments. This observation was due to the high volume of diesel as compared to other cases which provides high pressure to migrate deeper in a short time. In all experiments, the diesel migration was fast during the first few minutes of observation and then, the velocity was decreased gradually. This is due to pressure exerted by diesel in order to allow the diesel to percolate through the sand voids. Overall, this study proved that the image analysis can be a good and reliable tool to monitor the LNAPL migration in porous media.
Improper solid waste management (SWM) has resulted in an environmental and epidemiological catastrophe, emphasizing the urgency of SWM due to escalating solid waste generation. Over the past few decades, there has been significant growth in publications studying the relationship between SWM and the environment. Higher education institutes (HEIs) also have a social responsibility to promote public understanding of SWM and to increase awareness among students about SWM. A bibliometric analysis was conducted to provide an overview of research on student awareness of SWM in HEIs over the past 35 years. Data on publication output are identified based on the Scopus database (from 1989 to 2024). A total of 634 articles on SWM awareness and practices among students in HEIs were identified. VOSviewer was used to map the current studies and visualize the current trends in this area. The analysis of keywords used in the publications highlights recurring terms such as “recycling”, “environmental awareness”, and “waste management”, indicating the primary research focus. The results show a significant increase in publications in this area over the last 35 years. China, the US, and the UK emerge as the countries with the highest number of publications with 115, 82, and 44 publications, respectively, where China alone contributed 18.14% of the total publications on the topic, with the Chinese Academy of Sciences and Tsinghua University being the leading institutions in this research field. The results also highlight the top researchers in the field of student awareness of SWM in HEIs. It identifies influential journals in this field, such as Sustainability (MDPI) and the Journal of Cleaner Production (Elsevier). Overall, this study provides valuable insights into the current state of research on student awareness of SWM in HEIs, identifying research hotspots. It serves as a valuable resource for academics and practitioners interested in this area. The findings of the study are intended to guide researchers planning to conduct further research on the issue.