The aim of the conducted research was to obtain information on the main components of ashes from 35 biomass species used in combustion processes to obtain reference data for the development of utility possibilities for these ashes, with particular emphasis on agricultural use. The examined biomass samples were divided into groups depending on origin: woody biomass and energetic woody plants I-WWB, herbaceous and grassy energy plants II-EC, agricultural waste III-AR, forest waste IV-FR and waste from the agri-food industry V-AFIW. The analysis of the studied elements contents was carried out in the designated groups. The chemical composition of ash was dominated by the macroelements Ca, K, P and S, which suggests the possibility of their agricultural use. At the same time, the low content of toxic elements such as As and Pb should not be a limiting feature in their use, with the exception of wood biomass. In addition, ashes obtained from the biomass combustion were enriched with microelements such as Zn, Cu and Mn, which further increases their possibilities of fertilizer use. The potential use of ash from each type of biomass in the aspect of its chemical composition should be considered individually, regardless of the division into groups depending on the origin of biomass.

This article presents the influence of ash-forming temperature on ash content and the content of selected heavy metals. The biomasses most commonly used in low-power heating boilers, such as miscant, oak, pine, sunflower husk, wheat straw and willow, were selected for the research. The biomass was incinerated at temperatures of 600 °C, 700 °C, 800 °C, 900 °C and 1000 °C, using the X-ray Fluorescence Spectrometer (XRF) for the measurement of element content. The results show that the content of heavy metals in the examined ash was not excessive and could not be considered as potentially dangerous. As the ash-forming temperature increased, the content of Zn, Cd, Cu and Pb decreased, which indicates that, at higher temperatures, they went into the gas phase. Cr, Ni and Fe were thermally stable and less volatile, thus the ashes were enriched with them as the ash-forming temperature increased.

The content of heavy metals Cd, Cr, Cu, Fe, Ni, Pb and Zn in ash samples from miscanthus, oak, pine, sunflower husk, wheat straw, and willow ashes burned at 500, 600, 700, 800, 900, and 1000 °C, respectively, was determined. The statistical analysis of the results was based on multivariate methods: hierarchical cluster analysis (HCA), and principal component analysis (PCA), which made it possible to classify the raw materials ashed at different temperatures into the most similar groups, and to study the structure of data variability. Using PCA, three principal components were extracted, which explain more than 88% of the variability of the studied elements. Therefore, it can be concluded that the application of multivariate statistical techniques to the analysis of the results of the study of heavy metal content allowed us to draw conclusions about the influence of biomass properties on its chemical characteristics during combustion.

The paper presents results of experimental studies concerning CO₂ emission of S-4003 diesel engine Ursus C-360 at a variable fuel injection advance angle and opening pressure of injectors. Measurements were made on the dynamometric stand on the test bench. The engine operated according to the load characteristic at two characteristic rotational speeds i.e., at the maximum torque velocity (1600 rpm) and at the rated speed (2200 rpm). In each measurement point of load characteristics, CO₂ concentration was measured in exhaust gases with the use of exhaust gases analyser M-488 Multigas Plus. For a more detailed analysis of the CO₂ content in exhaust gases, additional change of O₂ level emission was presented, which in the biggest amount combines elementary carbon included in fuel during combustion. The studies showed the CO₂ content reduction in exhaust gases at the reduced (by 3º of crankshaft rotations) fuel injection advance angle in comparison to the nominal angle by 4.5% at the rotational speed of 1600 rpm and by 5.7% at the speed of 2200 rpm (the average values for all measurement points of load - brake horsepower of engine). Similarly, CO₂ concentration decrease in exhaust gases of the investigated engine was reported for the increased (by 1.5 MPa) opening pressure of injectors in comparison to the nominal pressure, on average by 9.8% for the speed of the maximum rotational moment and by 4.5% for the rated speed.

Oil has an enormous influence on the condition of the engine. Determining its degradation allows companies to maximize the availability of a specific vehicle and fleet of vehicles in general. In the evolution of engine oil degradation, one of the variables considered to be the most important is soot content. This article examines the direction and severity of soot content and dispersion changes in engine oil occurring during actual engine operation during four complete change intervals. The oil under study was operated in a city bus. It belonged to the fleet of vehicles of a transport company from new to the mileage of about 200,000 km. Soot content was determined in accordance with ASTM E2412-10, while dispersion size was determined using the dried drop test in accordance with ASTM D7899. The results obtained provide the basis for the conclusion that the direction of change in soot content in each interval is characterized by a high degree of homogeneity. With respect to the degree of soot build-up, a high level of similarity was observed between the intervals studied. The study of change in the degree of oil dispersion using the “drop on blotter” method made it possible to confirm the trend of decreasing dispersion as the run increases. The obtained results led to the development of a statistical model describing these relationships.