We demonstrate the possibility of diffusion formation of the chemically ordered L1 ₀-MnPt phase through the vacuum annealing of Pt(24 nm)/Mn(20 nm) and Pt(12 nm)/Mn(20 nm)/Pt(12 nm) layered stacks at 400 °C for 30 min. For the bi-layered stack annealed at 400 °C, the effect of Pt atoms segregation at the film/substrate interface was detected, which remained after annealing even at higher temperatures (500 °C and 600 °C) and prevented the whole homogenization of the chemical composition through the film depth. By contrast, for the tri-layered stack annealed at 400 °C, the presence of the additional Pt bottom layer enabled to change the rate and mechanism of reactive diffusion, leading to homogeneous distribution of components and enhanced crystallinity of the ordered L1 ₀-MnPt phase compared to the bi-layered sample. An explanation of the obtained experimental data is provided based on the fundamentals of mass transfer theory and its quantitative parameters (e.g. activation energy and diffusion coefficients).

Composite ZnO/Fe nanostructured thin films are synthesized via physical vapor deposition using radio frequency magnetron sputtering in conventional, as well as in glancing angle deposition (GLAD) geometries. ZnO is employed as a compact nanocolumnar template to direct Fe growth in bilayer and multilayer architectures. Morphological analysis reveals well-defined ZnO/Fe interfaces for normal deposition geometry, with diminished interface clarity and reduced layer thickness in GLAD samples. Crystallographic characterization indicates clear ZnO-{002} and α-Fe-{110} texture. Magnetostatic characterization investigates the effects of morphology on coercivity and domain nucleation. GLAD-deposited Fe films exhibit clear in-plane magnetic anisotropy, with remanence to saturation magnetization (M_REM/M_SAT) equal to 1 for the easy axis and equal to 0.24 for the hard axis, consistent with inclined nanocolumn morphology. Our findings show that deposition geometry, rather the ZnO template, mostly affects the morphology of Fe films. The above, highlight the potential of engineered ZnO/Fe nanocomposites for magnetic, spintronic, and magnetoplasmonic applications, by tuning morphology and interface quality through deposition parameters.