The use of polymer foams is becoming increasingly important due to the attainable weight reduction and value‐added properties. The development of foam structures is a popular research area as they have outstanding energy absorbing capability, which is related to the special deformation mechanisms of the cell structure (cell wall buckling and collapse of the cells). This property is exploited by the sports industry, where the main task of such products is to protect the health of the athlete and to ensure safe sports conditions. This review provides a comprehensive presentation of the advanced energy absorbing applications of polymeric foams in sports. The article presents in detail the processing technologies of polymer foams, as well as the sports‐specific regulations which contain the requirements for sports products. The impact damping of polymeric foams is typically determined by falling weight impact tests, which were used in several previous studies. However, it is a great challenge to compare the published results, as the test parameters and the tested materials are different. Currently, an unexplored field of research is the detailed study of multilayer sandwich foam structures. Understanding the effect of layer order on mechanical properties would help researchers achieve a major improvement in this field.
This study presents the applicability of different types (exothermic and endothermic) of chemical blowing agents (CBAs) in the case of poly(lactic acid) (PLA). The amount of foaming agent is a fixed 2 wt%. We used a twin-screw extruder and added the individual components in the form of dry mixture through the hopper of the extruder. We characterized the PLA matrix and the chemical blowing agents with different testing methods. In case of the produced foams we carried out morphological and mechanical tests and used scanning electron microscopy to examine cell structure. We showed that PLA can be successfully foamed with the use of chemical blowing agents. The best results were achieved with an exothermic CBA and with PLA type 8052D. The cell population density of PLA foams produced this way was 4.82 × 105 cells/cm3, their expansion was 2.36, their density 0.53 g/cm3 and their void fraction was 57.61%.
1 March 2015 in Composites Part A: Applied Science and Manufacturing
This study presents the investigation of different content of thermally expandable microsphere (EMS) type of a physical blowing agent added to polylactic acid (PLA). The effects of the different doses of EMS, processing temperatures, and d-lactide content of the polylactic acid were analyzed for foam properties and structures. We characterized the different PLAs and the physical blowing agent with different testing methods (gel permeation chromatography, rotational rheometry, isothermal thermogravimetric analysis, and thermomechanical analysis). The amounts of the foaming agent were 0.5, 1, 2, 4, 8 wt%, and processing temperatures were 190 °C, 210 °C, and 230 °C. The foam structures were produced by twin-screw extrusion. We used scanning electron microscopy to examine the cell structure of the foams produced, and carried out morphological and mechanical tests as well. The result of extrusion foaming of PLA using different amounts of EMS shows that an exponentially decreasing tendency of density reduction can be achieved, described by the following equation, ρ(x (R2 = 0.947) at 190 °C. With increasing processing temperature, density decreases at a lower rate, due to the effect that the microspheres are unable to hold the pentane gas within the polymer shell structure. The d-lactide content of the PLAs does not have a significant effect on the density of the produced foam structures.