Sugarcane bagasse is an inexpensive and eco-friendly natural biosorbent for the removal of various organic pollutants. The adsorption of Remazol Brilliant Violet-5R (RBV-5R) dye on sugarcane bagasse (SCB) was studied. Biosorbent was characterized using EDX and FTIR. The effect of various experimental parameters, such as pH, biosorbent dosage, initial dye concentration, contact time, adsorption with shaking and without shaking, and the temperature, was optimized. At pH 6, maximum biosorption of 92.22% was achieved using 0.15 g of SCB. The equilibrium was attained within 30–40 min for the removal of RBV-5R. The initial dye concentration of 10 µg/mL was determined as an optimum concentration for maximum removal of RBV-5R at 30 °C. Langmuir and Freundlich adsorption isotherms were applied, and it was found that the biosorption of RBV-5R follows Freundlich adsorption isotherms. Kinetic studies were also carried out and it was found that the proposed method followed the pseudo-second-order kinetic model (R2 = 0.98). From desorption study, it was found that maximum desorption in the increasing order was obtained using ethanol, methanol, and 0.2 M sodium hydroxide (NaOH). The biosorption study was applied to actual textile waste effluent to pave way for the practical usage of this technology on a larger scale and the results were found effective.
This study reveals the modification of the surface area of natural zeolite Clinoptilolite (CLN) by implementing the ion exchange method. The ammonium chloride cation exchange method was adopted and was followed by calcination at 450 °C for 5 h. This procedure helps to increase the surface area of CLN and also enhances its adsorption efficiency. The modifications of the CLN were confirmed by Fourier-transform infrared (FT-IR) spectroscopy and X-ray diffraction (XRD) analysis. The efficiency and adsorption capacity of the modified CLN were determined by the adsorption of a Rhodamine B (Rh B) dye from an aqueous medium. The comparative analysis of the adsorption efficiency of raw CLN and the modified CLN revealed an enhanced adsorption of Rh B by the modified CLN at pH = 10. For desorption, different solvents were used. The results showed good desorption in ethanol and methanol, and poor desorption in acidic (HCl) and basic (NaOH) solutions. The kinetic study of the adsorption of Rh B by the modified CLN helped us to conclude that the adsorption follows a pseudo-second-order kinetics. For the surface study and to understand the mechanism of adsorption, several isotherm models were applied to the adsorption data at equilibrium. The data showed consistency with the Freundlich adsorption isotherm confirming that the process took place at its heterogeneous surface. The experimentally calculated adsorption capacity of the modified CLN was 2.81 mg g−1, showing a comparable value to certain other common adsorbents. Therefore, the modified CLN may also be considered a cost-effective and promising adsorbent for the removal of Rh B dye from wastewater.
Nebrodenside A was isolated from the plant Dodonaea viscosa and its chemical structure was elucidated by spectroscopic methods. Molecular docking simulation predicted its strong ability to be tested as a potential anti-inflammatory compound. Carrageen-induced paw model and formalin test were utilized for the assessment of anti-inflammatory and analgesic potential. Nebrodenside A was found to be significantly active in reducing inflammation, when compared with diclofenac as a standard drug. Similarly, the compound also possesses substantial analgesic activity in the formalin-induced writhing test. Thus, nebrodenside A revealed a robust potential to be developed as a possible leading medicinal agent for better management of pain and inflammation.