Concrete structures under cyclic exposure to chlorides entail a higher risk of embedded steel corrosion along with accelerated ionic ingress from the environment. This study proposes a coupled transport model considering moisture and chloride distribution in concrete to investigate the influence of a cyclic exposure condition on chloride penetration. In this model, pore size distribution to quantify the effective pore space for moisture and chloride mobilizations was determined to establish the governing equation for chloride transport through non-saturated concrete. From the simulation results, the rate of chloride penetration increases with decreasing ambient humidity levels due to the enhanced chloride convection. Finally, the coupled transport model was verified by comparing in-situ data, showing reasonable correlations with 0.83 and 0.93 of determinant coefficients for 22 and 44 years of exposure, respectively, while those obtained from LIFE 365 were much lower.

Rapid-hardening concrete is widely used for rapid repairs but can suffer from accelerated hydration, shrinkage-related cracking, and durability concerns. This study evaluates the feasibility of replacing cement with OLED waste glass powder (0–30%) in CSA-type rapid-hardening concrete as a low-impact repair material. Mixtures were prepared at a constant binder content (400 kg/m³) and water-to-binder ratio (0.425), and fresh properties (slump, air content, setting time) and mechanical performance (compressive and bond strength) were tested from 4 h to 56 d. Mercury intrusion porosimetry (MIP) and TG/DTG were additionally used to interpret changes in pore structure and hydration-related thermal indices. Increasing glass powder replacement improved workability but delayed setting. A 10% replacement (O-GP10) maintained 4 h compressive strength and showed slightly higher long-term strength and consistently higher long-term bond strength than the control, whereas 20–30% replacement caused pronounced strength loss due to dilution. MIP results indicated that O-GP10 suppressed large pores (>0.1 μm) and promoted a refined pore structure dominated by finer pores. TG/DTG trends were interpreted using temperature windows as comparative indicators, suggesting age-dependent bound-water development and a reduced apparent contribution in the Al-bearing-hydrate-related region for O-GP10. Overall, roughly 10% OLED waste glass powder is suggested for CSA rapid-hardening concrete to ensure early functioning while enhancing long-term bonding and microstructural stability.